Homoannular disubstituted ruthenocenes containing a trifluoromethyl(tetramethyl)cyclopentadienyl ligand

The reaction of the divalent ruthenium complexes [Cp^FRuCl]_n and [Cp^FRu(MeCN)₃]PF₆ with substituted pentafulvenes 1,2-(Me₂NCH)(CO₂Et)C₅H₃ and 1,3-(Me₂NCH)(CO₂Et)- C₅H₃ followed by hydrolysis affords new homoannular disubstituted ruthenocenes {1,2- (CO₂Et)(CHO)C₅H₃}RuCp^F and {1,3-(CO₂Et)(CHO)C₅H₃}RuCp^F (Cp^F = C₅Me₄CF₃), re- spectively.     

Synthesis and Crystal Structures of Cs<Subscript>2</Subscript>Mo<Subscript>4</Subscript>O<Subscript>13</Subscript> and Cs<Subscript>4</Subscript>Mo<Subscript>8</Subscript>O<Subscript>26</Subscript>

Polymolybdates of the composition Cs₂Mo₄O₁₃ (1) and Cs₄Mo₈O₂₆ · 4H₂O (2) are synthesized under hydrothermal conditions from a mixture containing (NH₄)₆Mo₇O₂₄ · 4H₂O and CsCl at pH 2.5 and 3.6, respectively.     

N-环钯化二茂铁衍生物的合成和应用（英文）

近年研究表明二茂铁的环钯化衍生物被广泛地应用于各类偶联反应中,比如Heck反应、Suzuki反应、aza-Claisen重排反应等.主要综述了含氮导向基的二茂铁衍生物的环钯化反应,包括通过不对称诱导或拆分手段合成具有平面手性环钯化合物,基于环金属化反应1,1'-取代二茂铁钯化物的合成,以及其在催化反应的应用.     

On some generalizations of the factorization method

The classical factorization method reduces the study of a system of ordinary differential equations U_t=[U₊, U] to solving algebraic equations. Here U(t) belongs to a Lie algebra which is the direct sum of its subalgebras and , where “+” signifies the projection on . We generalize this method to the case . The corresponding quadratic systems are reducible to a linear system with variable coefficients. It is shown that the generalized version of the factorization method can also be applied to Liouville equation-type systems of partial differential equations. Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 110, No. 3, pp. 339–350, March, 1997.     

Cyclization of N-allylthiourea derivatives by the action ofα-chloronitrosoalkanes

A convenient method is proposed for obtaining difficultly available derivatives of 2-amino-5-chloromethyl-2-thiazoline by the cyclization of N-allythioureas under the action of-chloronitrosoalkanes. It is assumed that the reaction proceeds as a halogenophilic process leading to the intermediate formamidinesulfenyl chloride which is rapidly and selectively cyclized with the formation of 2-amino-2-thiazoline derivatives.Institute of Physiologically Active Substances, Russian Academy of Sciences, Chernogolovka 142432, Russia. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 381–384, March, 1998.     

Discrete model of a dynamo with diffusion

A model of magnetic field generation by the turbulent motions of a highly conducting fluid is constructed. It is assumed that the field is generated in individual cells of space in a statistically independent manner. A coupling between the cells is realized by magnetic diffusion. The rates of growth of the field and its moments are calculated. The field distribution generated by this mechanism possesses an intermittent nature in both time and space.     

Neutron to proton cross section ratios in neutrino and antineutrino charged current reactions forE ν<30 GeV

Using the freon filled bubble chamber SKAT at the Serpukhov accelerator we study event charge distributions in neutrino and antineutrino charged current reactions in the (anti)neutrino energy region from 3–30 GeV. We derive from the data the total cross section ratios of reactions on neutrons to reactions on protonsR _ν=2.24±0.18 and \(R_{\bar v} = 0.43\) in agreement with the predictions of the quark parton model. These values agree also with other experimental results at different energies. For neutrino reactions we study additionally the differential distributions in Bjorken variablesx andy.     

Constant loss in Brillouin spectra of polymers

The polarized (VV) and depolarized (VH) light scattering spectra of polyisobutylene, poly(methyl methacrylate), and glycerol were measured in the gigahertz frequency range at temperatures below and above the glass transition. Both VV and VH spectra exhibit a significant constant loss contribution that appears as a frequency‐independent imaginary part of the susceptibility spectrum. Existence of the frequency‐independent susceptibility in VV spectra below the Brillouin lines suggests that the constant loss also appears in mechanical relaxation in the gigahertz frequency range. Intensity of the constant loss increases strongly with temperature. Analysis of the spectra and literature data suggests that the constant loss can be general for many glass‐forming systems, but it is hidden in many cases by other relaxation contributions. © 2001 John Wiley & Sons, Inc. J Polym Sci Part B: Polym Phys 40: 201–209, 2002