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141.
    
A bifunctional terminal organic‐inorganic dendrimer with fluorocarbon and hydrocarbon units at its terminal groups was successfully prepared by a hydrosilylation reaction, and a combination of a ring‐opening reaction and condensation reaction of octakis(propenylsuccinicanhydrido)polyhedraloctasilicate (OS‐SA) with 1‐decanol and 1H,1H,2H,2H‐perfluoro‐1‐decanol. The structure of the OS‐core dendrimer bearing the decyl and 1H,1H,2H,2H‐heptadecafluorodecyl groups (OS‐CF) was fully characterized by FT‐IR, NMR spectra, and MALDI TOF MS spectrum. The crystallinity of the fluorinated domains in OS‐CF decreased in comparison with that in I‐CF and the fluorocarbon/hydrocarbon chains form no ordered structure due to suppression of the molecular motion of their branches resulting from the rigid inorganic core. The composite films of PMMA containing OS‐CF were prepared through solution blending of PMMA with various concentrations of OS‐CF (5, 10, and 20 wt %). The refractive index of the neat PMMA film is 1.49, and the refractive indices of the composite films containing OS‐CF decrease linearly with increases in the OS‐CF weight fraction. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 912–918  相似文献   
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We investigated the fabrication process of a nanostructure with alumina insulator layer and nanoscale Cu paths punching through an alumina layer inserted between magnetic multilayers. Ion-beam–assisted oxidation was applied to an AlCu layer, where ion beams with three kinds of noble gases of different mass, Ne, Ar and Xe, were compared. The heavy gas overcame the trade-off between the increasing purity of nanoscale Cu paths and the decreasing oxygen defects of the alumina. It is considered that the high mobility of surface atoms in the AlCu layer brought about by the heavy-gas ion beam promotes segregation of alumina and Cu.https://doi.org/10.1209/0295-5075/101/47005  相似文献   
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Metal nanowires with electric conductive properties can be useful for optical polarization control medium and electro-conductive nanomaterial. We report on metallic Cu nanowires with a length of 1.0 μm and a diameter of 85 nm which were successfully photo-converted from commercial scale-like Cu particles, dispersed in a methanol solution, by using femtosecond laser irradiation. The growth mechanism of Cu nanowires under laser irradiation was suggested to be a nucleation growth process.  相似文献   
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Genetic variation of orosomucoid (ORM) in the genus Macaca was investigated. Plasma samples were subjected to isoelectric focusing in a pH range of 4-6.5, followed by immunoprinting with anti-human ORM antibodies. A total of 25 alleles were identified in 231 Asian macaques belonging to 13 species from 23 populations and 22 members belonging to a family of M. fascicularis. Family data presented evidence for a codominant mode of inheritance with multi-alleles at a single autosomal locus. A population study revealed enormous intra- and interspecies variations. The heterozygosity values varied from 0.855 in M. fascicularis (Malaysia) to 0.000 in M. radiata (India), M. silenus (India) and M. arctoides (Malaysia).  相似文献   
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The bent conformation of a trisaccharide containing 2,4-diaminoxylopyranoside, in which both end sugars are presented in 1,3-diaxial orientation, is fixed by chelation of the diamino groups to Pt(II) and unfixed by a ligand exchange reaction with NaCN or thiourea giving its extended conformation.  相似文献   
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Nagilactone F was synthesized from (+)-podocarpic acid of the established structure. This work constitutes the first total synthesis of the biologically active norditerpenoid dilactones in Podocarpus plants.  相似文献   
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Electron injection is demonstrated to trigger electrocatalytic chain reactions capable of releasing a solvent molecule and forming a redox active guest molecule. One-electron reduction of a hydroxy anthrone derivative (AQH–CH2CN) results in the formation of an anthraquinone radical anion (AQ˙) and acetonitrile (CH3CN). The resulting fragment of AQ˙ exhibits high stability under mild reducing conditions, and it has enough reducing power to reduce the reactant of AQH–CH2CN. Hence, subsequent electron transfer from AQ˙ to AQH–CH2CN yields the secondary AQ˙ and CH3CN, while the initial AQ˙ is subsequently oxidized to AQ. Overall, the reactants of AQH–CH2CN are completely converted into AQ and CH3CN in sustainable electrocatalytic chain reactions. These electrocatalytic chain reactions are mild and sustainable, successfully achieving catalytic electron-triggered charge-transfer (CT) complex formation. Reactant AQH–CH2CN is non-planar, making it unsuitable for CT interaction with an electron donor host compound (UHAnt2) bearing parallel anthracene tweezers. However, conversion of AQH–CH2CN to planar electron acceptor AQ by the electrocatalytic chain reactions turns on CT interaction, generating a host CT complex with UHAnt2 (AQ ⊂ UHAnt2). Therefore, sustainable electrocatalytic chain reactions can control CT interactions using only a catalytic amount of electrons, ultimately affording a one-electron switch associated with catalytic electron-triggered turn-on molecular recognition.

The reactants of AQH–CH2CN are converted into AQ and CH3CN in sustainable electrocatalytic chain reactions, successfully achieving catalytic electron-triggered charge-transfer (CT) complex formation.  相似文献   
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