全文获取类型
收费全文 | 956篇 |
免费 | 9篇 |
国内免费 | 6篇 |
专业分类
化学 | 641篇 |
晶体学 | 14篇 |
力学 | 13篇 |
数学 | 52篇 |
物理学 | 251篇 |
出版年
2022年 | 4篇 |
2020年 | 5篇 |
2019年 | 12篇 |
2018年 | 15篇 |
2017年 | 7篇 |
2016年 | 7篇 |
2015年 | 10篇 |
2014年 | 20篇 |
2013年 | 41篇 |
2012年 | 33篇 |
2011年 | 71篇 |
2010年 | 30篇 |
2009年 | 22篇 |
2008年 | 61篇 |
2007年 | 46篇 |
2006年 | 61篇 |
2005年 | 48篇 |
2004年 | 42篇 |
2003年 | 36篇 |
2002年 | 39篇 |
2001年 | 30篇 |
2000年 | 17篇 |
1999年 | 10篇 |
1998年 | 7篇 |
1997年 | 7篇 |
1996年 | 7篇 |
1995年 | 11篇 |
1994年 | 19篇 |
1993年 | 14篇 |
1992年 | 15篇 |
1991年 | 15篇 |
1990年 | 13篇 |
1989年 | 11篇 |
1988年 | 7篇 |
1987年 | 9篇 |
1986年 | 19篇 |
1985年 | 17篇 |
1984年 | 15篇 |
1983年 | 10篇 |
1982年 | 13篇 |
1981年 | 12篇 |
1980年 | 11篇 |
1979年 | 6篇 |
1978年 | 7篇 |
1977年 | 12篇 |
1976年 | 8篇 |
1975年 | 4篇 |
1974年 | 6篇 |
1973年 | 8篇 |
1972年 | 4篇 |
排序方式: 共有971条查询结果,搜索用时 10 毫秒
81.
82.
83.
84.
H. Kageyama K. Onizuka Y. Ueda M. Nohara H. Suzuki H. Takagi 《Journal of Experimental and Theoretical Physics》2000,90(1):129-132
The specific heat of a two-dimensional spin gap system SrCu2(BO3)2 realizing the Shastry-Suther-land model was measured between 1.3 and 25 K under various magnetic fields up to 12 T. The analysis based on an isolated dimer model in a low temperature region revealed that the value of the spin gap at zero field is Δ = 34.4 K. It turned out that Δ decreases in proportion to H due to the Zeeman splitting of the excited triplet levels. This simplest model, however, fails to reproduce the result in a high-temperature region, suggesting rather strong spin-spin correlation of the system. 相似文献
85.
Ken Naitoh Yasuo Takagi Kunio Kuwahara Egon Krause Katsuya Ishii 《Fluid Dynamics Research》1990,6(5-6):277-294
The transition to turbulent flow in the compression stage of a reciprocating engine is studied by obtaining the finite-difference numerical solutions to the governing Navier-Stokes equations without using explicit turbulence models. A computational method is developed under the assumption that the flow is in a low-subsonic regime with strong compression. The numerical method is a simple extension of the well known MAC method. Computations were performed for three different chamber geometries at the engine speed of 1400 rpm. The results of the computations clearly demonstrate the transient process in which large tumbling vortices break down into smaller ones near the end of the compression process. The transition process is also caught experimentally by using Mach-Zehnder interferometry. 相似文献
86.
87.
88.
A new route for (2S,3S,4S)-form, the physiologically active stereoisomer of dehydroxymethylepoxyquinomicin (DHMEQ), a potent NF-κB inhibitor, was established by chemoenzymatic approach. Elaboration on the asymmetric epoxidation of a p-benzoquinone monoketal with benzylcinchonidinium tert-butylhydroperoxide yielded an epoxyenone, in 79.8% ee and 57% yield in reproducible manner. By way of the transformation of this key intermediate to enantiomerically pure (2S,3S,4S)-DHMEQ, the contaminating undesired enantiomer could be effectively removed by applying Burkholderia cepacia lipase-catalyzed hydrolysis of diacylated precursor. The above integrated combination of chemical asymmetric synthesis and enzyme-catalyzed kinetic resolution enabled us to prepare active DHMEQ in a large-scale. 相似文献
89.
Chang KS Yoshioka T Kanezashi M Tsuru T Tung KL 《Chemical communications (Cambridge, England)》2010,46(48):9140-9142
A new molecular dynamics simulation method was successfully applied to construct a homogeneous organic-inorganic hybrid silica membrane using the hybrid-pcff (h-pcff) potential function. Analysis suggested that the hybrid BTESE silica membrane provided a looser network and larger cavity size for the enhancement of gas permeability and selectivity. 相似文献
90.
Toshinori Taishi Hideaki Ise Yu Murao Takayuki Osawa Masashi Suezawa Yuki Tokumoto Yutaka Ohno Keigo Hoshikawa Ichiro Yonenaga 《Journal of Crystal Growth》2010,312(19):2783-2787
Oxygen-containing germanium (Ge) single crystals with low density of grown-in dislocations were grown by the Czochralski (CZ) technique from a Ge melt, both with and without a covering by boron oxide (B2O3) liquid. Interstitially dissolved oxygen concentrations in the crystals were determined by the absorption peak at 855 cm−1 in the infrared absorption spectra at room temperature. It was found that oxygen concentration in a Ge crystal grown from melt partially or fully covered with B2O3 liquid was about 1016 cm−3 and was almost the same as that in a Ge crystal grown without B2O3. Oxygen concentration in a Ge crystal was enhanced to be greater than 1017 cm−3 by growing a crystal from a melt fully covered with B2O3; with the addition of germanium oxide powder, the maximum oxygen concentration achieved was 5.5×1017 cm−3. The effective segregation coefficients of oxygen in the present Ge crystal growth were roughly estimated to be between 1.0 and 1.4. 相似文献