纳米银的制备及其应用

本文采用紫外光化学法制备了纳米银胶,通过观察发现,在混合溶液搅拌的过程中溶液颜色没有任何变化,在紫外灯照射的过程中混合溶液经历了一系列的颜色变化。通过研究硝酸银的浓度对银胶吸收光谱的影响,发现随着硝酸银浓度的增加,银胶的吸收峰先红移然后蓝移,即随着硝酸银溶液浓度的增大,银粒子尺寸最终将减小。最后通过霉菌实验研究了纳米银的应用,发现纳米银具有较强的杀菌作用。     

Influence of the ZSM-5 Support Acidity on the Catalytic Performance of Pd/ZSM-5 in Lean Methane Oxidation

Although zeolites are characterized by their special acidic properties, there is still no clear consensus on the effect of zeolite support acidity on the catalytic activity of supported Pd catalyst in methane oxidation. Herein, a series of Pd/H-ZSM-5 and Pd/Silicalite-1 catalysts was prepared by the deposition-precipitation method and used in lean methane oxidation. The effect of ZSM-5 support acidity on the catalytic performance of Pd/ZSM-5 was investigated. The results indicate that with the decrease of Si/Al ratio(x), viz., the increase of acid sites in H-ZSM-5(x), the catalytic activity of Pd/H-ZSM-5(x) increases substantially; the activity of various catalysts in the lean methane oxidation decreases in the order of Pd/H-ZSM-5(28)>Pd/H-ZSM-5(48)>Pd/H-ZSM-5(88)>Pd/H-ZSM-5(204)>Pd/Silicalite-1. Furthermore, various characterization measures reveal that the catalytic activity of Pd/H-ZSM-5(x) in lean methane oxidation is mainly related to the Lewis acid sites in the H-ZSM-5 support, whereas less relevant to the Brønsted acid sites. The abundant Lewis acid sites in H-ZSM-5 are capable to enhance the interaction between the Pd species and H-ZSM-5 support, which can inhibit the agglomeration of Pd particles and improve the dispersion of Pd species, and thus boost the catalytic activity of Pd/H-ZSM-5 in methane oxidation.     

RF Ion Beam Sources Used in Etching

Ion beam technology is used widely in many fields such as electric, material, optics, medicine, biology and so on. At the same time, it brings some huge technological effects and economical benefits, especially for the optical applocations. According for the technology, the properties of high accuarate spectral analyzer also can be improved by manufacturing the lage-area holographic ion beam eathing（HIBE） grating. Simultaneously, as one of the parts of ion beam technology, the developments of ion beam sources have some important effects to content the demands of ion beam technology such as large ion beam flux, excellent optical qualities. In this paper, an ion beam source called inductively coupled plasma（ICP） ion beam source was introduced, and the extractor system, the application prospect were also discussed.     

新颖的人造偏振片

作者设计并制作了偏振轴呈同心圆、放射形、；悬线形以及波浪形等几种新的特殊人造偏振片.文中讨论了这些人造偏振片的设计原理.实验证明,此类人造偏振片有可能在光学信息处理、光纤通讯及立体显示等近代光学技术中,被用作特殊的方向滤波器或区域滤波器以及编码器等     

The packing measure of the Cartesian product of the middle third Cantor set with itself

For the packing measure of the Cartesian product of the middle third Cantor set with itself, the exact value

     

Q-Switched Large-Mode-Area Yb-Doped Fibre Laser Using GaAs as Saturable Absorber

A passive Q-switched large-mode-area Yb-doped fibre laser is demonstrated using a GaAs wafer as the saturable absorber. A high Yb doping concentration double-clad fibre with a core diameter of 30μm and a numerical aperture of 0.07 is used to increase the laser gain volume, permitting greater energy storage and higher output power than conventional fibres. The maximum average output power is 7.2W at 1080nm wavelength, with the shortest pulse duration of 580ns and the highest peak power of 161W when the laser is pumped with a 25W diode laser operating at 976nm. The repetition rate increases with the pump power linearly and the highest repetition rate of 77kHz is obtained in the experiment.     

Preparation and recognition performance of ratio-fluorescent probe based on sulfadiazine imprinted polymersEI北大核心CSCD

A novel ratio-fluorescent probe based on molecular imprinting polymer ( MIP) for the detection of sulfadiazine was prepared by using nitrogen-doped carbon quantum dots (N-CQDs) as the fluorescence response signal, silica-embedded cadmium telluride quantum dots ( CdTe QDs) as the fluorescence reference signal, sulfadiazine ( SDZ) as template molecule, acrylamide as functional monomer, N, N-methyl bisacrylamide as crosslinking agent and 2,2-Azobisisobutyronitrile as initiator. The results showed that the probe has a core-shell structure and fluorescence sensitive to SDZ, by the characterization of scanning electron microscopy, transmission electron microscopy, and fluorescence spectrophotometer. Under the wavelength of 360 nm, the ratio-fluorescent signal of probe showed a linear response with SDZ concentration in the range of 0-100 μmol / L with the detection limit of 11 nmol / L. Also, the ratio-fluorescent probe was applied to the detection of SDZ with a recovery of 92. 0%-95. 1% and relative standard deviation (RSD) of 3. 6% in real water samples. © 2022, Youke Publishing Co.,Ltd. All rights reserved.     

基于分子动力学模拟的TRPM8通道门控特性分析

TRPM8通道的温度感知等生理功能依赖于正常的门控, 但现有晶体结构中S6跨膜螺旋C末端形成的门控结构存在氨基酸缺失, 所以其门控特性未能揭晓. 本文基于已有的晶体结构和AlphaFold算法构建了 11个完整不同构象的TRPM8通道, 发现其S6跨膜螺旋C末端构成的门控存在回环和螺旋2种构象. 在回环构象中, 多个氨基酸参与形成阻碍离子通透的孔道区; 而在螺旋构象中, 仅有关键氨基酸V956发挥门控作用. 由于回环构象的柔性大于螺旋构象, 导致回环构象参与阻碍离子通透的关键氨基酸构象和数量变化多样. 二级结构预测与模建结果表明, S6跨膜螺旋C末端存在回环构象向螺旋构象的转变, 此过程中柔性的回环构象结构域向胞外侧上移, 关键氨基酸向孔道衬外扭转, 增强了与相邻跨膜螺旋S5的相互作用以及S5与TRP螺旋之间的相互作用, 进而形成刚性、 稳定且有序的螺旋构象. 这增加了TRPM8通道各结构域间的协同性, 使能量信息更高效地传递到门控结构域, 为TRPM8通道开启蓄势.     

螺桨盘转子轴头动刚度实验测量方法及技术处理

在螺桨盘转子系统的颤振涡动研究中,系统的安装刚度对转子的颤振涡动失稳有着重要的作用.对于飞机发动机,实际安装情况十分复杂,发动机短舱.安装节、机翼等对螺桨盘转子的运动均有影响.所以,在颤振涡动研究中,必须考虑轴头的动刚度.轴头的动刚度是通过动柔度转换而来的,而在动柔度的实验测量中必须解决几个技术问题,首先是提高信噪比.其次是消除工艺夹具带来的附加质量和附加转动惯量的影响,从而提高动刚度系数的测量精度.本文通过对模型转子以及某实际桨轴发动机转子轴头动刚度系数的测量及处理,阐述轴头动刚度矩阵的测量方法,以及有关技术问题的处理过程.     

轴流压气机端壁附面层的理论预测

从Ｎ－Ｓ方程出发，推导了轴流压气机端壁边界层动量积分方程，并提出了一种适用范围广泛的叶片力亏损模型，结合边界层的卷吸方程和速度分布表达式，可以方便的预测压气机环壁边界层的发展，与传统的叶片力亏损模型相比，该方法的计算准确性和适用范围均得到提高。