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81.
Zirconacycles 1, obtained from diethyl 1-alkynylphosphonates, insert either acyl chlorides or nitriles to provide, after acidic workup, (E)-3-oxo-1-alkenylphosphonates, 2, in isolated yields of 55-83%. Insertion produces only one regio- and stereoisomer. The reaction is quite general and proceeds well with both aliphatic and aromatic acyl chlorides. Acetonitrile and p-methoxybenzonitrile also inserted efficiently. Insertion of isobutyl chloroformate produced the vinylphosphonocarboxylate, 2c, the first representative of this class of compounds. 相似文献
82.
Multiparticle production data on proton-nucleus collisions have been analyzed taking the number of ‘created’ charged particles
instead of the observed number of shower particles as the variable. The mean normalized multiplicity,R
A
, has been found to be independent of energy in the energy range (7–8000) GeV and its mass number dependence has been obtained.
The modified analysis introduces some more regularities in the experimental results onp-nucleus collisions like the invariance with respect to energy of the relationshipR
A
= α + βN
h
and the KNO-like scaling of the multiplicity distributions of the created charged particles. The functional form of the scaling
function has been calculated. 相似文献
83.
J. Badier J. Boucrot J. Bourotte G. Burgun O. Callot Ph. Charpentier M. Crozon D. Decamp P. Delpierre B. Gandois R. Hagelberg M. Hansroul Y. Karyotakis W. Kienzle P. Le D? J. Lefran?ois Th. Leray J. Maillard A. Michelini Ph. Miné G. Rahal O. Runolfsson P. Siegrist A. Tilquin R. Vanderhaghen S. Weisz NA Collaboration 《Zeitschrift fur Physik C Particles and Fields》1985,26(4):489-494
84.
Lamkadem M Schwob I Mimouni J Aziz M Bouali A Rabier J Fontonge R Melhaoui A 《Natural product research》2005,19(6):573-580
Numerous original alkaloids are present in tubers of Arisarum vulgare Targ. a species belonging to the Araceae family known in Morocco for its toxicity. Some previous works deal with the activity of these natural compounds as R-irniine. As the enantioselective total synthesis of irniine has been realised, the R- and S-forms were obtained and this last one could be tested. Thus, a study of the cytotoxicity and the electrophysiological activity of S-irniine was carried out on human MRC-5 fibroblasts. A cytotoxic effect of S-irniine at 40 microg/mL was detected on MRC-5 fibroblasts. An electrophysiological study was also carried out on the MRC-5 cells by using the patch-clamp technique and no effect of this compound at this concentration on the outward potassium current of MRC-5 fibroblasts was observed. Thus, this study showed, as it was for R-irniine, that the cytotoxicity of S-irniine was not explained by an effect on the potassium currents. 相似文献
85.
Abe K Abe K Adachi I Aihara H Akatsu M Anipko D Asano Y Aushev T Aziz T Bahinipati S Bakich AM Banerjee S Bedny I Bitenc U Bizjak I Blyth S Bondar A Bozek A Bracko M Brodzicka J Chang P Chao Y Chen A Chen KF Chen WT Cheon BG Chistov R Choi SK Choi Y Chuvikov A Dalseno J Danilov M Dash M Drutskoy A Eidelman S Eiges V Fang F Fratina S Gabyshev N Garmash A Gershon T Gokhroo G Golob B Haba J Hastings NC Hayasaka K Hayashii H Hazumi M Higuchi T Hinz L Hokuue T Hoshi Y Hou S Hou WS Iijima T Imoto A 《Physical review letters》2005,94(22):221805
We report on the first observation of D0/1(2420)-->D0pi- pi+ and D+/1(2420-->D+ pi- pi+ decays (where the contribution from the dominant known D1-->D*pi decay mode is excluded) in the B- -->D0/1pi-) and (-)B0-->D+/1pi- decays, respectively. The observation is based on 15.2 x 10(7) B(-)B events collected with the Belle detector at the KEKB collider. We also set 90% confidence level upper limits for the branching fractions of the four following decays: B- -->D0/1pi-, D01-->D(*0)pi- pi+, (-)B0-->D+/1pi-, D+/1-->D(*+) pi- pi+, B- -->D(*0)2(2460)pi-, D(*0)2 -->D(*0) pi- pi+, (-)B0-->D(*+)2(2460)pi-, D(*+)2-->D(*+)pi- pi+. 相似文献
86.
Aushev T Iwasaki Y Abe K Abe K Adachi I Aihara H Akatsu M Asano Y Aziz T Bahinipati S Bakich AM Bay A Bedny I Bitenc U Bizjak I Blyth S Bondar A Bozek A Bracko M Brodzicka J Chang P Chao Y Chen A Chen WT Cheon BG Chistov R Choi Y Chuvikov A Danilov M Dash M Dong LY Dragic J Drutskoy A Eidelman S Eiges V Enari Y Fang F Fratina S Gabyshev N Garmash A Gershon T Gokhroo G Golob B Hastings NC Hayasaka K Hazumi M Higuchi T Hinz L Hokuue T Hoshi Y Hou S Hou WS Iijima T Imoto A Inami K Ishikawa A 《Physical review letters》2004,93(20):201802
We report a search for CP-violating asymmetry in B0-->D(*+/-)D-/+ decays. The analysis employs two methods of B0 reconstruction: full and partial. In the full reconstruction method all daughter particles of the B0 are required to be detected; the partial reconstruction technique requires a fully reconstructed D- and only a slow pion from the D(*+)-->D0pi(+)(slow) decay. From a fit to the distribution of the time interval corresponding to the distance between two B meson decay points we calculate the CP-violating parameters and find the significance of nonzero CP asymmetry to be 2.7 standard deviations. 相似文献
87.
P.?RudolphEmail author F.J.?Ligterink J.L.?Pedersoli Jr. M.?van Bommel J.?Bos H.A.?Aziz J.B.G.A.?Havermans H.?Scholten D.?Schipper W.?Kautek 《Applied Physics A: Materials Science & Processing》2004,79(2):181-186
Paper is one of the most important materials in cultural heritage given its extensive use as the data carrier for religious, artistic and scientific records. For both aesthetic and conservation reasons, cleaning of these materials is often needed. Current paper cleaning methods using conventional means are not always sufficient, e.g. for the local cleaning of paper in the vicinity of sensitive media. In this respect a ns-pulse laser provides a valuable tool for solving difficult cleaning problems. The influence of various laser wavelengths (355 nm, 532 nm, and 1064 nm) and the ageing status of modern paper test systems were studied. Colorimetric measurements, the determination of the average molecular mass of cellulose, and chemiluminescence analysis proved to be useful for the characterization of the laser-treated paper. Treatment with green laser light at =532 nm below the paper ablation threshold fluence gave the most promising results on pure papers, with no discolouration and no other visible alteration, nor detectable chemical changes. PACS 06.60.J; 78.60.Ps; 81.65.Cf 相似文献
88.
1-Alkynylboronates form five-membered zirconacycles with Cp(2)ZrCl(2)/2-EtMgBr as indicated by deuterium labeling. The zirconacycles add aldehydes to form seven-membered zirconacycles. Hydrolysis of the latter provides 5-hydroxy-1-alkenylboronates in fair to good isolated yields. Both aliphatic and aromatic aldehydes undergo insertion. 相似文献
89.
Journal of Statistical Physics - Using mathematical statistical mechanics methods, this paper shows that decisions to heavily promote entrepreneurship beyond a certain threshold in a society would... 相似文献
90.
Zhi NA Bei JIANG Hui YANG Zhong Wen LIN Han Dong SUN* Laboratory of Phytochemistry Kunming Institute of Botany Chinese Academy of Sciences Kunming Chemistry Deparment of the College of Life Science Chemistry Yunnan University K 《中国化学快报》2001,(8)
Isodon enanderianus (Hand. -Mazz.) H. W. Li, has been used in folk medicine as anti-inflammatory and detoxified agent1. The Isodon genus is known to be rich in ent-kaurane diterpenoids, a series of new ent-kaurane diterpenoids have been isolated from the dried leaves of I. enanderianus2-4. In order to find more biologically active substances, we have carefully investigated the chemical constituents of I. enanderianus collected in Shiping county of Yunnan province, and as a result, enanderi… 相似文献