Nachweis und Bestimmung des Eisens, sowie seine Trennung von anderen Elementen

Ohne Zusammenfassung     

Valanimycin biosynthesis: investigations of the mechanism of isobutylhydroxylamine incorporation

[reaction: see text] The incorporation of [(15)N, (18)O]-isobutylhydroxylamine into the antibiotic valanimycin by Streptomyces viridifaciens has been shown to proceed with loss of the (18)O label, thereby demonstrating that the azoxy oxygen atom of valanimycin is not derived from the oxygen atom of isobutylhydroxylamine.     

Development of an elemental tracer using neutron activation analysis for application in an estuarine environment

Summary The work describes the selection of an activable tracer that could be used to study dispersion patterns in an English estuary and was carried out in connection with the development and testing of a particle-tracking computer model. Understanding estuarine dynamics will assist in the decision-making process for estuarine management and in contingency planning. Neutron activation analysis (NAA) has been used to characterize the concentration and natural variation of 40 trace elements in suspended particulate matter and inter-tidal bed sediment in order to identify a suitable tracer. Results have shown that europium, terbium and ytterbium would be suitable to use in a tracer study as they have low background concentrations in sediments and little variability, (Eu: 1.31 mg ^. kg^-1±13%, Tb: 0.90 mg ^. kg^-1±16% and Yb: 2.91 mg ^. kg^-1±18%). The ratios of these elements are constant throughout the estuary and experiments have shown that increases in concentration of any of these elements due to the addition of artificial elemental tracer could be quantitatively determined by changes in the ratio constant.     

Evaluation of nuclear effects in the analysis of plastics by neutron activation analysis

Validation of a method for the determination of trace elements in plastic using neutron activation analysis (NAA) required evaluation of nuclear effects. Since plastic is a moderator of neutrons, it is possible that the neutron flux may be affected in such a way as to effectively increase or decrease the measured activity of radionuclides within the plastic. Such effects are likely to depend on the thickness of the sample and so thicknesses of plastic ranging from 1 to 20 mm were used to quantify the effects. A standard containing vanaldium (a thermal neutron absorber) and silver (with epithermal neutron resonances) was used in a sandwich of the plastic. The sandwich was then irradiated and the standard counted. The activity of each radionuclide for each thickness was evaluated. The results showed that a variation of only 10% maximum was observed for thicknesses up to 20 mm. An increase in measured activity was observed for both the thermal and epithermal absorbers.     

Biotin biosynthesis. Incorporation of 5(RS)-3H-Dethiobiotin into biotin

5(RS)-³H-(±)-Dethiobiotin has been synthesized and its incorporation into biotin by $\text{Aspergillus}$$\text{niger}$ has been investigated. The incorporation was found to proceed without tritium loss.     

Adsorption of Pb(II), Cu(II), Cd(II), Zn(II), Ni(II), Fe(II), and As(V) on bacterially produced metal sulfides

The adsorption of Pb(II), Cu(II), Cd(II), Zn(II), Ni(II), Fe(II) and As(V) onto bacterially produced metal sulfide (BPMS) material was investigated using a batch equilibrium method. It was found that the sulfide material had adsorptive properties comparable with those of other adsorbents with respect to the specific uptake of a range of metals and, the levels to which dissolved metal concentrations in solution can be reduced. The percentage of adsorption increased with increasing pH and adsorbent dose, but decreased with increasing initial dissolved metal concentration. The pH of the solution was the most important parameter controlling adsorption of Cd(II), Cu(II), Fe(II), Ni(II), Pb(II), Zn(II), and As(V) by BPMS. The adsorption data were successfully modeled using the Langmuir adsorption isotherm. Desorption experiments showed that the reversibility of adsorption was low, suggesting high-affinity adsorption governed by chemisorption. The mechanism of adsorption for the divalent metals was thought to be the formation of strong, inner-sphere complexes involving surface hydroxyl groups. However, the mechanism for the adsorption of As(V) by BPMS appears to be distinct from that of surface hydroxyl exchange. These results have important implications to the management of metal sulfide sludge produced by bacterial sulfate reduction.     

Molecular states of atoms. II

Orbital energy parameters, previously obtained from atomic valence state energies, are used in calculating approximate wave functions for their orbitals. The radial factors of these wave functions are expressed as linear combinations of three Gaussian type orbitals with selected exponents, the coefficients being determined by normalisation and reproduction of the kinetic energy and interelectron repulsion parameters. Wave functions of universal form are obtained for the non-transition elements up to xenon. Each calculated s orbital wave function (except 1s) has a radial node, as is appropriate if there is a p orbital in the same shell with none.     

Kerr constant of water from 280 to 350 K at 632.8 nm

The Kerr constant (B_T) of deionized liquid water was measured in the temperature range from 280 K to 350 K using 2 μs duration electric pulse fields up to 50 kV cm^?1. The value of B_T has been determined as 2.92 × 10^?14 mV^?2 at 298 K. Results indicate a steady decrease in the value of the Kerr constant with the rise of temperature.     

Apparent Neutron Emissions from Polyethylene Capsules during Neutron Activation and Delayed Neutron Counting

At Imperial College uranium is determined at very low levels in environmental samples by delayed neutron counting. High density polyethylene capsules are used for transporting the samples in a pneumatic transfer system, from the reactor, to the neutron detection rig. The detector has a background of 3.6 counts per minute, however the empty transport capsules produce 11.0 counts above the background. We have determined that neither uranium in the polyethylene or from contamination of the capsule nor ¹⁷N from the ¹⁷O(n,p)¹⁷N and ¹⁸O(n,d)¹⁷N reactions are the cause. This paper reports the results of the investigation into the source of the extra counts.     

Platinum metal concentrations in urban road dust and soil in the United Kingdom

Concentrations of Pt, Pd, Rh and Au in soils and road dusts taken from areas of high and low traffic flows in the London Borough of Richmond and from a section of the Kingston bypass (A3) at New Malden, Surrey, have been measured. High concentrations of platinum are associated with high traffic densities. Samples taken from streets of lower traffic flows were found to contain the lower concentrations of the ranges. These values correlated well with the levels of lead which were also high at roundabouts. If the preliminary results obtained in this study apply more generally throughout the UK, then the potential for exposure to enhanced levels of Pt would appear to be higher for road users and for those living in urban environments or along major highways.