全文获取类型
收费全文 | 2138篇 |
免费 | 55篇 |
国内免费 | 3篇 |
专业分类
化学 | 1180篇 |
晶体学 | 51篇 |
力学 | 116篇 |
数学 | 461篇 |
物理学 | 388篇 |
出版年
2024年 | 7篇 |
2023年 | 18篇 |
2022年 | 26篇 |
2021年 | 25篇 |
2020年 | 52篇 |
2019年 | 65篇 |
2018年 | 73篇 |
2017年 | 63篇 |
2016年 | 114篇 |
2015年 | 77篇 |
2014年 | 92篇 |
2013年 | 310篇 |
2012年 | 90篇 |
2011年 | 101篇 |
2010年 | 97篇 |
2009年 | 91篇 |
2008年 | 89篇 |
2007年 | 86篇 |
2006年 | 84篇 |
2005年 | 63篇 |
2004年 | 64篇 |
2003年 | 40篇 |
2002年 | 38篇 |
2001年 | 33篇 |
2000年 | 17篇 |
1999年 | 27篇 |
1998年 | 26篇 |
1997年 | 31篇 |
1996年 | 15篇 |
1995年 | 21篇 |
1994年 | 19篇 |
1993年 | 13篇 |
1992年 | 10篇 |
1990年 | 8篇 |
1989年 | 8篇 |
1988年 | 13篇 |
1987年 | 9篇 |
1985年 | 16篇 |
1984年 | 11篇 |
1983年 | 12篇 |
1982年 | 7篇 |
1981年 | 13篇 |
1980年 | 11篇 |
1979年 | 9篇 |
1978年 | 6篇 |
1977年 | 6篇 |
1975年 | 10篇 |
1973年 | 5篇 |
1971年 | 5篇 |
1927年 | 5篇 |
排序方式: 共有2196条查询结果,搜索用时 15 毫秒
41.
The thermal behaviours of the Ti(II), Mn(II), Fe(II), Ni(II), Cu(II) and Zn(II) complexes of triethanolamine were studied by means of thermogravimetry, differential thermogravimetry, differential thermal analysis infrared spectrophotometry and elemental analysis. The sequence of thermal stability of the metal complexes, determined by using the initial decomposition temperature, was found to be Ti(II)?Mn(II)>Fe(II)>Ni(II)>Zn(II)>Cu(II). Some of the kinetic parameters, such as the activation energy and order of reaction for the initial decomposition reaction, were calculated and the relationship between the thermal stability and the chemical structure of the complexes is discussed. 相似文献
42.
Atta-ur-Rahman Nasim S Baig I Sener B Orhan I Ayanoglu F Choudhary MI 《Natural product research》2004,18(5):465-471
Two new isoflavones 1 and 2 along with eleven known compounds 3-13, have been isolated for the first time from the rhizomes of Iris soforana. The structures of these compounds were determined on the basis of spectroscopic methods and found to be 5,3'-dihydroxy-4'-methoxy-6,7-methylenedioxyisoflavone (1) (Soforanarin A), and 5,7,5'-trimethoxy-6,3',4'-trihydroxyisoflavone (2) (Soforanarin B). 相似文献
43.
This preliminary study describes the concentration of radionuclides 238U, 232Th, 40K, and 226Ra in Afin-Elbistan lignite samples which are primarily used for power generation in the Afin-Elbistan Coal-Fired Power Plant. The results show that the concentration of 238U is higher in the Afin-Elbistan lignite compared to various world coals whereas the opposite is observed with 232Th and 40K. 相似文献
44.
D. Karakaş I. Ölmez S. Tosun G. Tuncel 《Journal of Radioanalytical and Nuclear Chemistry》2004,259(1):187-192
Instrumental neutron activation analysis (INAA), flame atomic absorption spectrometry (FAAS), flame atomic emission spectrometry (FAES), graphite furnace atomic absorption spectrometry (GF-AAS), ion chromatography (IC) and visible spectrometry (VIS) were used to determine the composition of atmospheric aerosols, collected at a rural site in the Western Black Sea Coast of Turkey. A total of 354 daily aerosol samples were analyzed for 46 trace and major elements and ions. Sample preparation, quality control procedures, instrumental operating conditions for INAA and source apportionment work is presented. 相似文献
45.
Sevim Hamamci Veysel T. Yilmaz Orhan Büyükgüngr 《Acta Crystallographica. Section C, Structural Chemistry》2006,62(1):m1-m3
Crystallization of the title compound, di‐μ‐pyridazine‐1κ2N:2κ2N′‐bis[(2,3‐dihydro‐3‐oxobenzisosulfonazolato‐κN)silver(I)], [Ag2(C7H4NO3S)2(C4H4N2)2], from acetonitrile yields both monoclinic, (I), and triclinic, (II), polymorphs. In both forms, the silver(I) ions have a slightly distorted trigonal AgN3 coordination geometry and are doubly bridged by two neutral pyridazine (pydz) ligands, generating a centrosymmetric dimeric structure. The saccharinate (sac) ligands are N‐coordinated. The dihedral angles between the sac and pydz rings are 8.43 (7) and 7.94 (8)° in (I) and (II), respectively, suggesting that the dimeric molecule is nearly flat. The bond geometry is similar in both polymorphs. In (I), the dimers interact with each other via aromatic πsac–πpydz stacking interactions, forming two‐dimensional layers, which are further crosslinked by weak C—H⋯O interactions. Compound (II) exhibits similar C—H⋯O and π–π interactions, but additional C—H⋯π and π⋯Ag interactions help to stabilize the packing of the dimers. 相似文献
46.
47.
The beta dose response and Optically Stimulated Luminescence (OSL) signal stability characteristics of human tooth enamel deproteinated by hydrazine reagent under blue photon stimulation are reported. Removal of the protein organic component of tooth enamel resulted in a higher OSL sensitivity and slower fading of OSL signals. The effect of chemical sample preparation on the enamel sample sensitivity is discussed and further steps to make this deproteinization treatment suitable for in vitro dose reconstruction studies are suggested. 相似文献
48.
Michael Mehring Christian LÖW Ioannis Vrasidas Markus SchÜRmann Klaus Jurkschat 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1):311-318
Recent results are reported on the application of the novel O,C,O-coordinating pincer ligand {2,6-[P(O)(OEt)2]2-4-tert-Bu-C6H2} (A) for the synthesis of hypercoordinate organotin(IV) compounds ASnR3 (R = Ph, Cl), heteroleptic stannylenes ASnR (R = Cl, CH2SiMe3) and intramolecularly coordinated 1,2,5-oxaphosphastannolanes. 相似文献
49.
Gülhan Turan-Zitouni Ahmet Özdemir Zafer Asim Kaplancikli Pierre Chevallet Yagmur Tunali 《Phosphorus, sulfur, and silicon and the related elements》2013,188(12):2717-2724
The increasing clinical importance of drug-resistant fungal and bacterial pathogens has lent additional urgency to microbiological research and new antimicrobial compound development. For this purpose, new pyrazoline derivatives were synthesized and evaluated for antimicrobial activity. Some 1-[(N, N-disubstitutedthiocarbamoylthio)acetyl]-3,5-diaryl-2-pyrazolines derivatives were synthesized by reacting 1-(chloroacetyl)-3,5-diaryl-2-pyrazolines with appropriate potassium salts of secondary amine dithiocarbamic acids. The chemical structures of the compounds were elucidated by IR, 1 H-NMR, and FAB+-MS spectral data. Their antimicrobial activities against Staphylococcus aureus (B-767), Escherichia coli (B-3704), Pseudomonas aeruginosa (ATCC 27853), Proteus vulgaris (NRLL B-123), and Candida albicans (NRRL-27077) were investigated. The results showed that some of the compounds have notable activity against S. aureus and C. albicans. 相似文献
50.