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51.
Technetium decontamination factor as a function of the acidity, flow ratio, scrubbing stage number was investigated by counter-current cascade experiments or mixer-settler batch tests. Results showed that the acidity of the scrubbing acid has little influence on the decontamination factor of technetium when the acidity was kept in the range of 4.5–6 M. The most effective method to increase the decontamination factor is to lower the feed-to-acid flow ratio. Keeping other condition same the factor increased to 10.3 from 3.1 when feed-to-acid ratio changed to 4 from 5.6. The loss of uranium and plutonium can be recovered through a re-extraction technology.  相似文献   
52.
Eleven triazolyl substituted tetrahydrobenzofuran derivatives were synthesized in high yields as novel H+/K+‐ATPase inhibitor via one‐pot CuI‐catalyzed three‐component click reaction of azide, secondary amine and 3‐bromopropyne under mild conditions in water. Their structures were characterized by NMR, IR, ESI‐MS, elemental analysis and single‐crystal X‐ray diffraction analysis. Most of the target compounds exhibited better H+/K+‐ATPase inhibitory activity than commercial omeprazole with IC50 values less than 15 µmol·L?1. The initial structure‐activity analysis suggested that the triazole substituted by cycloalkyl, aromatic ring or O‐containing side‐chain seemed to be beneficial for enhancing the activity.  相似文献   
53.
Radial flow reactor operated at cross-flow heat transfer is focused for large scale methanol synthesis. The effects of operating conditions including the reactor inlet air temperature, the heating pipe temperature and the air flow rate on the cross-flow heat transfer were investigated and results show that the temperature profile of the area in front of the heating pipe is slightly affected by all the operating conditions. The main area whose temperature profile is influenced is located behind the heating pipe. The heat transfer direction is related to the direction of the flow. In order to obtain the basic parameters for radial flow reactor designing calculation, the dimensionless number group method was used for data fitting of the bed effective thermal conductivity and the wall heat transfer coefficient which were calculated by the mathematical model with the product of Reynolds number and Prandtl number. The comparison of experimental data and calculated values shows that the calculated values fit the experimental data satisfactorily and the formulas can be used for reactor designing calculation.  相似文献   
54.
Searching new structured black phosphorus (BP) and exploring intriguing functions and applications have become a hot topic so far.Here,we introduce a novel Iso-...  相似文献   
55.
δ-Glyconolactams were first synthesized by the intramolecular Schmidt–Boyer reaction using corresponding δ-azidosugars as starting material. The reaction could be efficiently performed in good yields of 61–69% under microwave radiation in acid condition, providing an alternative protocol to iminosugar δ-lactam.  相似文献   
56.
A phenylacetylene macrocycle (PAM) derivative containing triphenylamine as the framework was synthesized in one-step Sonogashira coupling. The photophysical and electrochemical properties were investigated in details. This hexamer shows significant enhancement in two-photon absorption cross-section relative to reported PAM derivatives.  相似文献   
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Xue  Xiaofeng  Chen  Lanzhen  Zhou  Jinhui  Wu  Liming  Li  Yi  Chen  Fang  Zhang  Jinzhen  Zhao  Jing 《Chromatographia》2012,75(3-4):165-168

Determination of the levels of 1-octacosanol is important in food stuff for the study of its pharmacological activities and health benefits. In this study, a novel, simple and fast internal standard method for the non-derivatization ultra-performance liquid chromatographic determination of 1-octacosanol in raw materials and health products was developed and validated based on evaporative light scattering detection. The linearity (r 2 > 0.998), recovery (99.1–100.2%, RSD <2.7%), intra- and inter-day precision (RSD <3.8%), limit of detection (1.0 mg/L), limit of quantification (2.2 mg/L) of the 1-octacosanol were determined. The method was successfully applied to nine real 1-octacosanol products. The results of analyses had close agreement with the labeled claims of 1-octacosanol content in these products. Compared with the classical gas chromatography method, the developed method was simpler, faster and more environmentally friendly due to avoiding any derivatization step. This protocol represents a rapid and feasible method for quality control of 1-octacosanol products.

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