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排序方式: 共有236条查询结果,搜索用时 15 毫秒
31.
Zakaria Elaoud Slaheddine Kamoun Joel Jaud Tahar Mhiri 《Journal of chemical crystallography》1998,28(4):313-315
The salt N-benzylmethylammonium dihydrogenmonophosphate monohydrate is monoclinic with the following unit cell dimensions: a = 6.356(1)Å, b = 8.385(7)Å, c = 11.472(5)Å, = 104.32(1)°, space group P21 with Z = 2. The structure consists of infinite parallel two-dimensional [110] planes built of mutually connected ions and water molecules by strong O–H···O and N–H···O hydrogen bonding. There are no contacts other than normal van der Waals interactions between the layers. 相似文献
32.
Elektorowicz M El-Sadi H Lin J Ayadat T 《Journal of colloid and interface science》2007,309(2):445-452
Clay soils have specific properties that cause difficulty in the assessment and remediation of contaminated sites. Furthermore, polyaromatic hydrocarbons, when present in soil, are difficult to extract due to their nonpolar, high molecular weight characterization. In this study, the supercritical fluid (carbon dioxide) extraction (SFE) technique, with and without methanol modifier, was used for removal of PAHs (phenanthrene) from kaolinite, illite, and montmorillonite soils. The impact of SFE parameters (fluid pressure, fluid temperature, and time), and of clay properties (such as clay minerals content, initial moisture content, soil porosity or equivalent pores size, clay surface area, cation-exchange capacity, and clay-swelling index) on the removal efficiency of PAHs from clayey soils were investigated. The results of this investigation were used to develop a semi-empirical correlation between the recovery (i.e. the extraction efficiency) at any time and above mentioned parameters and properties. 相似文献
33.
Effect of thermooxidation on tinuvin 783 in LDPE films: Characterization by UV and ftir spectroscopy
The effect of thermooxidation on Tinuvin 783 which is a hindered amine light stabilizer in LDPE films has been investigated by UV and FTIR spectroscopy. Initially, a standard curve describing the variation of the concentration of Tinuvin 783 in LDPE films was plotted using the method of integration of the band area. The relation obtained was: band area = 19.6249 × [Tinuvin 783]. This equation was then applied to measure the variation of the concentration of Tinuvin 783 in the 0.2%wt stabilized samples which have undergone thermooxidation at 90°C for 98 days. The results showed a considerable decrease in the concentration of Tinuvin 783 by 35% during the first 30 days due to probably the formation of nitroxyl radicals. After this, the concentration was observed to be unchanged and may correspond to the phase of nitroxyl radical regeneration. On the other hand, no chemical change in the stabilized LDPE films was observed by FTIR spectroscopy at 90°C during 98 days while the band characteristic of ketone groups (1720 cm−1) was detected for the unstabilized samples after only 11 days. (LDPE: low density polyethylene; HALS: hindered amine light stabilizer) 相似文献
34.
In this work, an experimental study on the chemical etching reaction of polycrystalline p-type 6H-SiC was carried out in HF/Na2O2 solutions. The morphology of the etched surface was examined with varying Na2O2 concentration, etching time, agitation speed and temperature. The surfaces of the etched samples were analyzed using scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) Fourier transform infrared spectroscopy (FT-IR) and photoluminescence. The surface morphology of samples etched in HF/Na2O2 is shown to depend on the solution composition and bath temperature. The investigation of the HF/Na2O2 solutions on 6H-SiC surface shows that as Na2O2 concentration increases, the etch rate increases to reach a maximum value at about 0.5 M and then decreases. A similar behaviour has been observed when temperature of the solution is increased. The maximum etch rate is found for 80 °C. In addition, a new polishing etching solution of 6H-SiC has been developed. This result is very interesting since to date no chemical polishing solution has been developed on the material. 相似文献
35.
Kamel Abderrazak Wassim Kriaa Wacef Ben Salem Hatem Mhiri Georges Lepalec Michel Autric 《Optics & Laser Technology》2009,41(4):470-480
A pulse laser (Nd:YAG) interaction with an AZ91 magnesium alloy has been experimentally and numerically studied. A two-dimensional (2D) axisymmetric model of a molten pool created by a laser heat source has been developed. The elaborated model solves the coupled equations of a laminar fluid flow and heat transfer to demonstrate the flow behavior in the pool. This model takes into account the coupled effects of buoyancy and Marangoni forces, the thermophysic variation properties with temperature, and the radiation and convection heat losses. Concerning numerical results, the molten temperature distribution, velocity field and molten shape were discussed. It was noted that the Marangoni flow significantly alters the characteristics of the thawing and solidifying processes, and makes the molten pool wider and shallower. On the other hand, the experimental results showed that the material thermal properties have significant effects on the transport phenomena which takes place in the molten pool, and consequently on the formation as well as the shape of the pool. Finally, a comparison between the numerical and experimental results exhibited a good agreement. 相似文献
36.
Walid Rekik Houcine Naïli Tahar Mhiri 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(4):i50-i52
Potassium gadolinium polyphosphate, KGd(PO3)4, was synthesized using the flux method. The atomic arrangement consists of an infinite long‐chain polyphosphate organization. Two types of chains, with a period of eight PO4 tetrahedra, run along the [101] direction. The Gd atoms have an eightfold coordination, while the K atoms have nine O‐atom neighbours. 相似文献
37.
A Raman study of K3H(SO4)2 as a function of temperature reveals that this compound undergoes a phase transition at Tc = 483 K prior to the decomposition at 508 K. 相似文献
38.
A New Higher Order Shear Deformation Model for Static Behavior of Functionally Graded Plates
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Tahar Hassaine Daouadji Abdelouahed Tounsi & El Abbes Adda Bedia 《advances in applied mathematics and mechanics.》2013,5(3):351-364
In this paper, a new displacement based high-order shear deformation theory is introduced
for the static response of functionally graded plate. Unlike any other theory, the number
of unknown functions involved is only four, as against five in case of other shear deformation
theories. The theory presented is variationally consistent, has strong similarity with
classical plate theory in many aspects, does not require shear correction factor, and
gives rise to transverse shear stress variation such that the transverse shear stresses
vary parabolically across the thickness satisfying shear stress free surface conditions.
The mechanical properties of the plate are assumed to vary continuously in the thickness
direction by a simple power-law distribution in terms of the volume fractions of the
constituents. Numerical illustrations concerned flexural behavior of FG plates with
Metal-Ceramic composition. Parametric studies are performed for varying ceramic volume
fraction, volume fraction profiles, aspect ratios and length to thickness ratios. The
validity of the present theory is investigated by comparing some of the present results
with those of the classical, the first-order and the other higher-order theories. It
can be concluded that the proposed theory is accurate and simple in solving the static
behavior of functionally graded plates. 相似文献
39.
A. Radhouane N. Mahjoub Saïd H. Mhiri H. Bournot G. Le Palec 《Heat and Mass Transfer》2014,50(2):253-274
The present paper examines the common configuration of “twin inclined jets in crossflow” that is widely present in several industrial and academic, small and large-scale applications. It is particularly found in aerodynamic and engineering applications like VTOL aircrafts, the combustion mixing process and other chemical chambers. It can also be found in some domestic applications like chimney stacks or water discharge piping systems in rivers and seas. The twin jets considered in this work are elliptic as inclined with a 60° angle and arranged inline with the oncoming crossflow according to a jet spacing of three diameters. They are examined experimentally in a wind tunnel. The corresponding data is tracked by means of the particle image velocimetry technique in order to obtain the different instantaneous and mean dynamic features (different velocity components, vortices, etc.). The same case is numerically reproduced by the resolution of the Navier–Stokes equations by means of the finite volume method together with the Reynolds stress model second order turbulent closure model. A non-uniform mesh system tightened close to the emitting nozzles is also adopted. The comparison of the measured and calculated data gave a satisfying agreement. Further assumptions are adopted later in order to improve the examined configuration: a non-reactive fume is injected within the discharged jets and the jets’ temperature is varied with reference to a constant mainstream temperature. Our aim is to evaluate precisely the impact of this temperature difference on the flow field, particularly on the dynamics of the jets in a crossflow. This parameter, namely the temperature difference, proved mainly to accelerate the discharged jet plumes in the direction of the main flow, which enhanced the mixing, particularly in the longitudinal direction. The mixing in the other directions was also increased due to the weaker density of the jets, which enabled them to progress relatively unhindered before undergoing the impact of the crossflow. 相似文献
40.
Ahmed El Kharroubi Abdelhak Yaacoubi Abdelghani Ben Tahar Kawtar Bichard 《Queueing Systems》2012,70(4):299-337
In this paper we consider the variational problem in the non-negative orthant of ℝ3. The solution of this problem gives the large deviation rate function for the stationary distribution of an SRBM (Semimartingal
Reflecting Brownian Motion). Avram, Dai and Hasenbein (Queueing Syst. 37, 259–289, 2001) provided an explicit solution of this problem in the non-negative quadrant. Building on this work, we characterize reflective
faces of the non-negative orthant of ℝ
d
, we construct boundary influence cones and we provide an explicit solution of several constrained variational problems in ℝ3. Moreover, we give conditions under which certain spiraling paths to a point on an axis have a cost which is strictly less
than the cost of every direct path and path with two pieces. 相似文献