全文获取类型
收费全文 | 560篇 |
免费 | 17篇 |
国内免费 | 6篇 |
专业分类
化学 | 432篇 |
晶体学 | 7篇 |
数学 | 27篇 |
物理学 | 117篇 |
出版年
2022年 | 3篇 |
2021年 | 4篇 |
2020年 | 7篇 |
2019年 | 9篇 |
2018年 | 6篇 |
2017年 | 2篇 |
2016年 | 14篇 |
2015年 | 16篇 |
2014年 | 7篇 |
2013年 | 26篇 |
2012年 | 13篇 |
2011年 | 30篇 |
2010年 | 16篇 |
2009年 | 14篇 |
2008年 | 32篇 |
2007年 | 30篇 |
2006年 | 37篇 |
2005年 | 33篇 |
2004年 | 35篇 |
2003年 | 28篇 |
2002年 | 33篇 |
2001年 | 9篇 |
2000年 | 7篇 |
1999年 | 14篇 |
1998年 | 12篇 |
1997年 | 8篇 |
1996年 | 16篇 |
1995年 | 4篇 |
1994年 | 8篇 |
1993年 | 10篇 |
1992年 | 3篇 |
1991年 | 10篇 |
1990年 | 5篇 |
1989年 | 6篇 |
1988年 | 2篇 |
1987年 | 3篇 |
1985年 | 6篇 |
1984年 | 6篇 |
1983年 | 7篇 |
1982年 | 9篇 |
1981年 | 7篇 |
1980年 | 10篇 |
1979年 | 5篇 |
1977年 | 2篇 |
1976年 | 3篇 |
1975年 | 5篇 |
1974年 | 1篇 |
1973年 | 5篇 |
1972年 | 1篇 |
1967年 | 3篇 |
排序方式: 共有583条查询结果,搜索用时 17 毫秒
11.
M. Saeki M. Nakada T. Kawasaki T. Nishimura T. Kitazawa M. Takeda 《Journal of Radioanalytical and Nuclear Chemistry》2006,270(2):379-384
Summary The correlations of isomer shifts in various neptunyl(V and VI) compounds with crystallographic structures were revaluated.
A linear correlation between the isomer shifts of neptunyl(VI) compounds and Np-O bond lengths of neptunyl group has been
demonstrated. On the other hand, it has been evidenced that the isomer shifts of neptunyl(V) compounds are correlated much
stronger with the mean Np-O distances in the crystals than the lengths in neptunyl(V) group. 相似文献
12.
Hiroki Nakamura Jiro Tanaka Nobuaki Nakashima Keitaro Yoshihara 《Chemical physics letters》1981,77(2):419-421
The photoionization of 8-anilino-1-naphthalenesulfonate in polar solvents occurs through a biphotonic process, as proved by nanosecond flash photolysis. A transient absorption of a charge transfer to solvent (CTTS) state is found with ≈10 ns life-time. The state is shown to be an intermediate of the photoionization process. 相似文献
13.
Kô Kaneko Mikako Tanaka Kimiaki Haruki Nobuaki Naruse Hiroshi Mitsuhashi 《Tetrahedron letters》1979,20(39):3737-3740
The 13C-NMR spectra of seven cavanine alkaloids isolated from Veratrum and Fritillaria plants were measured and their signals were assigned, and these results were applicated for structure elucidation of two new cevanine alkaloids, baimonidine and isoverticine, isolated from mature Fritillaria verticillata. 相似文献
14.
15.
16.
17.
Soh N Imato T Kawamura K Maeda M Katayama Y 《Chemical communications (Cambridge, England)》2002,(22):2650-2651
A novel fluorescent probe, which could be the first example of a ratiometric molecular probe for direct monitoring of NO production, has been developed using a 'spin-exchange' mechanism. 相似文献
18.
Yuichi Yoshimura Tetsuya Kuze Fumiko Komiya Hiromichi Tanaka Kohei Yamada Nobuaki Kaneko 《Tetrahedron letters》2006,47(4):591-594
A practical synthesis of 4′-thioribonucleosides starting from inexpensive l-arabinose is described. 1,4-Anhydro-2,3-O-isopropylidene-4-thioribitol, which was prepared by using a novel reductive ring-contraction reaction, was converted to the 5-O-silylated sulfoxides. The Pummerer-type thioglycosylation of the sulfoxides gave the 4′-thioribonucleosides stereoselectively. 相似文献
19.
A new method for regioselective carbomagnesation of alkenes and dienes has been developed by the use of a titanocene catalyst. This reaction proceeds efficiently at 0 degrees C in THF in the presence of Cp(2)TiCl(2) by the combined use of organic halides (R-X; R = alkyl, aryl and vinyl) and n-BuMgCl to afford benzyl, alpha-silylalkyl, or allyl Grignard reagents, which were trapped with various electrophiles. The present reaction involves (i) addition of carbon radicals toward alkenes or dienes in the carbon-carbon bond-forming step and (ii) transmetalation on Ti of benzyl-, alpha-silylalkyl-, or allyltitanocene with n-BuMgCl in the carbon-magnesium bond-forming step. The scope and limitations of this reaction have also been examined. 相似文献
20.
Moriya Y Hasegawa T Hayashi K Maruyama M Nakata S Ogawa N 《Analytical and bioanalytical chemistry》2003,376(3):374-378
Visible reflection spectra of diprotonated meso-tetraphenylporphyrin adsorbates spontaneously formed at a dodecane-aqueous sulfuric acid interface have been measured using a home-made device comprising a prism-cell and variable-angle optics. The tilt angle of the pyrrole ring plane was estimated to be 47 degrees from the interface normal by use of an experimentally evaluated molecular density (1.20x10(-10) mol cm(-2)) of the diprotonated molecule in a monolayer form at the liquid-liquid interface. Positive and negative bands have been observed in the p-polarized partial internal reflection (p-PIR) spectra, whose band locations correspond to those in p-polarized external reflection (p-ER) spectra. Nevertheless, the bands in the p-PIR exhibited reversed sign to those of p-ER spectra. These suggest that the surface selection rule of the p-PIR spectrometry has a reversal rule of p-ER and p-PIR can also be used for the analysis of molecular orientation. 相似文献