全文获取类型
收费全文 | 14749篇 |
免费 | 2266篇 |
国内免费 | 1333篇 |
专业分类
化学 | 10711篇 |
晶体学 | 179篇 |
力学 | 830篇 |
综合类 | 67篇 |
数学 | 1766篇 |
物理学 | 4795篇 |
出版年
2024年 | 50篇 |
2023年 | 323篇 |
2022年 | 561篇 |
2021年 | 565篇 |
2020年 | 673篇 |
2019年 | 579篇 |
2018年 | 506篇 |
2017年 | 440篇 |
2016年 | 699篇 |
2015年 | 729篇 |
2014年 | 752篇 |
2013年 | 1102篇 |
2012年 | 1257篇 |
2011年 | 1256篇 |
2010年 | 827篇 |
2009年 | 831篇 |
2008年 | 972篇 |
2007年 | 835篇 |
2006年 | 743篇 |
2005年 | 707篇 |
2004年 | 513篇 |
2003年 | 421篇 |
2002年 | 408篇 |
2001年 | 323篇 |
2000年 | 291篇 |
1999年 | 294篇 |
1998年 | 196篇 |
1997年 | 155篇 |
1996年 | 197篇 |
1995年 | 165篇 |
1994年 | 138篇 |
1993年 | 123篇 |
1992年 | 102篇 |
1991年 | 86篇 |
1990年 | 91篇 |
1989年 | 68篇 |
1988年 | 63篇 |
1987年 | 49篇 |
1986年 | 40篇 |
1985年 | 42篇 |
1984年 | 37篇 |
1983年 | 17篇 |
1982年 | 16篇 |
1981年 | 20篇 |
1980年 | 11篇 |
1979年 | 8篇 |
1976年 | 10篇 |
1975年 | 11篇 |
1971年 | 7篇 |
1969年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
91.
ICP-AES法测定富锗酵母中微量元素 总被引:2,自引:0,他引:2
本文采用美国LeemanLabs公司中阶梯光栅光谱仪测定了人工培养的富锗酵母中高含量锗及镁、铜、锌、铁、钾、钠等微量元素,研究了富锗样品的前处理方法,样品加标回收率在90%-103%之间,测量相对标准偏差:锗10%,镁、铜、锌、铁、钾、钠等元素小于7%。 相似文献
92.
93.
Manicka Dhanasekar Jianjun Han Qinghua Qin 《Finite Elements in Analysis and Design》2006,42(14-15):1314-1323
Much work on special elements that simplify geometrical modelling of structures containing holes, cracks and/ or inclusions has been reported extensively in the literature. This paper presents a hybrid-Trefftz element containing elliptic hole formulated using Hellinger–Reissner principle by employing trial functions based on the mapping technique and the Cauchy integral method. The element presented in this paper could be regarded as an improved formulation over Piltner [Special finite elements with holes and internal cracks, Int. J. Numer. Methods Eng. 21 (1985) 1471–1485] element because the chosen trail functions in this paper have provided relatively more stable solutions. The use of the element with other ordinary displacement-based finite elements has also yielded very accurate solutions even when very coarse meshes relative to the size of the elliptic hole have been used. 相似文献
94.
Zhishen Mo Lixiao Wang Hongfang Zhang Ping Han Baotong Huang 《Journal of Polymer Science.Polymer Physics》1987,25(9):1829-1837
Wide-angle X-ray scattering from presumed block copolymers of polypropylene (PP) and ethylene-propylene copolymer (EPR), i.e., PP-EPR and PP-EPR-PP, synthesized by sequential polymerization with δ-TiCl3? Et2AlCl, was examined and compared with WAXS of mechanical blends and chain-transfer mixtures of PP and EPR with comparable compositions. The peak at 2θ = 20° for both the copolymers and the mixtures was attributed to the γ modification of PP in EPR. A strong variation in the ratio of diffraction intensities I040/I110 of PP in block copolymers and mixtures was explained in terms of crystallite growth in different directions. Analysis of the patterns and calculation of crystallinity, crystallite size, and lattice parameters led to the conclusion that block structure existed in the prepared copolymers. 相似文献
95.
Guilin Wen Qing-Guo Wang Chong Lin Xu Han Guangyao Li 《Chaos, solitons, and fractals》2006,29(5):1142-1146
Synchronization under output feedback control with multiple random time delays is studied, using the paradigm in nonlinear physics—Chua’s circuit. Compared with other synchronization control methods, output feedback control with multiple random delay is superior for a realistic synchronization application to secure communications. Sufficient condition for global stability of delay-dependent synchronization is established based on the LMI technique. Numerical simulations fully support the analytical approach, in spite of the random delays. 相似文献
96.
N. Jiten Singh Adriana C. Olleta Anupriya Kumar Mina Park Hai-Bo Yi Indrajit Bandyopadhyay Han Myoung Lee P. Tarakeshwar Kwang S. Kim 《Theoretical chemistry accounts》2006,115(2-3):127-135
In earlier studies, the interactions of isolated ionic species with various solvents were investigated using ab initio calculations.
The ionic species investigated included cations (proton, hydronium, ammonium, and metal cations) and anions (single electron,
hydroxide, and halide anions). However in the present study, we investigate the interactions of these ionic species with the
solvent in the presence of other competing ionic species. We also elaborate on how the information obtained from these extensive
studies have been employed in designing and synthesizing various kinds of novel ionophores and receptors. 相似文献
97.
Xiujie Li Weiping Zhang Shenglin Liu Xiuwen Han Longya Xu Xinhe Bao 《Journal of molecular catalysis. A, Chemical》2006,250(1-2):94-99
The interfacial interaction of Mo species with the HBeta zeolite was studied by multinuclear MAS NMR, XRD and N2 adsorption. As proved by the quantitative 27Al MAS NMR, this interaction is so strong as to dealuminate the framework of HBeta, and leads to a new peak appearing at −14 ppm, which indicates the formation of crystalline Al2(MoO4)3. This can also be detected by XRD measurements when the Mo loading is as high as 9.0 wt.%. The corresponding quantitative 29Si and 1H MAS NMR spectra show that the amount of silanols and Brønsted acidic sites decrease obviously with increasing Mo loading. This also reveals an interaction between Mo species and HBeta support through an oxygen bridge resulting from condensation with the hydroxyls on the support. At higher Mo loadings, the interaction is so strong that it results in an extraction of aluminum from the zeolite framework, and subsequently appearance of Al2(MoO4)3 and loss of Brønsted acidic sites. These can be correlated to the low catalytic activity of Mo/HBeta in metathesis of ethylene and 2-butylene to propylene. 相似文献
98.
Hee Seok Choi Young Han Kim Shun Myung Shin 《Journal of polymer science. Part A, Polymer chemistry》2006,44(8):2428-2439
An in‐line monitoring device using a quartz crystal resonator for thin film polymerization was proposed, and its performance has been evaluated by implementing in the UV polymerization of 2‐hydroxyethyl methacrylate with a photoinitiator of 1‐chloroanthraquinone. Because the variation of resonant resistance of the resonator is proportional to the square root of viscosity change that is closely related to the polymerization degree, the resistance can be used as a measure of the polymerization degree. The resistance measurements were compared with the outcome of instrumental analyses of polymerization degree using an FTIR spectrometer and a gel permeation chromatograph. The experimental results showed that the resistance measurements were consistent with the experimental outcome of the instrumental analyses, and this indicates the effectiveness of the proposed device. Owing to the simplicity and availability of the resonator system, its wide utilization in the monitoring of a variety of film polymerization processes, including photoresistor application, is expected. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 2428–2439, 2006 相似文献
99.
100.
The solubility and diffusion coefficient of carbon dioxide in intermediate‐moisture starch–water mixtures were determined both experimentally and theoretically at elevated pressures up to 16 MPa at 50 °C. A high‐pressure decay sorption system was assembled to measure the equilibrium CO2 mass uptake by the starch–water system. The experimentally measured solubilities accounted for the estimated swollen volume by Sanchez–Lacombe equation of state (S‐L EOS) were found to increase almost linearly with pressure, yielding 4.0 g CO2/g starch–water system at 16 MPa. Moreover, CO2 solubilities above 5 MPa displayed a solubility increase, which was not contributed by the water fraction in the starch–water mixture. The solubilities, however, showed no dependence on the degree of gelatinization (DG) of starch. The diffusion coefficient of CO2 was found to increase with concentration of dissolved CO2, which is pressure‐dependent, and decrease with increasing DG in the range of 50–100%. A free‐volume‐based diffusion model proposed by Areerat was employed to predict the CO2 diffusivity in terms of pressure, temperature, and the concentration of dissolved CO2. S‐L EOS was once more used to determine the specific free volume of the mixture system. The predicted diffusion coefficients showed to correlate well with the measured values for all starch–water mixtures. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 607–621, 2006 相似文献