SYNTHESIS OF LIGHT OLEFINS FROM SYNGAS VIA DIMETHYLETHR——A NEW TECHNIQUE PROCESS

A new route named as SDTO method for the synthesis of lightolefins from syngas has been proposed.That is to convert syngas todimethylether and then to convert dimethylether to light olefins.The catalystsfor the two conversion reactions have been developed.For the first reaction,the catulySt was synthesized by the combination of methanol synthesis catalystwith γ-Al_2O_3or zeolites which possesses both metallic and acidic functions.Thecatalyst for the second reaction was modified SAPO-34 molecular sieve.Thevariables of the reactions have also been investigated.The results from theserial connection of the two conversion steps without any separation show thatthe yield of C_2~-C_4~- olefins Could be>100g/(m~3 syngas).     

随机删失下乘积限过程和累积失效率过程振动模的局部渐近性

在随机删失下研究了乘积限过程和累积失效率过程的振动模的局部性质 .给出了这两个过程的振动模的重对数律 ,并应用这些结果得到了几种核密度估计和Bahadur-Kiefer过程的精确收敛速度     

混合曲率曲面变形方程的Tricomi问题——Ⅱ.解的存在性

本文在很弱的条件下,证明对混合曲率曲面无穷小变形方程的Tricomi问题,存在L₂弱解和H₁强解。     

Spectral Representation Theory for Dielectric Behavior of Nonspherical Cell Suspensions

Recent experiments revealed that the dielectric dispersion spectrum of fission yeast cells in a suspension was mainly composed of two sub-dispersions. The low-frequency sub-dispersion depended on the cell length, while the high-frequency one was independent of it. The cell shape effect was simulated by an ellipsoidal cell model but the comparison between theory and experiment was far from being satisfactory. Prompted by the discrepancy, we proposed the use of spectral representation to analyze more realistic cell models. We adopted a shell-spheroidal model to analyze the effects of the cell membrane. It is found that the dielectric property of the cell membrane has only a minor effect on the dispersion magnitude ratio and the characteristic frequency ratio. We further included the effect of rotation of dipole induced by an external electric field, and solved the dipole-rotation spheroidal model in the spectral representation.Good agreement between theory and experiment has been obtained.     

低速二维流动的粒子仿真研究

本文运用信息保存法对低速二维的流动现象进行模拟，考察了低速条件下的有限平板绕流以及微槽道气体流动问题。研究表明：在对低速流动的模拟过程中，运用IP法在能够获得较好的结果的同时，具有比DSMC方法更高的计算效率。     

晶格反演的嵌入原子法模型及其应用

讨论一种基于晶格反演的嵌入原子法模型 ,其特点是未知函数的参数化是对原子间对势和单原子电荷密度函数的晶格和 ,而不是对原子间对势和单个原子的电荷密度函数进行的 ,其最大优点在于待定参数可以用物理输入解析地表达出来 ,而不是像大多数埋入原子法模型中那样通过拟合来确定 .给出了它在计算点缺陷 (自间隙杂质和空位原子 )和晶体表面形成能方面的应用 .     

PHASE INVERSION AND ITS MECHANICAL MODEL STUDIES FOR THE TWO-PHASE POLYMER BLEND SYSTEMS (Ⅱ)——DYNAMIC VISCOELASTIC RESPONSE

The dynamic viscoelastic response of the two-phase polymer blend systems shows the characteristics of the thermorheologically complex materials. In this paper theoretical equations for describing the dynamic viscoelastic response of such polymer blend systems have been established by means of the mechanical modeling technique. The dynamic viscoelastic response of the blend systems at any blend composition can be predicted theoretically by using the equations established, provided that the dynamic viscoelastic response of the two pure components and the mechanical model parameters are known in advance. Thus, we provide an effective method for studying the dynamic mechanical properties and the molecular relaxation characteristics of the two-phase polymer blend systems.     

APPLICATION OF MSW-X_α METHOD WITH OVERLAPPING ATOMIC-SPHERE TO IONIZATION POTENTIALS FOR SOME PLANAR ORGANIC MOLECULES

Application of multiple scattered-wave X_α method with overlapping atomic-sphere to ionization potentials is reported for benzene, pyridine, pyrazine, pyrrole and imidazole. The calculated results show that the orbital charges in the intersphere region are non-negative and the energy levels get improvements in orderings.