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31.
Philip W. Westerman Sarath P. Gunasekera M. Uvais S. Sultanbawa Rymantas Kazlauskas 《Magnetic resonance in chemistry : MRC》1977,9(11):631-636
The 13C n.m.r. spectra of 36 naturally occurring xanthones are reported and all chemical shifts assigned. The shifts in substituted xanthones can be predicted from substituent effects evaluated for simple derivatives. The agreement between calculated and observed shifts decreases as the extent of substitution in the xanthone increases. 相似文献
32.
Geraldo DA Duran-Lara EF Aguayo D Cachau RE Tapia J Esparza R Yacaman MJ Gonzalez-Nilo FD Santos LS 《Analytical and bioanalytical chemistry》2011,400(2):483-492
Polyamidoamine (PAMAM) dendrimers and water-soluble 3-mercaptopropionic acid (MPA)-capped CdSe quantum dots (QDs) were combined
to produce a new gel containing supramolecular complexes of QDs/PAMAM dendrimers. The formation of the QDs/PAMAM supramolecular
complexes was confirmed by high resolution electron microscopy and Fourier transform infrared (FTIR) analyses. Molecular dynamics
simulations corroborated the structure of the new QDs/PAMAM-based supramolecular compound. Finally, on the basis of the prominent
fluorescent properties of the supramolecular complexes, PAMAM dendrimer was functionalized with folic acid to produce a new
QDs/PAMAM-folate derivative that showed an efficient and selective performance as a marker for gastric cancer cells. 相似文献
33.
Romas?Baronas Juozas?Kulys Karolis?PetrauskasEmail author Julija?Razumiene 《Journal of mathematical chemistry》2011,49(5):995-1010
This paper presents a two-dimensional-in-space mathematical model of an amperometric biosensor based on an enzyme-loaded carbon
nanotubes layer deposited on a perforated membrane. The developed model is based on non-linear non-stationary reaction-diffusion
equations. By changing input parameters the output results are numerically analysed with a special emphasis to the influence
of the geometry and the catalytic activity of the biosensor to its response. The numerical simulation at transition and steady
state conditions was carried out using the finite difference technique. The mathematical model and the numerical solution
were validated by experimental data. The obtained agreement between the simulation results and experimental data was admissible
at different concentrations of the substrate and the mediator. 相似文献
34.
Leonavicius K Ramanaviciene A Ramanavicius A 《Langmuir : the ACS journal of surfaces and colloids》2011,27(17):10970-10976
A very simple, environmentally friendly, one-step oxidative polymerization route to fabricate polypyrrole (Ppy) nanoparticles of fixed size and morphology was developed and investigated. The herein proposed method is based on the application of sodium dodecyl sulfate and hydrogen peroxide, both easily degradable and cheap materials. The polymerization reaction is performed on 24 h time scale under standard conditions. We monitored a polaronic peak at 465 nm and estimated nanoparticle concentration during various stages of the reaction. Using this data we proposed a mechanism for Ppy nanoparticle formation in accordance with earlier emulsion polymerization mechanisms. Rates of various steps in the polymerization mechanism were accounted for and the resulting particles identified using atomic force microscopy. Application of Ppy nanoparticles prepared by the route presented here seems very promising for biomedical applications where biocompatibility is paramount. In addition, this kind of synthesis could be suitable for the development of solar cells, where very pure and low-cost conducting polymers are required. 相似文献
35.
V. Venckutė S. Kazlauskas E. Kazakevičius A. Kežionis R. Korobko T. Šalkus 《Ionics》2018,24(4):1153-1159
The gadolinia-doped ceria (GDC) thin films were deposited by pulsed laser deposition. Samples with special geometry were prepared which allowed us to characterize GDC film in across-plane direction. The electrical properties of the films were investigated by means of impedance spectroscopy in the frequency range of 10 Hz to 10 GHz and 380–600 K temperature interval. The data analysis was performed by using appropriate equivalent circuit. The equivalent circuit modeled thin GDC film itself, platinum metal connections (traces) in the dielectric medium of sapphire substrate and interfaces between the film and platinum electrodes. Hence, several factors influenced the impedance spectra, namely the properties of substrate, the oxygen-ion transport in the film, ion blocking at the interface between the film and the electrode, and metal traces. The electrical properties of GDC thin films were compared with these of bulk ceramics and showed similar conductivity and dielectric permittivity values. The study also revealed that measurement data at electrical field frequencies of up to 10 GHz were particularly important to correctly estimate electrical properties of GDC thin films, because at high temperatures the electric response of GDC film shifts to high frequencies (higher than 1 MHz at 600 K). The thin film sample preparation for high frequency measurements and fitting of impedance data by using relatively simple equivalent circuit model is presented. 相似文献
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Six new diterpene isocyanides have been isolated from a sponge ( sp.). Their structures support the biosynthetic suggestion for the formation of diisocyanoadociane reported from the same sponge. 相似文献
39.
A simple and efficient procedure has been developed for the derivatization of diuretic agents in human urine by direct extractive alkylation and their detection by gas chromatography-mass spectrometry. The procedure is an improvement over previous extractive alkylation methods because of the development of a simple clean-up step using a macroreticular acrylic copolymer (SM-7 resin) to remove the coextracted phase-transfer reagent from the organic phase after derivatization. With 1 ml of sample the method gives detection limits in the range 10-50 ng/ml for acetazolamide, probenecid, dichlorphenamide, hydroflumethiazide, furosemide, chlorthalidone, bumetanide, hydrochlorothiazide, quinethazone, bendroflumethiazide, metolazone and cyclopenthiazide. 相似文献
40.
Parr MK Kazlauskas R Schlörer N Opfermann G Piper T Schulze G Schänzer W 《Rapid communications in mass spectrometry : RCM》2008,22(3):321-329
In recent years products containing 6alpha-methylandrost-4-ene-3,17-dione have appeared on the sport supplement market. Scientific studies have proven aromatase inhibition and anabolic and mild androgenic properties; however, no preparation has been approved for medical use up to now. In sports 6alpha-methylandrost-4-ene-3,17-dione has to be classified as a prohibited substance according to the regulations of the World Anti-Doping Agency (WADA). For the detection of its misuse the metabolism was studied following the administration of two preparations obtained from the Internet (Formadrol and Methyl-1-Pro). Several metabolites as well as the parent compounds were synthesized and the structures of 3alpha-hydroxy-6alpha-methyl-5beta-androstan-17-one, 6alpha-methylandrost-4-ene-3,17-dione, and 5beta-dihydromedroxyprogesterone were confirmed by nuclear magnetic resonance (NMR) spectroscopy. The main metabolite, 3alpha-hydroxy-6alpha-methyl-5beta-androstan-17-one, was found to be excreted as glucuronide and was still detectable in microg/mL amounts until urine collection was terminated (after 25 h). Additionally, samples from routine human sports doping control had already tested positive for the presence of metabolites of 6alpha-methylandrost-4-ene-3,17-dione. Screening analysis can be easily performed by the existing screening procedure for anabolic steroids using 3alpha-hydroxy-6alpha-methyl-5beta-androstan-17-one as target substance (limit of detection <10 ng/mL). Its discrimination from the closely eluting drostanolone metabolite, 3alpha-hydroxy-2alpha-methyl-5alpha-androstan-17-one, is possible as the mono-TMS derivative. 相似文献