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121.
Liliane Bokobza Mostafa Rahmani Colette Belin Jean‐Luc Bruneel Nour‐Eddine El Bounia 《Journal of Polymer Science.Polymer Physics》2008,46(18):1939-1951
The reinforcement of a styrene‐butadiene rubber (SBR) by single fillers—carbon black (CB) or multiwall carbon nanotubes (MWNTs)—or by mixtures of CB and MWNTs, is investigated. The morphologies, mechanical and electrical properties of the composites, are analyzed. A significant improvement in the tensile properties is observed for samples containing a dual phase. Using atomic force (AFM) and transmission electron (TEM) microscopies, we demonstrate that the double loading improves the dispersion of the nanotubes in SBR. Electrical measurements show lower resistivity and a lower percolation threshhold for composites containing blends of fillers, which provides further evidence of better dispersion. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci 46: 1939–1951, 2008 相似文献
122.
123.
We discuss a case study of an industrial production-marketing coordination problem involving component commonality. For the product line considered, the strategic goal of the company is to move from the current low volume market to a high volume market. The marketing department believes that this can be achieved by substantially lowering the end products’ prices. However, this requires a product redesign to lower production costs in order to maintain profit margins. The redesign decision involves grouping end products into families. All products within one family use the same version of some components. This paper fits in the stream of recent literature on component commonality where the focus has shifted from inventory cost savings to production and development cost savings. Further, we consider both costs and revenues, leading to a profit maximization approach. The price elasticity of demand determines the relationship between the price level and number of units sold. Consequently, we integrate information from different functional areas such as production, marketing and accounting. We formulate the problem as a net-present-value investment decision. We propose a mixed integer nonlinear optimization model to find the optimal commonality decision. The recommendation based on our analysis has been implemented in the company. In addition, the application allows us to experimentally validate some claims made in the literature and obtain managerial insights into the trade-offs. 相似文献
124.
Luc Lambs Frédéric Brunet Jean‐Luc Probst 《Rapid communications in mass spectrometry : RCM》2009,23(16):2543-2550
The Garonne is the largest river in the south‐west of France, and its drainage basin stretches between the Pyrénées and the Massif Central mountains. Until now, no water stable isotope study has been performed on the whole Garonne river basin which is composed of different geological substrata, and where the water resources are limited during the dry summer period. This study focuses on the Garonne river and its tributaries from the Pyrénées foothill upstream to its confluence with the Lot River downstream. The aim of the study is to determine the origins of the surface waters using their chemical and stable isotopic compositions (18O, D and 13C), to better understand their circulation within the drainage basin and to assess the anthropogenic influences. The Garonne displays a specific 18O seasonal effect, and keeps its Pyrénean characteristics until its confluence with the Tarn River. The difference in the dissolved inorganic carbon (DIC) comes mainly from the change in lithology between the Pyrénées and the Massif Central mountains. Agriculture activity is only detected in the small tributaries. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
125.
Scalarization of vector optimization problems 总被引:5,自引:0,他引:5
D. T. Luc 《Journal of Optimization Theory and Applications》1987,55(1):85-102
In this paper, we investigate the scalar representation of vector optimization problems in close connection with monotonic functions. We show that it is possible to construct linear, convex, and quasiconvex representations for linear, convex, and quasiconvex vector problems, respectively. Moreover, for finding all the optimal solutions of a vector problem, it suffices to solve certain scalar representations only. The question of the continuous dependence of the solution set upon the initial vector problems and monotonic functions is also discussed.The author is grateful to the two referees for many valuable comments and suggestions which led to major imporvements of the paper. 相似文献
126.
Porous polycrystal-type microstructures built up of needle-like platelets or sheets are characteristic for a number of biological and man-made materials. Herein, we consider (i) uniform, (ii) axisymmetrical orientation distribution of linear elastic, isotropic as well as anisotropic needles. Axisymmetrical needle orientation requires derivation of the Hill tensor for arbitrarily oriented ellipsoidal inclusions with one axis tending towards infinity, embedded in a transversely isotropic matrix; therefore, Laws' integral expression of the Hill tensor is evaluated employing the theory of rational functions. For a porosity lower 0.4, the elastic properties of the polycrystal with uniformly oriented needles are quasi-identical to those of a polycrystal with solid spheres. However, as opposed to the sphere-based model, the needle-based model does not predict a percolation threshold. As regards axisymmetrical orientation distribution of needles, two effects are remarkable: Firstly, the sharper the cone of orientations the higher the anisotropy of the polycrystal. Secondly, for a given cone, the anisotropy increases with the porosity. Estimates for the polycrystal stiffness are hardly influenced by the anisotropy of the bone mineral needles. Our results also confirm the very high degree of orientation randomness of crystals building up mineral foams in bone tissues. To cite this article: A. Fritsch et al., C. R. Mecanique 334 (2006). 相似文献
127.
Annelien Deneckere Walter Schudel Marina Van Bos Helena Wouters Anna Bergmans Peter Vandenabeele Luc Moens 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2010,75(2):511-519
X-ray fluorescence spectroscopy (XRF) and Raman spectroscopy have been used to examine 15th century mediaeval and 16th century renaissance vault paintings in the Our Lady's Cathedral (Antwerp, Belgium) in view of their restoration. The use of mobile instruments made it possible to work totally non-destructively. This complementary approach yields information on the elemental (XRF) and on the molecular composition (Raman) of the pigments. For the 15th century vault painting the pigments lead–tin yellow (Pb2SnO4), lead white (2PbCO3·Pb(OH)2), vermilion (HgS), massicot (PbO) and azurite (2CuCO3·Cu(OH)2) could be identified. The pigments used for the 16th century vault painting could be identified as red lead (Pb3O4), hematite (Fe2O3), lead white (2PbCO3·Pb(OH)2) and azurite (2CuCO3·Cu(OH)2). For both paintings the presence of the strong Raman scatterer calcite (CaCO3) resulted in a difficult identification of the pigments by Raman spectroscopy. The presence of gypsum (CaSO4·2H2O) on the mediaeval vault painting probably indicates that degradation took place. 相似文献
128.
Volker Leen Dr. Wenwu Qin Prof. Dr. Wensheng Yang Jie Cui Chan Xu Xiaoliang Tang Dr. Weisheng Liu Prof. Dr. Koen Robeyns Dr. Luc Van Meervelt Prof. David Beljonne Prof. Dr. Roberto Lazzaroni Prof. Dr. Claire Tonnelé Noël Boens Prof. Wim Dehaen Prof. 《化学:亚洲杂志》2010,5(9):2016-2026
Starting from the conformationally unconstrained compound 3,5‐di‐(2‐bromophenoxy)‐4,4‐difluoro‐8‐(4‐methylphenyl)‐4‐bora‐3a,4a‐diaza‐s‐indacene ( 1 ), two BODIPY dyes ( 2 and 3 ) with increasingly rigid conformations were synthesized in outstanding total yields through palladium catalyzed intramolecular benzofuran formation. Restricted bond rotation of the phenoxy fragments leads to dyes 2 and 3 , which absorb and fluoresce more intensely at longer wavelengths relative to the unconstrained dye 1 . Reduction of the conformational flexibility in 2 and 3 leads to significantly higher fluorescence quantum yields compared to those of 1 . X‐ray diffraction analysis shows the progressively more extended planarity of the chromophore in line with the increasing conformational restriction in the series 1 → 2 → 3 , which explains the larger red shifts of the absorption and emission spectra. These conclusions are confirmed by quantum chemical calculations of the lowest electronic excitations in 1 , 1a , 2 , 2a , 3 and dyes of related chemical structures. The effect of the molecular structure on the visible absorption and fluorescence emission properties of 1 , 1a , 2 , 2a , 3 has been examined as a function of solvent by means of the new, generalized treatment of the solvent effect (J. Phys. Chem. B 2009 , 113, 5951–5960). Solvent polarizability is the primary factor responsible for the small solvent‐dependent shifts of the visible absorption and fluorescence emission bands of these dyes. 相似文献
129.
Hans Postma Luc Amkreutz Alessandro Borella Martijn Clarijs Hans Kamermans Winfried Kockelmann Anna Paradowska Peter Schillebeeckx Dirk Visser 《Journal of Radioanalytical and Nuclear Chemistry》2010,283(3):641-652
Two neutron based techniques, neutron resonance capture analysis (NRCA) and time-of-flight neutron-diffraction (TOF-ND) have
been used to determine the elemental composition and structure of a precious and very well preserved all-metal sword from
the Bronze Age. This Buggenum sword was on loan from the National Museum of Antiquities (NMA) in Leiden (NL). NRCA and TOF-ND
experiments have been carried out at a number of more or less identical positions of the sword. The tin-bronze ratio and the
relative amounts of some minor elements (Sb, As, Ag, In) have been determined. The results of neutron diffraction measurements
showed considerable tin-segregation, and clear indications of hardening on the edges of the blade. In addition, radiographs
using Bremsstrahlung revealed the construction of the hilt–blade connection. The work was carried out at the EC Joint Research
Centre IRMM in Geel (B) and at the ISIS facility of the Rutherford Appleton Laboratory (UK). 相似文献
130.
Aline Staub Sylvain Giraud Martial Saugy Serge Rudaz Jean‐Luc Veuthey Julie Schappler 《Electrophoresis》2010,31(2):388-395
CE is a powerful analytical tool used to separate intact biomolecules such as proteins. The coupling of CE with TOF/MS produces a very promising method that can be used to detect and identify proteins in different matrices. This paper describes an efficient, rapid, and simple CE‐ESI‐TOF/MS procedure for the analysis of endogenous human growth hormone and recombinant human growth hormone without sample preparation. Operational factors were optimized using an experimental design, and the method was successfully applied to distinguish human growth hormone and recombinant human growth hormone in unknown samples. 相似文献