全文获取类型
收费全文 | 1114篇 |
免费 | 53篇 |
国内免费 | 4篇 |
专业分类
化学 | 843篇 |
晶体学 | 14篇 |
力学 | 27篇 |
数学 | 49篇 |
物理学 | 238篇 |
出版年
2023年 | 5篇 |
2022年 | 6篇 |
2021年 | 6篇 |
2019年 | 14篇 |
2018年 | 14篇 |
2017年 | 15篇 |
2016年 | 19篇 |
2015年 | 38篇 |
2014年 | 32篇 |
2013年 | 50篇 |
2012年 | 38篇 |
2011年 | 59篇 |
2010年 | 37篇 |
2009年 | 30篇 |
2008年 | 56篇 |
2007年 | 54篇 |
2006年 | 61篇 |
2005年 | 67篇 |
2004年 | 67篇 |
2003年 | 40篇 |
2002年 | 53篇 |
2001年 | 19篇 |
2000年 | 11篇 |
1999年 | 24篇 |
1998年 | 13篇 |
1997年 | 11篇 |
1996年 | 19篇 |
1995年 | 9篇 |
1994年 | 18篇 |
1993年 | 11篇 |
1992年 | 11篇 |
1991年 | 10篇 |
1990年 | 19篇 |
1989年 | 14篇 |
1988年 | 20篇 |
1987年 | 13篇 |
1986年 | 13篇 |
1985年 | 12篇 |
1984年 | 22篇 |
1983年 | 16篇 |
1982年 | 13篇 |
1981年 | 14篇 |
1980年 | 15篇 |
1979年 | 10篇 |
1978年 | 16篇 |
1977年 | 7篇 |
1976年 | 11篇 |
1975年 | 8篇 |
1974年 | 9篇 |
1973年 | 4篇 |
排序方式: 共有1171条查询结果,搜索用时 15 毫秒
141.
Takiue T Hirose D Murakami D Sakamoto H Matsubara H Aratono M 《The journal of physical chemistry. B》2005,109(34):16429-16434
The interfacial tension gamma of the hexane solution of 1H,1H-perfluorononanol (FDFC(9)OH) and its omega-hydrogenated analogue, 1H,1H,9H-perfluorononanol (HDFC(9)OH), against water was measured as a function of pressure and concentration at 298.15 K in order to clarify the effect of omega-dipole on the orientation of fluorononanol molecules from the viewpoint of volume. The adsorbed films of both alcohols exhibit two kinds of phase transitions among three different states: the gaseous, expanded, and condensed states. The partial molar volume changes of adsorption - in the expanded and condensed states were evaluated and compared between the two systems. The - values of both alcohols are negative, and thus the alcohol molecules have smaller volume in the adsorbed film than in the bulk solution. Furthermore, the value was obtained through the evaluation of by the density measurement of the bulk hexane solution. It was found that the value of HDFC(9)OH is smaller than that of FDFC(9)OH in the condensed state. On the basis of three matters concerning the molecular structure of alcohols, the occupied area at the interface, and the orientation of FDFC(9)OH in the adsorbed film deduced from the earlier results of X-ray reflectivity measurement, the mean tilt angle of HDFC(9)OH from the interface normal in the condensed film was estimated to be 15 degrees . The thermodynamic estimation demonstrated here is highly valuable one to provide structure information on an adsorbed film. 相似文献
142.
H Hagiwara T Nagasawa K M Lodhi M Kozuka T Ito S Hirose 《Journal of chromatography. A》1992,597(1-2):331-334
Endothelin receptor was purified from bovine lung by affinity chromatography using biotinylated endothelin and avidin-agarose. Endothelin was biotinylated with sulphosuccinimidyl 2-(biotinamido)ethyl-1,3-dithiopropionate, a reactive form of biotin with a cleavable spacer arm containing a disulphide bond designed for a simple elution by thiols. Starting from 3.5 kg of bovine lung, about 200 micrograms of pure receptor were obtained. 相似文献
143.
Masataka Hakamada Fumi Hirashima Kota Kajikawa Mamoru Mabuchi 《Applied Physics A: Materials Science & Processing》2012,106(1):237-244
The magnetic moments of the fcc/fcc, hcp/hcp twin and fcc/hcp twin-like boundaries in cobalt were investigated by first-principles calculations based on density functional theory. The
magnetic moments in fcc/fcc were larger than those of the bulk fcc, while the variations in the magnetic moment were complicated in hcp/hcp and fcc/hcp. The magnetovolume effect on the magnetic moment at the twin(-like) boundaries was investigated in terms of the local average
atomic distance and the average deviation from equilibrium; however, the complicated variations in the magnetic moment could
not be explained from the magnetovolume effect. Next, the narrowing (or broadening) of the partial density of states (PDOS)
width of 3d orbitals, the number of occupied states for the spin-down channel, and the PDOS around the Fermi level were investigated.
The entire variation in the magnetic moment at the twin(-like) boundaries could be understood in terms of these factors. Charge
transfer occurred in hcp/hcp. In this case, the contributions of 4s and 4p electrons to the variation in the magnetic moment were relatively large. 相似文献
144.
Masataka Tomari 《Mathematische Nachrichten》1993,164(1):37-48
The Milnor number μ and the geometric genus pg of normal 2-dimensional double points are studied by using Zariski's canonical resolution. By using formulas due to E. HORIKAWA and H. LAUFER, we represent μ ? 8pg in terms of the number of blowing-ups along ?1 and the number l of ?even”? components in the resolution process. A key point of our arguments is the fact that if l is small then the resolution process is restricted very much. For rational double points and double points with pa = 1, each classes are characterized by numerical invariants appearing in this resolution process. For the case pa = 1, we can make our inequality sharper and can prove 12 · pg ? 3 ≤ μ. This is an another proof of Xu-Yau's inequality for the singularity with pa = 1 in our situation. 相似文献
145.
Hiroya Yamaguchi Yoshie Yotsukura Hirosaku Sata Yoko Watanabe Hajime Hirose Noriko Kobayashi Diane M. Bless 《Journal of voice》1993,7(3)
A voice therapy program using pushing exercises to correct glottal incompetence is described. The program utilizes various types of instrumentation to determine whether or not a given patient is likely to benefit from the treatment. The program also provides feedback of target voices. Three cases with incomplete glottal closure and subsequent vocal dysphonia characterized by an asthenic breathy quality are used to illustrate the program. Details of the program, termination criteria, and problems and precautions learned from treating 29 patients over a 3-year period are presented. 相似文献
146.
Takahito Itoh Motoka Ikeda Nobuyuki Hirata Yuji Moriya Zhaoyin Wen Yoshiaki Ichikawa Masataka Kubo Osamu Yamamoto 《Ionics》2002,8(1-2):44-52
Terminal-acetylated hyperbranched poly(ethylene glycol) derivatives containing diethylene, triethylene, and hexaethylene and
3,5-dioxybenzoate branching units (poly-Ac1a, poly-Ac1b, and poly-Ac1c) were synthesized. Electrochemical and thermal properties of the hyperbranched polymer electrolytes with lithium salts such
as LiCF3SO3 and LiN(CF3SO2)2, the composite hyperbranched polymer electrolytes with LiN(CF3SO2)2 containing α-LiAlO2 and γ-LiAlO2 fillers, and the hyperbranched polymer blended poly(ethylene oxide) electrolytes with LiN(CF3SO2)2 were investigated and discussed.
Paper presented at the 8th EuroConference on Ionics, Carvoeire, Algarve, Portugal, Sept. 16–22, 2001. 相似文献
147.
Satomi Onoue Baosheng Liu Yoshitaka Nemoto Mariko Hirose Takehiko Yajima 《Analytical sciences》2006,22(12):1531-1535
Thymopentin (TP5) is a synthetic pentapeptide fragment, which corresponds to position 32 - 36 of thymic polypeptide thymopoietin. Thymopoietin and TP5 display a variety of biological functions, including phenotypic differentiation of T cells and the regulation of immune systems. Previous chemical modification experiments suggested that there was an absolute requirement for N-terminal amino acids to maintain the biological activity of TP5. On the basis of this structure-activity relationship, we designed and synthesized the C-terminally 5-carboxyfluorescein-coupled TP5 (TP5-FAM) as a fluorescent probe for thymopoietin receptor. TP5-FAM could bind to the membrane of human lymphoid cell lines, MOLT-4 cells, in which the thymopoietin receptor is expressed. The binding is specific and saturable (K(d) = 33 microM). TP5 and human splenopentin are nearly equipotent inhibitors of TP5-FAM binding to the thymopoietin receptor, but porcine secretin did not show any significant inhibition of TP5-FAM binding to MOLT-4 cells. Thus, TP5-FAM is suggested to be a potent and biologically active ligand that would be useful for studying the binding and functional characteristics of the human thymopoietin receptor. 相似文献
148.
Masaya Nakata Takashi Ishiyama Youichi Hirose Hiroshi Maruoka Kuniaki Tatsuta 《Tetrahedron letters》1993,34(52):8439-8442
The enantiospecific synthesis of the oligomycin B degradation product 2, corresponding to the C19–C34 spiroketal portion, has been achieved by sequential coupling of the C19–C21, C22–C27, and C28–C34 subunits, establishing the absolute stereochemistry of oligomycin B. 相似文献
149.
Polymer electrolytes plasticized with hyperbranched polymer for lithium polymer batteries 总被引:1,自引:0,他引:1
Hyperbranched polymers (HBPs) with different terminal groups and different ethylene oxide (EO) chain lengths were prepared,
and the influence of the HBP structures including molecular weights and molecular weight distribution on the ionic conductivity
and the mechanical property of the composite polymer electrolytes composed of poly (ethylene oxide) (PEO), HBP, BaTiO3 as a ceramic filler, and LiN(CF3SO2)2 as a lithium salt were investigated. It was found that the molecular weights of the HBP do not affect significantly the ionic
conductivity, but the molecular weight distribution might affect it, and also further branching at the terminals of the HBP
led to a decrease in the ionic conductivity. The HBP with longer EO chain length was effective for enhancement of the ionic
conductivity in comparison with the HBP with shorter one. The increase in cross-linkable groups (acryloyl group) at the terminals
of the HBP improved the tensile strength, but caused the ionic conductivity to decrease. Loosely cross-linked composite polymer
electrolyte showed higher ionic conductivity and higher tensile strength than no cross-linked one.
Paper presented at the Patras Conference on Solid State Ionics — Transport Properties, Patras, Greece, Sept. 14 – 18, 2004. 相似文献
150.
Kayoko Tahara Emi Makii Shiro Iijima Yoshihiro Abe Masataka Mochizuki 《Analytical sciences》2008,24(7):935-938
The electrochemical oxidation of (+/-)-alpha-tocopherol on a porous graphite electrode was performed in the presence of methanol, and successive separation and detection of the products were performed by an on-line liquid chromatography/mass spectrometry system. Three products were identified, one of which was determined to be alpha-tocopheryl quinone, because its m/z was 469 [M+Na](+). The other two products showed identical mass and UV spectra, and were suspected to be diastereomers of 9-methoxy-alpha-tocopheron, because their molecular weights were m/z 483 [M+Na](+), and also because it is known that the chemical oxidation of alpha-tocopherol by benzoyl peroxide or N-bromosuccinimide in the presence of methanol should provide 9-methoxy-alpha-tocopheron. To confirm that these two compounds were diastereomers, a circular dichroism detector was used. The signs of both peaks detected by the circular dichroism detector at 230 nm were opposite. In addition to observations of identical mass and ultraviolet spectra, these results indicated that the two products were diastereomers of 9-methoxy-alpha-tocopheron, whose stereochemistry is different at the newly generated chiral center of the 9-position. The on-line use of a circular dichroism detector with an electrochemical cell/liquid chromatography system may expand the utility of the system to study the metabolism of a chiral drug. 相似文献