排序方式: 共有31条查询结果,搜索用时 15 毫秒
11.
N. Wannarit N. Chaichit C. Pakawatchai S. Youngme 《Russian Journal of Coordination Chemistry》2010,36(10):778-785
New trinuclear carbonato-bridged copper(II) complexes, [Cu3(Bipy)6(μ3-CO3)](CF3SO3)4(H2O)0.5 (I) and [Cu3(Phen)6(μ3-CO3)](CF3SO3)4(H2O)0.5 (II) (Bipy = 2,2′-bipyridine and Phen = 1,10-phenanthroline), have been synthesized and characterized by X-ray crystallography.
In the trinuclear units, a carbonate anion triply bridges three Cu atoms in a μ3-η1:η1:η1-CO3 mode. The environment around each copper(II) center is five-coordinate ranging between intermediate to distorted square-pyramidal
geometry. In the crystal packing, the molecule of I is involved in a variety of intra/intermolecular non-covalent interactions such as intra/intermolecular stacking and CH···π
interactions between the pyridine groups of the chelated ligand, leading to a one-dimensional arrangement of I. In complex II, the molecule is involved in both intra- and intermolecular Phen-Phen π-stacking, forming a three-dimensional network. The
spectroscopic (IR, diffuse reflectance, and EPR spectra) properties and the preliminary results of magnetic measurements of
both complexes are investigated and compared to other closely related trinuclear copper(II) complexes. 相似文献
12.
13.
Lumduan Mangsup Sutatip Siripaisarnpipat Narongsuk Chaichit 《Analytical sciences》2003,19(9):1345-1346
The reaction between CoCl2 x 6H2O and 2-1-(2-thiazolylazo)-p-cresol (TAC) in acetone resulted in six coordinated cobalt(III) complex, [Co(TAC)2]Cl3. Two TAC ligands coordinate with cobalt ion forming four five membered chelate rings. The cobalt ion is octahedrally coordinated by a phenolic oxygen, azo nitrogen and nitrogen in thiazole rings. Three chloride ions are disordered. 相似文献
14.
15.
Sujittra Youngme Pimprapun Gunnasoot Narongsak Chaichit Chaveng Pakawatchai 《Transition Metal Chemistry》2004,29(8):840-846
Two dinuclear CuII complexes of formula [Cu2(dpyam)4(μ-C2O4)](PF6)2(H2O)2 (1) and [Cu2(dpyam)2(μ-C2O4)(NO3)2(DMF)2] (2) (dpyam=di-2-pyridylamine) have been synthesized and their spectroscopic and magnetic properties characterized. Complex (1) crystallizes in the non-centrosymmetric monoclinic space group Pc, while (2) crystallizes in the non-centrosymmetric triclinic space group P1. Compound (1) involves the compressed octahedral CuII environment, whereas (2) exhibits an elongated octahedral CuII geometry. Both complexes contain six-coordinate metal centers bridged by planar bis-didentate oxalate group. The geometry, spectroscopic properties and the effective magnetic moment of (1) are very close to those of the recently published [Cu2(dpyam)4 (μ-C2O4)](ClO4)2(H2O)3 and [Cu2(dpyam)4(μ-C2O4)](BF4)2(H2O)3. Thus (1) is expected to exhibit a very weak ferromagnetic interaction between the CuII centers which is confirmed by EPR spectrum. Those of (2) are comparable to those of the recently published [Cu2(dpyam)2(μ-C2O4)(NO3)2(DMSO)2]. Therefore a strong antiferomagnetic interaction is expected. The effective magnetic moment at room temperature of (1) was measured to be 2.55 BM/dimer, which agrees with the spin only value of CuII, 2.45BM calculated for two uncoupled spin=1/2 centers. In (2) the room temperature effective magnetic moment of 2.16 BM/dimer indicates the partial spin paring by antiferromagnetic coupling. This is confirmed by the e.p.r. spectrum and is explained as a result of the magnetic interaction between the coplanar ${\rm d}_{x^2-y^2}$ orbitals on the two copper atoms. 相似文献
16.
Sujittra Youngme Jaturong Phatchimkun Narongsak Chaichit 《Acta Crystallographica. Section C, Structural Chemistry》2006,62(6):m267-m268
In the structure of the title complex, [Cu(C2O4)(C10H9N3)(H2O)]·H2O, the CuII atom displays a square‐pyramidal geometry, being coordinated by two N atoms from the di‐2‐pyridylamine ligand, two O atoms from the oxalate group and one O atom of a water molecule. The complex molecules are linked to form a three‐dimensional supramolecular array by hydrogen‐bonding interactions between coordinated/uncoordinated water molecules and the uncoordinated oxalate O atoms of neighboring molecules. 相似文献
17.
Nongnuj Jaiboon Narongsak Chaichit Bongkot Pipoosananakaton Thawatchai Tuntulani Mongkol Sukwattanasinitt 《Journal of chemical crystallography》2000,30(11):717-720
Diethoxynitrobenzene-p-tert-butylcalix[4]arene2(CH3)2C=O crystallized in the monoclinic system, space group P21/c, with cell dimensions a = 16.1437(2) Å, b = 21.0292(2) Å, c = 18.9685(3) Å and = 110.308(1)°. The asymmetric unit consists of a diethoxynitrobenzene-p-tert-butylcalix[4]arene molecule and two solvated acetone molecules. Besides the usual CH/ interaction between p-tert-butylcalix[4]arene cavity and a solvated acetone, this structure shows the intra- and intermolecular CH/ interactions among a nitrobenzene ring, ethylene bridge of the ethoxynitrobenzene side chain and a solvated acetone molecule. 相似文献
18.
Surachai Pornpakakul Sophon Roengsumran Amorn Petsom Nattaya Ngamrojnavanich Narongsak Chaichit 《Tetrahedron letters》2007,48(4):651-655
A novel CYP3A4 inhibitor, diaporthichalasin, together with pycnidione were isolated from an endophytic fungus, Diaporthe sp. Their structures were elucidated on the basis of spectral data and the structure of diaporthichalasin was confirmed by X-ray crystallographic analysis. Diaporthichalasin exhibited significantly potent inhibition of CYP3A4 with an IC50 value of 0.626 μM, while the IC50 value of pycnidione was 465 μM. 相似文献
19.
The inclusion complexes of β-cyclodextrin (β-CD) with pyrazinamide (PYA) and piperazine (PIZ) have been investigated both in the solid phase by single-crystal X-ray diffraction analysis and in the gas phase by semi-empirical PM3 calculation. In the crystalline phase, the disordered PYA and PIZ molecules are entirely embedded in the β-CD cavity. The PYA pyrazine-centre displaces upwards by 1.15(1) Å from the β-CD plane, whereas the PIZ centre shifts downwards by 0.76(1) Å from the β-CD plane. The inclusion scenario changed in the gas phase. Two inclusion geometries of the PYA molecule are comparatively stable with binding energies of ? 22.28 and ? 25.29 kJ mol? 1: the pyrazine centre shifts upwards by 0.5 Å and downwards by 2.0 Å from the β-CD plane. The PIZ molecule positioning at 2.0 Å below the β-CD plane gives a more stable inclusion complex than does the PYA molecule by 22–25 kJ mol? 1. Structural distinction of the β-CD–PYA and β-CD–PIZ inclusion complexes in the solid phase (by X-ray crystallography) and gas phase (by PM3 calculation) is a paradigm of the CD conformational flexibility, the induced-fit mechanism and the dynamics of the inclusion process. 相似文献