全文获取类型
收费全文 | 2681篇 |
免费 | 56篇 |
国内免费 | 8篇 |
专业分类
化学 | 2012篇 |
晶体学 | 43篇 |
力学 | 25篇 |
数学 | 154篇 |
物理学 | 511篇 |
出版年
2022年 | 15篇 |
2021年 | 26篇 |
2020年 | 17篇 |
2019年 | 27篇 |
2018年 | 17篇 |
2016年 | 33篇 |
2015年 | 29篇 |
2014年 | 42篇 |
2013年 | 104篇 |
2012年 | 114篇 |
2011年 | 138篇 |
2010年 | 86篇 |
2009年 | 52篇 |
2008年 | 129篇 |
2007年 | 136篇 |
2006年 | 145篇 |
2005年 | 147篇 |
2004年 | 121篇 |
2003年 | 98篇 |
2002年 | 110篇 |
2001年 | 42篇 |
2000年 | 43篇 |
1999年 | 42篇 |
1998年 | 40篇 |
1997年 | 31篇 |
1996年 | 40篇 |
1995年 | 38篇 |
1994年 | 27篇 |
1993年 | 49篇 |
1992年 | 42篇 |
1991年 | 33篇 |
1990年 | 29篇 |
1989年 | 30篇 |
1988年 | 32篇 |
1987年 | 31篇 |
1986年 | 26篇 |
1985年 | 56篇 |
1984年 | 53篇 |
1983年 | 39篇 |
1982年 | 36篇 |
1981年 | 37篇 |
1980年 | 37篇 |
1979年 | 37篇 |
1978年 | 39篇 |
1977年 | 37篇 |
1976年 | 41篇 |
1975年 | 29篇 |
1974年 | 33篇 |
1973年 | 32篇 |
1972年 | 13篇 |
排序方式: 共有2745条查询结果,搜索用时 0 毫秒
91.
92.
M. H. Wang Y. Sawada K. Saito S. Horie T. Uchida M. Ohtsuka S. Seki S. Kobayashi T. Arii A. Kishi T. Takahashi Y. Nishimoto T. Wakimoto K. Monzen I. Kashima T. Nishikiori L. X. Sun R. Ozao 《Journal of Thermal Analysis and Calorimetry》2007,89(2):363-366
The thermal change of the tris(8-hydroxyquinolinato)aluminum (Alq3) is currently investigated by XRD-DSC and TG. The phase transition of Alq3 from α-phase to γ-phase takes place at 643–669 K. A very sharp peak with the peak temperature at approx. 709 K is ascribed
to the melting of the Alq3. The decomposition of the Alq3 was observed accompanied with the melting and evaporation at >703K. The effect of the atmospheres on the mass loss procedure
was studied by TG. It was found that thermal process of Alq3 was strongly influenced by the partial pressure of water vapor in the atmosphere instead of oxygen. 相似文献
93.
Prof. Dr. Masahiro Sadakane Sachie Moroi Yoshifumi Iimuro Dr. Natalya Izarova Prof. Dr. Ulrich Kortz Prof. Dr. Shinjiro Hayakawa Kazuo Kato Dr. Shuhei Ogo Dr. Yusuke Ide Prof. Dr. Wataru Ueda Prof. Dr. Tsuneji Sano 《化学:亚洲杂志》2012,7(6):1331-1339
Ruthenium(III)‐substituted α‐Keggin‐type silicotungstates with pyridine‐based ligands, [SiW11O39RuIII(Py)]5?, (Py: pyridine ( 1 ), 4‐pyridine‐carboxylic acid ( 2 ), 4,4′‐bipyridine ( 3 ), 4‐pyridine‐acetamide ( 4 ), and 4‐pyridine‐methanol ( 5 )) were prepared by reacting [SiW11O39RuIII(H2O)]5? with the pyridine derivatives in water at 80 °C and then isolated as their hydrated cesium salts. These compounds were characterized using cyclic voltammetry (CV), UV/Vis, IR, and 1H NMR spectroscopy, elemental analysis, titration, and X‐ray absorption near‐edge structure (XANES) analysis (Ru K‐edge and L3‐edge). Single‐crystal X‐ray analysis of compounds 2 , 3 , and 4 revealed that RuIII was incorporated in the α‐Keggin framework and was coordinated by pyridine derivatives through a Ru? N bond. In the solid state, compounds 2 and 3 formed a dimer through π? π interaction of the pyridine moieties, whereas they existed as monomers in solution. CV indicated that the incorporated RuIII–Py was reversibly oxidized into the RuIV–Py derivative and reduced into the RuII–Py derivative. 相似文献
94.
Susumu Tajima Yukiyoshi Nagai Osamu Sekiguchi Masao Fujishige Nozomu Uchida 《Journal of the American Society for Mass Spectrometry》1995,6(3):202-206
The spontaneous unimolecular dissociation reaction of methyl lactate (1) ionized by electron impact was investigated by a combination of mass-analyzed ion kinetic energy spectrometry and deuterium labeling. The metastable ions 1+· decompose in a variety of ways: four fragment peaks are observed at m/z 89, 76, 61, and 45, which correspond to the losses of ?H3, CO, CH3?O, and ?OOCH3, respectively. Double hydrogen atom transfer occurs in the third reaction. The source-generated m/z 61 ions decompose into oxygen-protonated methanols at m/z 33 ([CH3OH 2 + ]) by the loss of CO with double hydrogen atom migration. Both hydroxyl and methyne hydrogen atoms in 1 +· are present in the resultant protonated methanols. 相似文献
95.
96.
97.
Yoko Hirohara Yoshitaka OKawa Toshifumi Mihashi Tatsuo Yamaguchi Naoki Nakazawa Yasuko Tsuruga Hiroyuki Aoki Naoyuki Maeda Ichiro Uchida Takashi Fujikado 《Optical Review》2007,14(3):151-158
The purpose of this paper was to investigate the feasibility of a newly developed hyperspectral fundus imaging camera with
a liquid crystal tunable filter. The intensities of different wavelengths of light transmitted through an artery, vein, and
the area surrounding these vessels and reflected out were measured, and the differential spectral absorptions were analyzed.
Measurements were made from 16 normal eyes and from two artificial capillaries. The ratios of absorption (ROA) of arteries
to veins from 500 to 580 nm (range 1) and from 600 to 720 nm (range 2) were calculated. For all eyes, the ROArange1 was larger than ROArange2. The ROA obtained from the artificial capillary filled with blood saturated with oxygen or nitrogen was similar to that of
simulated data of oxy- and deoxyhemoglobin extinction rate. Most ROAs of human eyes were lower than those of the simulated
data and the artificial capillaries. Oxygen saturation analysis by hyperspectral fundus imaging of retinal vessels were qualitatively
in agreement with thein vitro analysis or simulated values. However, further improvements are necessary to evaluate the oxygen saturation quantitatively
in the retinal blood vessels. 相似文献
98.
Takeshi Yoshizako Akihiko WadaKoji Uchida Shinji HaraMikio Igawa Hajime KitagakiStephan E. Maier 《Magnetic resonance imaging》2011,29(1):106-110
Purpose
This retrospective study was designed to evaluate the apparent diffusion coefficient (ADC) of line scan diffusion images (LSDI) in normal prostate and prostate cancer. Single-shot echo planner images (SS-EPI) were used for comparison.Materials and Methods
Twenty prostate tumors were examined by conventional MRI in 14 patients prior to radical prostatectomy. All patients were examined with a 1.5-T MR imager (Signa CV/i ver. 9.1 GE Medical System Milwaukee, WI, USA). Diffusion-weighted MR imaging (DWI) using LSDI was performed with a pelvic phased-array coil, with b values of 5 and 800 s/mm2. DWI using SS-EPI was performed with a body coil, with b values of 0 and 800 s/mm2. The ADCs of each sequence for 14 normal prostate and 20 prostate cancers were histopathologically assessed. Signal-to-noise ratio (SNR) on DWI was estimated and compared for each sequence.Results
The mean ADCs (±S.D.) of normal peripheral zones (PZ), transition zones (TZ) and cancer (in 10−3 mm2/s) that used LSDI were 1.42±0.12, 1.23±0.10 and 0.79±0.19, respectively. Those that used SS-EPI were 1.76±0.26, 1.38±0.20 and 1.05±0.27, respectively. Using unpaired t test (P<.05), we found a significant difference in each sequence between normal tissue (both PZ and TZ) and the cancer. Paired t test (P<.05) also registered a significant difference between LSDI and SS-EPI. Mean SNR for DWI using LSDI was 16.49±5.03, while the DWI using SS-EPI was 18.85±9.26. The difference between the SNR of each sequence was not statistically significant by paired t test.Conclusion
We found that ADCs using LSDI and SS-EPI showed similar tendencies in the same patients. However, in all regions, LSDI ADCs had smaller standard deviations than SS-EPI ADCs. 相似文献99.
Kensuke Aishima Takayasu Matsuo Kazuo Murota Masaaki Sugihara 《Journal of Computational and Applied Mathematics》2010,234(4):1179-1187
DLASQ is a routine in LAPACK for computing the singular values of a real upper bidiagonal matrix with high accuracy. The basic algorithm, the so-called dqds algorithm, was first presented by Fernando-Parlett, and implemented as the DLASQ routine by Parlett-Marques. DLASQ is now recognized as one of the most efficient routines for computing singular values. In this paper, we prove the asymptotic superquadratic convergence of DLASQ in exact arithmetic. 相似文献
100.
Emission spectra and decay times of fluorescence of pyrene thin films prepared by evaporation onto substrates at liquid nitrogen temperature were measured. Structure in the emission from films warmed slowly up to higher temperature is found to the higher energy side of the excimer emission band. The decay time is about 410 ns at temperatures between 110 K and 210 K. But the emission from the film warmed up to a temperature above 210 K shows only the excimer emission. These results are discussed in relation to an amorphous structure in the pyrene evaporated thin film. 相似文献