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151.
152.
This article presents a full account of intramolecular vinylic substitution reactions of bromoalkenes having an acetylthio moiety, which give sulfur-containing heterocycles such as dihydrothiophene, tetrahydrothiopyran, and 2-alkylidenethietane derivatives. The reaction pathways of the substitution reactions were investigated by theoretical and experimental studies. 相似文献
153.
The security number of a graph is the cardinality of a smallest vertex subset of the graph such that any attack on the subset is defendable. In this paper, we determine the security number of two-dimensional cylinders and tori. This result settles a conjecture of Brigham et al. [R.C. Brigham, R.D. Dutton, S.T. Hedetniemi, Security in graphs, Discrete Appl. Math. 155 (2007) 1708-1714]. 相似文献
154.
Tomohiro Narukawa Takayoshi Kuroiwa Izumi Narushima Koichi Chiba 《Analytical sciences》2008,24(3):355-360
The sensitivity of graphite furnace atomic absorption spectrometry (GFAAS) to arsenobetaine (AB) was 1.3-times higher than to inorganic As. In order to understand the mechanism underlying this observation, the atomization processes for both chemical species were investigated in terms of the enthalpy change (DeltaH) during the atomization process in GFAAS. The enthalpy change of AB was slightly lower than that of inorganic As, which suggested that AB was atomized more efficiently than was inorganic As. Moreover, it was observed that some co-existing organic materials enhanced the analytical sensitivity of inorganic As. The sensitivity difference between inorganic As and AB depended upon the mechanisms of their atomization processes. 相似文献
155.
Yusaku Iwasawa Tetsuroh Shirasawa Takehiro Nojima Toshio Takahashi Masuaki Matsumoto Koichi Akimoto Hiroshi Sugiyama 《Applied Surface Science》2008,254(23):7803-7806
The structure of buried Si(1 1 1)-5 × 2-Au capped with amorphous Si was investigated using surface X-ray diffraction. It was found that the 5 × 2 structural periodicity is kept under the amorphous Si from the in-plane measurement. Furthermore, the intensity variation along the fractional-order rod indicates that Au atoms are located almost on the same plane. 相似文献
156.
Koichi Ishibashi Hirohito Tsue Hiroki Takahashi Rui Tamura 《Tetrahedron: Asymmetry》2009,20(3):375-380
The first inherently chiral azacalix[4]arene has been prepared by introducing three benzyl groups onto the nitrogen bridges. The highly enantioenriched compound was easily obtained via a moderately enantioselective cyclization followed by a simple crystallization procedure. NMR and X-ray crystallographic studies revealed that easy access to the enantiomer was permitted by the non-racemizable 1,3-alternate conformation in solution, up to 110 °C, as well as by the preferential crystallization of a racemic compound. 相似文献
157.
The possibility of constructing an interdigitated array electrode (IDA) with a submicrometre gap is proposed in which adjacent microband electrodes are separated from each other by an insulated step. Then the IDA is an assembly of protrusive and hollow microband electrodes. The unit model of the IDA consisted of half of the lower (hollow) microband electrode, an insulated step and half of the upper (protrusive) microband electrode with a finite thickness on the step. The boundary value problem involving the two-dimensional Laplace equation is presented for redox cycling at the IDA under diffusion control and is solved numerically by a boundary element method. The steady-state current was computed as a function of the height of the step and the thickness of the upper electrode. It was larger than the current at the ordinary IDA, partly because the true electrode area was larger than the area of the ordinary IDA. The current varied linearly with the logarithm of the step height. It was expressed by a simple approximate equation in order to facilitate prediction of its numerical value. 相似文献
158.
Masayuki Yamada Sugako Aramaki Tomoo Hosoe Masahiko Kurosawa Isao Kijima-Suda Koichi Saito Hiroyuki Nakazawa 《Analytical sciences》2008,24(7):911-914
Fluoxymesterone, an anabolic steroid with the 17alpha-methyl,17beta-hydroxy group, has been developed as an oral formulation for therapeutic purposes. However, it is also used illegally in racehorses to enhance racing performance. In this study, we detected 9alpha-fluoro-17,17-dimethyl-18-norandrostane-4,13-dien-11beta-ol-3-one by gas chromatography/mass spectrometry (GC/MS), which has not been reported as a fluoxymesterone metabolite so far in horse. It was synthesized for use as a reference standard, and characterized on the basis of (1)H NMR and (13)C NMR spectra, as well as GC/MS EI mass spectra of TMS derivatives. It was excreted as the main metabolite in horse urine, and its reference standard could be synthesized easily. Therefore, this metabolite could be a useful target for a doping test of fluoxymesterone in racehorses. 相似文献
159.
Tomohiro Hirano Shuhei Masuda Shou Nasu Koichi Ute Tsuneyuki Sato 《Journal of polymer science. Part A, Polymer chemistry》2009,47(4):1192-1203
Radical polymerization of N,N‐dimethylacrylamide (DMAAm) was investigated in the presence of tartrates, such as diethyl L ‐tartrate, diisopropyl L ‐tartrate, and di‐n‐butyl L ‐tartrate, in toluene at low temperatures. Syndiotactic polymers were obtained in the presence of tartrates, whereas isotactic polymers were obtained in the absence of tartrates. The syndiotactic‐specificity increased with increasing amount of tartrates and with decreasing polymerization temperature. NMR analysis suggested that DMAAm and tartrates formed a 1:1 complex through double hydrogen bonding. A mechanism for the syndiotactic‐specific radical polymerization of DMAAm is proposed. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 1192–1203, 2009 相似文献
160.
Tomohiro Hirano Shou Nasu Akihiro Morikami Koichi Ute 《Journal of polymer science. Part A, Polymer chemistry》2009,47(23):6534-6539
Radical polymerization of N‐methylacrylamide (NMAAm), N,N‐dimethylacrylamide (DMAAm), and N‐methyl‐N‐phenylacrylamide (MPhAAm) was investigated in toluene at low temperatures. Atactic, isotactic, and syndiotactic polymers were obtained by the polymerization of NMAAm, DMAAm, and MPhAAm, respectively, indicating that the stereospecificity of the radical polymerization of acrylamide derivatives depended on the N‐substituents of the monomer used. From the viewpoint of monomer structure, the origin of the stereospecificity of radical polymerization of NMAAm derivatives is discussed. © 2009 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 47: 6534–6539, 2009 相似文献