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11.
Imen Ben Atitallah Georgia Antonopoulou Ioanna Ntaikou Amaia Soto Beobide Vassilios Dracopoulos Tahar Mechichi Gerasimos Lyberatos 《Molecules (Basel, Switzerland)》2022,27(4)
The effect of different pretreatment approaches based on alkali (NaOH)/hydrogen peroxide (H2O2) on willow sawdust (WS) biomass, in terms of delignification efficiency, structural changes of lignocellulose and subsequent fermentation toward ethanol, was investigated. Bioethanol production was carried out using the conventional yeast Saccharomyces cerevisiae, as well as three non-conventional yeasts strains, i.e., Pichia stipitis, Pachysolen tannophilus, Wickerhamomyces anomalus X19, separately and in co-cultures. The experimental results showed that a two-stage pretreatment approach (NaOH (0.5% w/v) for 24 h and H2O2 (0.5% v/v) for 24 h) led to higher delignification (38.3 ± 0.1%) and saccharification efficiency (31.7 ± 0.3%) and higher ethanol concentration and yield. Monocultures of S. cerevisiae or W. anomalus X19 and co-cultures with P. stipitis exhibited ethanol yields in the range of 11.67 ± 0.21 to 13.81 ± 0.20 g/100 g total solids (TS). When WS was subjected to H2O2 (0.5% v/v) alone for 24 h, the lowest ethanol yields were observed for all yeast strains, due to the minor impact of this treatment on the main chemical and structural WS characteristics. In order to decide which is the best pretreatment approach, a detailed techno-economical assessment is needed, which will take into account the ethanol yields and the minimum processing cost. 相似文献
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13.
The synthesis and crystal structure of a novel hydrate of lithium cyclohexaphosphate are reported. Li6P6O18·10H2O crystallizes in the space group C2/c with a = 15.113(5), b = 12.006(2), c = 15.892(2) Å, = 122.85(2)°, and Z = 4. The structure consists of P6O18 ring layers stacked along the c direction in between which are located the lithiumions and water molecules. Two LiO4 tetrahedra share common edges with LiO5 pseudosquare pyramids to form two independant Li3O9 units. About 50% of the water molecules have fractional occupancy rates and form fragments of molecules. A linear relationship is established between the relative cell volume V/Z and the hydration degree, n, for all the known hydrates: Li6P6O18·nH2O. 相似文献
14.
Ayad T Faugeroux V Génisson Y André C Baltas M Gorrichon L 《The Journal of organic chemistry》2004,69(25):8775-8779
We developed a stereocontrolled route allowing potential access to the eight isomers of 4-benzylaminohex-5-ene-1,2,3-triol in two or four steps and ca. 50% yield from readily available chiral nonracemic cis- or trans-alpha,beta-epoxyimine precursors. A new (NH(4))(2)CO(3)-based carboxylation/intramolecular cyclization sequence allowed regio- and stereocontrolled C-3 epoxide opening while neat C-2 hydrolysis was ensured by simple aqueous acidic treatment. 相似文献
15.
The X-ray diffraction, vibrational and impedance spectroscopy studies of (Cs)0.26(Rb)0.74H(SO4)0.89(SeO4)0.11 (CsRbHSSe) new solid solution are presented. The title compound undergo a superionic phase transition (SPT) at This transition was confirmed by an abrupt increase of conductivity. The bulk impedance parameters of CsRbHSSe, RbH(SO4)0.81(SeO4)0.19 (RbHSSe) and CsH(SO4)0.76(SeO4)0.24 (CsHSSe) were determined from an analysis of AC conductivity data measured in a wide temperature range. The charge carriers concentration in the samples investigated has been evaluated using the Almond-West formalism and shown to be independent of temperature. 相似文献
16.
The effects of temperature and concentration on the reduced electrical conductivity of solutions of poly-(sodium styrene sulfonate) (PSSNa) in N,N-dimethylformamide + water were examined at different temperatures between 20 and 60°C and concentrations levels between 0.1 and 1 g/l. The effects of temperature were described by an Arrhenius-type equation. The intrinsic conductivities [σ] and the Huggins constant khσ of PSSNa were calculated and studied. Then, dln[σ]/d(1/T) was calculated as the indices for chain ?exibility and molecule conformation, respectively.These results showed that the intrinsic electrical conductivities decreased linearly with increasing temperature, for all concentrations of PSSNa. 相似文献
17.
Abdel-Ghani Boudjahem Tahar Mokrane Affef Redjel Mohammed M. Bettahar 《Comptes Rendus Chimie》2010,13(12):1433-1439
Palladium catalysts (1–10 wt.% Pd) supported on silica were prepared by hydrazine reduction of palladium chloride at room temperature. They were characterized by XRD, TEM, EDX, H2-adsorption, and H2-TPD and tested in the gas phase hydrogenation of benzene in the temperature range 75–250 °C. A conventional catalyst (1 wt.% Pd) obtained by calcination then hydrogen reduction of the same metal precursor was studied for comparison. Metal particles with a size range 6.8–28.4 nm were obtained. Dispersion, hydrogen storage and activity in benzene hydrogenation increased with decreasing particle size. In comparison, the classical catalyst was found much more dispersed (mean particle size of 1.6 nm) and more active (specific rate 1.6–3.7 times higher) than the homolog hydrazine catalyst. However, unexpectedly, turnover frequency (TOF) calculations indicated a greater reactivity of the metal surface atoms for the hydrazine catalyst. It also stored more hydrogen. These contrasting results are discussed in relation with the metal particle morphology. 相似文献
18.
Cyrielle Pautigny Charlotte Debouit Philippe Vayron Tahar Ayad Virgine Ratovelomanana-Vidal 《Tetrahedron: Asymmetry》2010,21(11-12):1382-1388
The asymmetric hydrogenation of various trisubstituted enamides derived from 2-tetralones under mild reaction conditions using Ru-SYNPHOS catalysts is reported. This practical and clean method gives access to several chiral 2-aminotetralins derivatives in high isolated yields and enantiomeric excesses up to 95% depending on the substitution pattern of the aromatic ring and the nature of the amide moiety. In addition, the usefulness of the current method is demonstrated via a practical synthetic approach to the enantiomerically pure SR58611A compound, a potent and selective β3-adrenergic receptor agonist. 相似文献
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20.
The salt 4-benzyl pyridinium dihydrogenmonophosphate is monoclinic P21/c with the following unit cell dimensions: ; ; ; and β=97.328(11). Also, , Dx=1.403, , F(000)=560; ; and R=0.0495 and Rw=0.0964 for 3733 independent reflections. The structure consists of infinite parallel two-dimensional planes built of H2PO4− anions and C6H5CH2C5H4NH+ cations mutually connected by strong O-H ?O and N-H ?O hydrogen bonding. There are no contacts other than the normal Van der Waals interactions between the layers. The conductivity relaxation parameters associated with some H+ conduction have been determined from an analysis of the spectrum measured in a wide temperature range. 相似文献