One‐pot Green Procedure for Synthesis of Tetrahydrobenzo[a]xanthene‐11‐one Catalyzed by Brønsted Ionic Liquids under Solvent‐free Conditions

An efficient one‐pot condensation of β‐naphthol, aldehydes and cyclic 1,3‐dicarbonyl compound has been achieved with ionic liquids as catalyst, thus a variety of 8,9,10,12‐tetrahydrobenzo[a]xanthen‐11‐one derivatives were prepared in good yields. The present approach offers several advantages such as shorter reaction times, good yields and mild reaction conditions.     

Adsorption properties of N<Subscript>2</Subscript>O on (6,0), (7,0), (8,0), and Al-doped (6,0) zigzag single-walled carbon nanotubes: a density functional study

Abstract  

The behavior of N₂O adsorbed on the external surface of H-capped (6,0), (7,0), (8,0), and Al-doped (6,0) zigzag single-walled carbon nanotubes was studied by using density functional calculations. Geometry optimizations were carried out at the B3LYP/6-31G* level of theory using the Gaussian 03 suite of programs. We present the nature of the N₂O interaction in selected sites of the nanotubes. Binding energies corresponding to adsorption of the N₂O are calculated to be in the range 4–21 kJ mol⁻¹. More efficient binding energies cannot be achieved by increasing the nanotube diameter. We also provide the effects of N₂O adsorption on the electronic properties of the nanotubes.     

Copper iodide nanoparticles on poly(4-vinyl pyridine) as new and green catalyst for multicomponent click synthesis of 1,4-disubstituted-l,2,3-triazoles in water

Poly(4-vinyl pyridine) supported nanoparticle of copper(Ⅰ) iodide is reported as a green and recyclable catalyst for the regioselective synthesis of 1,4-disubstituted-1H-1,2,3-triazoles from benzyl halides,sodium azide and terminal alkynes in water. This catalyst can be recovered by simple filtration and recycled up to 8 consecutive runs without any loss of its efficiency.     

Supramolecular assembled of hexameric water clusters into a 1D chain containing (H<Subscript>2</Subscript>O)<Subscript>6</Subscript> and [(H<Subscript>2</Subscript>O)<Subscript>4</Subscript>O<Subscript>2</Subscript>] stabilized by hydrogen bonding in a copper complex

Background  

Various water clusters including hexamers, heptamers, octamers, decamers and 1D or 2D infinite water chains in a number of organic and inorganic-organic hybrid hosts, have been reported.     

On the regular cosine family of linear correspondences

In this paper, we investigate the existence of unique continuous linear extension for linear correspondences. We also give some results on cosine families of linear correspondences.     

Ultrasonic route synthesis,characterization and electrochemical study of graphene oxide and reduced graphene oxide

Research on Chemical Intermediates - In this study, an efficient route for graphene oxide (GO) and reduced GO (RGO) synthesis was developed by using an ultrasonic probe and bath alternatively. RGO...     

Combination of polymer and halloysite chemistry for development of a novel catalytic hybrid system

Research on Chemical Intermediates - A covalent hybrid of halloysite-poly(methyl methacrylate-co-maleic anhydride) was prepared and applied for the immobilization of Pd nanoparticles. The hybrid...     

Syntheses,Characterization and X‐Ray Structures of the first Copper(I) and Silver(I) Complexes with ATT (ATT = 6‐Aza‐2‐thiothymine)

The reaction of copper(I) chloride with 6‐aza‐2‐thiothymine (ATT, 1 ) and triphenylphosphane in methanol/chloroform gives [(ATT)CuCl(PPh₃)] ( 2 ) as a neutral complex. [(ATT)Ag(NO₃)(PPh₃)₂]·MeOH ( 3 ) can be obtained by the reaction of 1 with silver(I) nitrate and triphenylphosphane in methanol/chloroform in excellent yields and the single crystals of 3 can be obtained from acetonitril solution. Both complexes were characterized by infrared spectroscopy, elemental analyses as well as by X‐ray diffraction studies. Crystal data for 2 at —80 °C: space group I2/a with a = 1859.3(1), b = 1143.2(1), c = 2208.2(1) pm, β = 104.84(1)°, Z = 8, R₁ = 0.0355 and for 3 at —80 °C: space group P2₁/c with a = 1344.1(1), b = 1553.6(1), c = 1977, 3(3) pm, β = 105.26(1)°, Z = 4, R₁ = 0.0436.     

A spectrophotometric and thermodynamic study of the charge-transfer complexes of iodine with nortriptyline and imipramine drugs in chloroform and dichloromethane solutions

The interaction of iodine as electron acceptor with nortriptyline and imipramine drugs as electron donors has been investigated spectrophotometrically at various temperatures in chloroform and dichloromethane solutions. The observed time dependence of the charge–transfer band and subsequent formation of in solution were related to the slow transformation of the initially formed iodine: drug outer complex to an inner electron donor–acceptor (EDA) complex, followed by fast reaction of the inner complex with iodine to form a triiodide ion. The pseudo-first-order rate constants and activation parameters for the transformation process were evaluated from the absorbance-time data. Stoichiometrices of the complexes were defined by the Job’s method of the continuos variation and obtaind 2: 1 for iodine: drug complexes. The formation constants and molar absorptivities were evaluated from the absorbance-mole ratio data. Thermodynamic parameters of the complexes have been determined from the temperature dependence of the stability constant by Van’t Hoff equation.