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51.
The effect of turbulence manipulators on the turbulent boundary layer above a flat plate has been investigated. These turbulence manipulators are often referred to as Large Eddy Break Up (LEBU) devices. The basic idea is that thin blades or airfoils are inserted into the turbulent flow in order to reduce the fluctuating vertical velocity component v above the flat plate. In this way, the turbulent momentum transfer and with it the wall shear stress downstream of the manipulator should be decreased. In our experiments, for comparison, a merely drag-producing wire also was inserted into the boundary layer.In particular, the trade-off between the drag of the turbulence manipulator and the drag reduction due to the shear-stress reduction on the flat plate downstream of the manipulator has been considered. The measurements were carried out with very accurate force balances for both the manipulator drag and the shear stress on the flat plate. As it turns out, no net drag reduction is found for a fairly large set of configurations. A single thin blade as a manipulator performed best, i.e., it was closest to break-even. However, a further improvement is unlikely, because the device drag of the thin blade elements used here has already been reduced to only that due to laminar skin friction, and is thus the minimum possible drag. Airfoils performed slightly worse, because their device drag was higher. A purely drag-producing wire device performed disastrously. The wire device, which consisted of a wire with another thin wire wound around it to suppress coherent vortex shedding and vibration, was designed to have (and did have) the same drag as the airfoil manipulator with which it was compared. The comparison showed that airfoil and blade manipulators recovered 75–90% of their device drag through a shear-stress reduction downstream, whereas the wire device recovered only about 25–30% of its device drag.Conventional LEBU manipulators with airfoils or thin blades produce between 0.25% and 1% net drag increase, whereas the wire device (with equal device drag) produces as much as 4% net drag increase. These data are valid for the specific plate length of our experiments, which was long enough in downstream extent to realize the full effect of the LEBU manipulators. Turbulence manipulators do indeed decrease the turbulent momentum exchange in the boundary layer by rectifying the turbulent fluctuations. This generates a significant shear-stress reduction downstream, which is much more than just the effect of the wake of the manipulator. However, the device drag of the manipulator cannot be reduced without simultaneously reducing the skin friction reduction. Thus, the manipulator's device drag exceeds, or at best cancels, the drag reduction achieved by the shear-stress reduction downstream. A critical survey of previous investigations shows that the suggestion that turbulence manipulators may produce net drag reduction is also not supported by the available previous drag force measurements. The issue had been stirred up by less conclusive measurements based on local velocity data, i.e., data collected using the so-called momentum balance technique.List of symbols b lateral breadth of test plate - c chord length of turbulence manipulator - d diameter of wire manipulator - e distance of the elastic center from the leading edge of the manipulator airfoil - h height of manipulator above test plate - q dynamic pressure of the potential flow above the test plate - s spacing of turbulence manipulator elements - t thickness of turbulence manipulator elements - u,v,w fluctuating velocities in downstream, platenormal, and lateral directions - x distance from the leading edge of the test plate in the downstream direction - x 0 location of the trailing edge of the first manipulator - z distance from test plate center in the lateral direction - C D drag coefficient - C L lift coefficient - D m drag of manipulated plate including device drag and shear stress, calculated from manipulator location to downstream location - D 0 drag of unmanipulated plate boundary layer, consisting of the shear stress calculated from manipulator location to downstream location - F drag force - F 0 total skin friction force, measured over a distance from 0.4 m upstream of manipulator to 6.35 m downstream of manipulator, measured without turbulence manipulator - F LEBU device drag force of the LEBU, i.e., the turbulence manipulator - F m total drag force of manipulated plate, consisting of - F LEBU and skin friction force, measured over a distance from 0.4 m upstream of manipulator to 6.35 m downstream - F cf skin friction force as measured by the floating element balance, manipulated case - F cfo skin friction force, as measured by the floating element balance, unmanipulated case - F cf skin friction saving, defined as F cf = F cf – F cfo - F cf cumulative skin friction savings, i.e., the sum of the skin friction savings F cf , added up from the location of the manipulator to the downstream location , as shown in Fig. 11. In Fig. 13 the cumulative skin friction savings are summarized up to their asymptotic value, reached at 200 - Re c Reynolds number of the manipulator elements, calculated with the chord length c and the local velocity in the boundary layer - Re 0 Reynolds number at the location x 0 of the manipulator, calculated with the momentum thickness of the boundary layer and the mean flow velocity U - U mean flow velocity in the potential regime of the wind tunnel test section - angle of attack of the manipulator airfoils - 0 boundary layer thickness at the location x 0 of the manipulator - dimensionless distance from the manipulator in the downstream direction, defined as - density of the air - 0 local skin friction shear stress, unmanipulated case - 0 Average skin friction shear stress, average value over the lateral span (b = 2 m) of the test plate, unmanipulated case - m local skin friction shear stress, manipulated case - momentum thickness of the undisturbed turbulent boundary layer at the location x 0 The authors would like to thank Prof. H. H. Fernholz for his scientific and administrative support. The hardware for the experiments was designed and built by C. Daase, W. Hage and R. Makris. Funding for the project was provided by the Deutsche Forschungsgemeinschaft and is gratefully acknowledged.  相似文献   
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Coupled-state calculations including positronium channels are reported for positron scattering by atomic hydrogen, lithium and sodium. Integrated cross sections and total cross sections are presented for all three atoms. For lithium differential cross sections are also given. Throughout, comparison is made between results calculated with and without inclusion of the positronium channels. S-wave cross sections for positron scattering by atomic hydrogen in the Ps(1s, 2s, 2p)+H(1s, 2s, 2p) approximation show the high energy resonance first observed by Higgins and Burke in the coupled-static approximation. This resonance has now moved up to 51.05 eV and narrowed in width to 2.92 eV. Other pronounced structure is seen in the S-wave cross sections between 10 and 20 eV; it is tentatively suggested that this structure may be due to the formation of a temporary pseudo-molecular collision complex. Results calculated in the Ps(1s, 2s, , 2p, ,+H(1s, 2s, , 2p, approximation show convergence towards accurate values in the energy region below and in the Ore gap. Contrary to previous work on lithium using only an atomic basis, it is found that coupling to the 3d state of lithium is not so important when positronium channels are included; this is because a mixed basis of atom and positronium states gives a more rapidly convergent approximation than an expansion based on atom states alone. The threshold behaviour of the elastic cross section and the Ps(1s) formation cross section for lithium is investigated. Results in the Ps(1s, 2s, 2p)+Na(3s, 3p) approximation for sodium show good agreement with the total cross section measurements of Kwan et al.  相似文献   
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The effects of adding millimolar quantities of a series of compounds containing the carbonyl function on the conductances of solutions (0.2 mM) of tri-n-butylammonium picrate ino-dichlorobenzene solvent at 25°C have been measured. Values of the complex formation constants K 1 + for 1:1 cation-ligand complexes are derived from these data. The corresponding values of –G 1 0 at 25°C are (in kcal-mole –1 ): 4-butyrolactone, 4.29; propylene carbonate, 3.87; ethylene carbonate, 3.59; cyclopentanone, 3.42; ethyl acetate, 2.84; and diethyl carbonate, 2.78. These results together with earlier results from this laboratory are discussed in terms of the effects of structure on cation-ligand affinity.  相似文献   
59.
Electron-capture-gas chromatographic (EC-GC) methods for the determination of chlorinated phenol metabolites of hexachlorobenzene (HCB) and pentachlorophenol (PCP) in urine are presented. After extraction the sample was reacted with diazomethane to produce the methyl ether of each metabolite prior to determination by EC-GC. An acid alumina column was used for cleanup and separation of methylated phenols into groups. Average recoveries of greater than 80% were obtained from urine fortified with known amounts of the phenol metabolites under investigation. A level of 1 ppb1 was established as minimum detection limit for each phenol metabolite. Previously unreported urinary metabolites of HCB and PCP were found as a result of a rat feeding study. Levels of chlorinated phenol residues from (a) human general population and (b) a worker occupationally exposed to PCP are also included.  相似文献   
60.
The reaction of CyPHNa with Sn(NMe2)2 in the presence of PMDETA (= (Me2NCH2CH2)2NMe) gives the title compound [(Sn(mu-PCy))3(Na x PMDETA)2] (1), containing an electron-deficient [(Sn(mu-PCy))]3(2-) dianion with a novel two-electron, three centre (2e-3c) bonding arrangement.  相似文献   
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