全文获取类型
收费全文 | 1232篇 |
免费 | 71篇 |
国内免费 | 7篇 |
专业分类
化学 | 1051篇 |
晶体学 | 13篇 |
力学 | 12篇 |
数学 | 70篇 |
物理学 | 164篇 |
出版年
2023年 | 6篇 |
2022年 | 18篇 |
2021年 | 18篇 |
2020年 | 24篇 |
2019年 | 41篇 |
2018年 | 16篇 |
2017年 | 15篇 |
2016年 | 45篇 |
2015年 | 35篇 |
2014年 | 44篇 |
2013年 | 82篇 |
2012年 | 97篇 |
2011年 | 87篇 |
2010年 | 64篇 |
2009年 | 60篇 |
2008年 | 79篇 |
2007年 | 72篇 |
2006年 | 70篇 |
2005年 | 59篇 |
2004年 | 62篇 |
2003年 | 43篇 |
2002年 | 38篇 |
2001年 | 13篇 |
2000年 | 15篇 |
1999年 | 13篇 |
1998年 | 11篇 |
1997年 | 5篇 |
1996年 | 18篇 |
1995年 | 9篇 |
1994年 | 12篇 |
1993年 | 8篇 |
1992年 | 7篇 |
1991年 | 6篇 |
1990年 | 7篇 |
1989年 | 10篇 |
1988年 | 6篇 |
1987年 | 12篇 |
1986年 | 12篇 |
1985年 | 6篇 |
1984年 | 14篇 |
1982年 | 6篇 |
1981年 | 7篇 |
1980年 | 8篇 |
1978年 | 5篇 |
1977年 | 4篇 |
1976年 | 3篇 |
1975年 | 5篇 |
1974年 | 4篇 |
1970年 | 2篇 |
1967年 | 3篇 |
排序方式: 共有1310条查询结果,搜索用时 8 毫秒
101.
Kazuhiro Yamamoto Haruhiko Ito Kouki Totsuka Tomohiro Sato 《Optics Communications》2006,265(2):692-695
We consider a new scheme of optically ionizing atoms with 10-nm-order spatial resolution. In this method, two-color near-field lights are generated on a narrow slit illuminated by two-color evanescent lights via total-internal reflection of two-wavelength light beams. In order to illustrate the feasibility, we first obtain the ionization cross section from two-step photionization of cold Rb atoms by two-color evanescent lights on a plane surface of a prism. Then, we numerically estimate the ionization efficiency as a function of the slit width using Bethe formula. The scheme is useful for detecting ground-state atoms under less perturbation by scattered light. 相似文献
102.
103.
104.
105.
Shin-ichi Nakakita Kayo Hasehira Tomohiro Hosokawa Masaaki Tokuda Ken Izumori Kaoru Takegawa Jun Hirabayashi 《Journal of chromatography. A》2009,1216(26):5112-5115
A rare sugar is considered to be a monosaccharide rarely found in nature. To investigate their natural distribution and biological roles, a robust analytical system must be used to isolate, identify, and quantify them. Herein, we report the development of such a system that can specifically quantify and chromatographically separate four aldopentoses and eight aldohexoses tagged with 2-aminopyridine. Purified monosaccharides derivatized with a pyridylamino moiety (PA–monosaccharides) are first chromatographed over a high-performance anion-exchange resin. But, because two of the PA–aldohexoses used in this study, PA–talose and PA–idose, co-elute with the common saccharides, PA–glucose and PA–mannose, respectively, a second chromatographic step, reversed-phase high-performance liquid chromatography, is used to completely separate them. Thus, as shown by the results of this study, chromatographic separation of PA–monosaccharides is achievable and provides a quantitative measurement of common and rare isomeric aldopentoses and aldohexoses. 相似文献
106.
107.
Shigenori Kashimura Yoshiyuki Tane Yoshihiro Murai Tomohiro Nakai Ryuich Hirose 《Tetrahedron letters》2008,49(2):269-271
Reduction of dichlorosilanes with Mg metal in the presence of Lewis acid and LiCl was found to be the highly practical method for the synthesis of polysilanes. 相似文献
108.
Kenji Miyatake Tomohiro Yasuda Masahiro Watanabe 《Journal of polymer science. Part A, Polymer chemistry》2008,46(13):4469-4478
A series of sulfonated polyimide (SPI) copolymers containing methyl, methoxy, or fluorine groups were synthesized to elucidate the substituents effect on their proton conducting properties as well as thermal, hydrolytic, and oxidative stability for polymer electrolyte membrane fuel cell applications. SPIs of high molecular weight (Mw > 200 kDa, Mn > 80 kDa) along with the ion exchange capacity (IEC) varying between 1.34 and 1.91 mequiv/g were obtained, which gave tough, ductile, and flexible membranes by solution casting. The thermal properties of the SPIs were dominated by the electronic structure of the sulfonated aromatic rings. The electron‐donating methyl groups lowered the thermal decomposition temperature. The hydrolytic and oxidative stability was roughly in the order of IEC (the higher IEC membranes were less stable). Fluorine groups, either as ? F or ? CF3, had negative effect on the hydrolytic and oxidative stability. In the water uptake and proton conductivity, hydrophobic components are rather more influential than the substituents. It was found out that the SPI(5, 8, 0.7) containing bis(phenoxy)biphenylene sulfone moieties as a rigid hydrophobic component showed the best balanced properties in terms of the stability and the proton conductivity for its rather low IEC. © 2008 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 4469–4478, 2008 相似文献
109.
A macrocyclic host molecule that comprised two different rotating modules, cerium(IV) bis(porphyrinate)s and ferrocenyl rotating units, exhibiting contraction/expansion motion was synthesized, which can be regarded as a prototype of artificial molecular spring driven by cooperative guest binding in 1:6 stoichiometry. 相似文献
110.
Tomohiro Narukawa Takayoshi Kuroiwa Izumi Narushima Koichi Chiba 《Analytical sciences》2008,24(3):355-360
The sensitivity of graphite furnace atomic absorption spectrometry (GFAAS) to arsenobetaine (AB) was 1.3-times higher than to inorganic As. In order to understand the mechanism underlying this observation, the atomization processes for both chemical species were investigated in terms of the enthalpy change (DeltaH) during the atomization process in GFAAS. The enthalpy change of AB was slightly lower than that of inorganic As, which suggested that AB was atomized more efficiently than was inorganic As. Moreover, it was observed that some co-existing organic materials enhanced the analytical sensitivity of inorganic As. The sensitivity difference between inorganic As and AB depended upon the mechanisms of their atomization processes. 相似文献