Four new Schiff base ligands carrying naphthalene groups were prepared from the reaction of 2,4-diamino-6-methyl-1,3,5-triazine and 2,4-diamino-6-undecyl-1,3,5-triazine with 2-hydroxy-1-naphthaldehyde. The influence of a series of metal ions including Cu2+, Co2+, Hg2+, Al3+, Cr3+, Fe3+, Pb2+, Ni2+, Cd2+, Zn2+, Mn2+, Ag+, Ba2+, Ca2+ and Mg2+ on the spectroscopic properties of the ligands was investigated by means of absorption and emission spectrometry. The results of spectrophotometric and spectrofluorimetric titrations disclosed the complexation stoichiometry and complex stability constant of the ligands with metal ions. A simple spectrofluorimetric method was developed using the Schiff base derived from 2,4-diamino-6-undecyl-1,3,5-triazine to determine Hg2+ ion. No cleanup or enrichment of the tap water sample was required. A modified standard addition method was used to eliminate matrix effect. The standard addition graph was linear between 0.2 and 2.6 mg/L in determination of Hg2+. Detection and quantification limits were 0.08 and 0.23 mg/L, respectively. The simple and cost-effective method can be applied to water samples. 相似文献
The dispersion polymerizations of styrene (St) and methyl methacrylate (MMA) initiated by poly(oxyethylene) macroinimer (PEO-MIM) in ethanol/water were investigated at 50, 60 and 80°C. The polymerisation rate vs. conversion dependence was described by with a maxim at the beginning of polymerisation. Polymerization was faster with MMA than with St. The limiting conversion was inversely proportional to temperature and was much more pronounced with St. The rate of polymerization increased with temperature. The overall initial activation energy increased with conversion and reached value ca. 25 kJ.mol−1 for MMA and 50 kJ.mol−1 for styrene at ca. 60% conversion. The particle size was observed to decrease with increasing the macroinimer concentration. The polymer dispersions were unstable and a large amount of coagulum appeared during the polymerisation especially in the styrene-containing reaction system. 相似文献
We consider the problem where a manager aims to minimize the probability of his portfolio return falling below a threshold while keeping the expected return no worse than a target, under the assumption that stock returns are Log-Normally distributed. This assumption, common in the finance literature for daily and weekly returns, creates computational difficulties because the distribution of the portfolio return is difficult to estimate precisely. We approximate it with a single Log-Normal random variable using the Fenton–Wilkinson method and investigate an iterative, data-driven approximation to the problem. We propose a two-stage solution approach, where the first stage requires solving a classic mean-variance optimization model and the second step involves solving an unconstrained nonlinear problem with a smooth objective function. We suggest an iterative calibration method to improve the accuracy of the method and test its performance against a Generalized Pareto Distribution approximation. We also extend our results to the design of basket options. 相似文献
Six rhodium–carbene complexes (2a–f) have been prepared and the new compounds characterized by C, H, N analyses, 1H-n.m.r. and 13C-n.m.r. Phenylboronic acid reacts with aldehydes in the presence of a catalytic amount of rhodium(I)–carbene complex, RhCl(COD)(1,3-dialkylbenzimidazolidin-2-ylidene), (2a–f), to give the corresponding aryl secondary alcohols in good yields. 相似文献
A new type of fluorescent chemosensor based on tethered hexa-borondipyrromethene cyclotriphosphazene platform (HBTC) linked via triazole groups was designed and synthesized. Its sensing behavior toward metal ions was investigated by ultraviolet-visible and fluorescence spectroscopies. Addition of a Fe2+ ion to a tetrahydrofuran solution of HBTC gave a visual color change as well as a significantly quenched fluorescence emission, while other tested 19 metal ions induced no color or spectral changes. This compound was found to be highly selective and sensitive for Fe2+ with a low limit of detection (2.03 μM) which is, to the best of our knowledge, the superior than the previously studied chemosensors for Fe2+.
We describe the synthesis and characterization of two novel azo ligands, 4,5-dihydroxy-3,6-bis(2-hydroxyphenylazo)-2,7 naphthalene
disulfonic acid (H2L) and 4,5-dihydroxy-3,6-bis(2-hydroxy-4-sulfophenylazo)-2,7-naphthalenedisulfonic acid (H2L1). The Cu(II), Ni(II), and Co(II) complexes of these ligands were prepared and characterized by infrared, UV–Vis, 1H- and 13C-NMR spectra, atomic absorption spectroscopy, mass spectrometry, elemental analyses, thermogravimetric analysis, conductivity,
cyclic voltammetry, and magnetic measurements. The results suggest that the complexes have a 2:1 (metal:ligand) molar ratio,
involving binuclear azo ligands with an ONO donor set. Metal ion uptake studies were conducted with a batch technique. Preliminary
histological studies were also made. The results indicate that the azo ligands have high thermal stability, good metal extraction
capacity, and favorable dying properties with certain tissues. 相似文献
Long-chain N-alkyl-2-(phenylthio)acetohydrazides were synthesized via the reactions of 2-(phenylthio)acetohydrazide with long-straight-chain aldehydes and then reduction with sodium borohydride.
The reactions of long-straight-chain hydrazides with carbon disulfide in alkaline media give the corresponding carbodithioate
salts. Heating of potassium 2-alkanoylhydrazinecarbodithioates with phenacyl bromide do not yield cyclization and failed to
give the corresponding long-chain thiazolidine-2-thiones, but gave the corresponding 2-oxo-2-phenylethyl-2-alkanoylhydrazinecarbodithioates
via nucleophilic substitution reaction. In addition, the synthesized compounds were tested for their corrosion prevention capabilities
in acidic or in mineral oil media.
Correspondence: Ayhan Yıldırım, Department of Chemistry, Faculty of Science and Arts, Uludağ University, 16059 Bursa, Turkey. 相似文献
Trans-Bis[1,3-bis(2,4-dimethylphenylimidazolidin-2-ylidene)]dichloropalladium(II), 4, was prepared from 1,3-bis(2,4-dimetilphenyl)imidazoliniumchloride. The crystal and molecular structure of 4 have been determined by single crystal X-ray diffraction. The title compound, C38H44N4PdCl2, crystalizes in the monoclinic space group P 21/n with a = 13.8713(9) Å, b = 12.1365(6) Å, c = 21.5499(15) Å. The Pd atom has a slightly distorted square planar coordination geometry. The molecules of the title compound are linked by C–H···Cl weak hydrogen bonds into two-dimensional sheets parallel to the (001) plane. In addition, the title compound was characterized by elemental analyses and NMR spectroscopy. 相似文献
This study reports the synthesis of water soluble iron(II) phthalocyanine and a facile method for spectrophotometric determination of Hg(II) in environmental water samples by ionic liquid based dispersive liquid–liquid microextraction (IL-DLLME). In the method, 1-heptyl-3-methylimidazolium hexafluorophosphate (250 µL) as extraction solvent, acetonitrile (750 µL) as dispersive solvent and Triton X-100 (200 µL) as anti-sticking agent were used. After the extraction of the Hg(II) complex (Hg(II):q-Fe(II)-Pc) into thin droplets of ionic liquid, the sample was centrifuged for 4 min at 2000 rpm. The upper aqueous phase was removed and the residue diluted to 250 µL with methanol and transferred to a 250 µL cell for spectrophotometric detection at 280 nm. The linear range of the method is 0.05–1 µg/mL. The limits of detection and quantification is 0.01 and 0.03 µg/mL, respectively. The RSD for the developed method was calculated as 0.78% at 0.50 µg/mL Hg(II). 相似文献