全文获取类型
收费全文 | 328篇 |
免费 | 6篇 |
国内免费 | 1篇 |
专业分类
化学 | 191篇 |
晶体学 | 27篇 |
力学 | 9篇 |
数学 | 28篇 |
物理学 | 80篇 |
出版年
2024年 | 4篇 |
2023年 | 2篇 |
2022年 | 8篇 |
2021年 | 8篇 |
2020年 | 2篇 |
2019年 | 11篇 |
2018年 | 5篇 |
2017年 | 15篇 |
2016年 | 14篇 |
2015年 | 22篇 |
2014年 | 22篇 |
2013年 | 22篇 |
2012年 | 16篇 |
2011年 | 16篇 |
2010年 | 17篇 |
2009年 | 15篇 |
2008年 | 8篇 |
2007年 | 6篇 |
2006年 | 9篇 |
2005年 | 9篇 |
2004年 | 7篇 |
2003年 | 4篇 |
2002年 | 3篇 |
2000年 | 3篇 |
1998年 | 2篇 |
1997年 | 4篇 |
1994年 | 4篇 |
1993年 | 4篇 |
1992年 | 4篇 |
1990年 | 3篇 |
1988年 | 2篇 |
1986年 | 3篇 |
1985年 | 6篇 |
1984年 | 4篇 |
1983年 | 3篇 |
1980年 | 3篇 |
1979年 | 4篇 |
1978年 | 3篇 |
1974年 | 2篇 |
1972年 | 2篇 |
1966年 | 5篇 |
1965年 | 1篇 |
1964年 | 1篇 |
1963年 | 9篇 |
1962年 | 2篇 |
1961年 | 1篇 |
1960年 | 2篇 |
1958年 | 2篇 |
1956年 | 2篇 |
1897年 | 1篇 |
排序方式: 共有335条查询结果,搜索用时 15 毫秒
11.
S. Balasubramonian Ravi Kant Srivastav Shekhar Kumar D. Sivakumar Pranay Kumar Sinha M. Sampath U. Kamachi Mudali 《Journal of Radioanalytical and Nuclear Chemistry》2013,295(3):1703-1707
Several solutions of 30 % TBP/n-dodecane were equilibrated with different concentrations of aqueous nitric acid solutions at 298.15 K at a phase ratio of unity. The resultant equilibrated aqueous and organic solutions were analyzed for acidity. A three-solvate model with molecular HNO3 based mechanism was assumed for nitric acid extraction by TBP. With nonlinear chemometric methods, the coefficients were evaluated. With the set of optimized coefficients, derived on the basis of experiments reported in this work, the estimated solvate species and free-TBP species in the TBP containing organic phase were found to be in good agreement with the reported concentrations in the literature. 相似文献
12.
Mehmet Burçin Pişkin Aysel Kantürk Figen Hatice Ergüven 《Research on Chemical Intermediates》2013,39(2):569-583
In this study, the solid-state reaction mechanism and kinetics were investigated for production of anhydrous sodium metaborate (NaBO2), an industrially and technologically important boron compound. To assess the kinetics of solid-state production of NaBO2, the chemical reaction between borax (Na2B4O7) and sodium hydroxide (NaOH) was investigated by use of the thermal analysis techniques thermogravimetry (TG) and differential thermal analysis (DTA). DTA curves obtained under non-isothermal conditions at different heating rates (5, 10 and 20 °C/min), revealed five endothermic peaks corresponding to five solid-state reactions occurring at 70, 130, 295, 463, and 595 °C. The stages of the solid-state reaction used for production NaBO2 were also analyzed by XRD, which showed that at 70 and 130 °C, Na2B4O7 and NaOH particles contacted between the grains, and diffusion was initiated at the interface. However, there was not yet any observable formation of NaBO2. Formation of NaBO2 was initiated and sustained from 295 to 463 °C, and then completed at 595 °C; the product was anhydrous NaBO2. Activation energies (E a) of the solid-state reactions were calculated from the weight loss based on the Arrhenius model; it was found that in the initial stages of the solid-state reaction E a values were lower than in the last three steps. 相似文献
13.
The present work describes the synthesis, characterization and application of functionalized surfactants derived through simple organic reaction steps. These surfactants have been particularly tailor made to resist hardness due to calcium ions in water. It is unique of its kind because here the surfactants have an analogous hydrophobic chain but differ structurally in the composition of the head groups in terms of the position of attachment of the chain. The effect of this small variability in the head group on the surfactant property, adsorption, self assembly and calcium tolerance behaviour has been studied in detail. This kind of phenol–keto surfactants has not been reported before. It was also found that one of the surfactants was more tolerant towards Ca2+ ion than the other. The individual packing behaviour of the surfactants at the air–water interface has been projected to cause this difference which is very interesting. 相似文献
14.
15.
Eymen Akşener Aysel Kantürk Figen Sabriye Pişkin 《Research on Chemical Intermediates》2014,40(5):2103-2117
In this study, the synthesis of barium metaborate powder (BaB2O4) was carried out by ultrasound-assisted precipitation using different borate solutions. Different solutions such as borax (Na2B4O7, BD), boric acid (H3BO3, BA), and sodium metaborate (NaBO2, SMB) were used in the synthesis and an ultrasonic immersion horn probe was used as the major source of ultrasound. The effect of reaction temperature and time, pH, and crystallization time on the BaB2O4 yield (%) was investigated. The ultrasound-assisted synthesis up to 90 % yield could be achieved using a 0.2 M BD solution at 80 °C, reacting for 5 min at pH 13 followed by 2 h of crystallization. Following crystallization, the obtained powder was heated up to 140, 250, 650, and 750 °C for 2.5 h, and it was shown that β-BaB2O4 nanometric powders were obtained after the 750 °C heat treatment. 相似文献
16.
Surya Kant Mishra 《Proceedings Mathematical Sciences》1964,59(1):21-48
We consider the propagation of sound pulses due to a line source in the inhomogeneous, semi-infinite mediumy ≥ 0 with the boundary conditionφ=0 or?φ/(?y)=0 aty=0, whereφ is the acoustic velocity potential. We suppose that the velocity of wave propagation,c, is given byc ?2=p ?qe ?ay , wherep, q, α are real and positive andp>q. The method of dual integral transformation is used. The solution in terms of pulse propagation modes yields the diffracted pulse and the method of steepest descents gives the geometrical acoustic field. 相似文献
17.
We consider the problem of scattering of two-dimensional sound pulses by a rigid circular cylinder embedded in a cylindrically stratified inhomogeneous medium. The line source is parallel to the axis of the cylinder. It is assumed that the velocity of soundc is given byc ?1=pr q, wherep andq are real constants andp>0. The method of dual integral transformation developed by Friedlander is used. The solution in terms of pulse propagation modes gives the diffracted pulse and the method of steepest descents yields the geometrical acoustic field. 相似文献
18.
Kinetics and Catalysis - In this study, Langmuir–Hinshelwood and Michaelis–Menten kinetic models are applied to describe the kinetic behaviour of the Co–B catalyst in the... 相似文献
19.
Self-focusing of Hermite–Gaussian laser beams in plasma under plasma density ramp has been investigated. It is known that a laser beam shows an oscillatory self-focusing and defocusing behavior with the propagation distance. To overcome the defocusing, localized upward plasma density ramp is introduced, so that the laser beam attains a minimum spot size and maintains it with only a mild ripple. The density ramp could be important for the self-focusing of a Hermite–Gaussian laser by choosing the laser and plasma parameters appropriately. Self-focusing becomes stronger as the propagation distance increases. The behavior of beam-width parameters with the distance of propagation is presented graphically. 相似文献
20.