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71.
Nylon‐6/glass‐fiber (GF)/liquid‐crystalline‐polymer (LCP) ternary blends with different viscosity ratios were prepared with three kinds of nylon‐6 with different viscosities as matrices. The rheological behaviors of these blends were characterized with capillary rheometry. The morphology was observed with scanning electron microscopy and polarizing optical microscopy. This study showed that although LCP did not fibrillate in binary nylon‐6/LCP blends, LCP fibrillated to a large aspect ratio in some ternary blends after GF was added. The addition of 5 wt % LCP significantly reduced the melt viscosity of nylon‐6/GF blends to such an extent that some nylon‐6/GF/LCP blends had quite low viscosities, not only lower than those of neat resins and nylon‐6/GF blends but also lower than those of corresponding nylon‐6/LCP blends. The mutual influence of the morphology and rheological properties was examined. The great reduction of the melt viscosity was considered the result of LCP fibrillation. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1619–1627, 2004 相似文献
72.
The effect of α‐cyclodextrin (α‐CD) on the crystallization behavior of poly(3‐hydroxybutyrate) (PHB) was investigated with polarized optical microscopy, differential scanning calorimetry, and wide‐angle X‐ray diffraction. We found that the addition of α‐CD can greatly accelerate the crystallization of PHB and that α‐CD has a potential not only to enhance the nucleation but also to accelerate the crystallization of PHB. Compared to a conventional nucleation agent, such as talc, α‐CD is a natural product and has many advantages because it is environmentally friendly and safe to humans. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 3461–3469, 2004 相似文献
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76.
半自由声场环境下的声源重建和声场预测研究对声全息技术走向实际应用具有非常重要的意义.在提出基于分布源边界点法的半自由声场全息重建和预测方法的基础上,对此展开了实验研究.并将重建和预测的结果与常规方法重建和预测的结果进行了比较和讨论,说明了重建预测过程中反射声压的影响和考虑反射声压的必要性,证明了所提出方法在解决半自由声场环境下存在地面反射时的声源重建和声场预测时的有效性和准确性.还提出了采用奇异值截断滤波和Tikhonov正则化方法来削弱测量误差的影响,从而进一步优化了重建结果,提高了全息成像的可信度.
关键词:
声全息
半自由场
边界点
声辐射
反射声 相似文献
77.
稀土固体是重要的激光和光电子材料。目前 ,由于以宽带信号和太赫兹比特数据传输率为特征的信息技术的发展 ,稀土固体材料的相干瞬态动力学过程成为宽带与高速信息光子学的基本物理问题之一。研究了室温下稀土粉末样品Eu3+ ∶Y2 O3自由感应衰减的相干瞬态光谱 ,这有助于理解有效的光吸收动力学、激发态弛豫、相干能量传递和超短光脉冲在稀土固体中的传播。用一对紫外飞秒相干光脉冲作用于稀土粉末样品Eu3+ ∶Y2 O3,然后监测物质激发态的布居数随两个激发脉冲之间的延时的变化 ,测量到其自由感应衰减量子拍 (FID) ,从拍频周期分析确定了其能级精细结构 ,能级的退相时间长达皮秒量级。理论分析和实验结果符合得很好。对稀土离子的量子干涉的研究 ,表明其在受激受控光放大方面具有潜在的应用前景 相似文献
78.
The immobilization of proteins, especially receptor proteins commonly used in high through-put screening of drugs (HTS), have received great attention in recent years. There are many successful isothermal models for describing the adsorption of protein onto solid surface, such as Langmuir model, Bi-Langmuir model, Fowler model, Freundlich model, Freundlich-Langmuir model and Tekmin model etc. In all these models, Langmuir model was the most favorable one model accepted by many researchers, but the experimental results showed that it was not entirely fit to all adsorption behaviors. So new models were required for describing protein adsorption onto microspheres in different conditions.In our research, a novel isothermal model, including Langmuir and other adsorbing behaviors was presented basing on the holding degree of surface active sites and the interaction styles of protein immobilization. In Langmuir model, the adsorbing amount of protein was described as [PS] =Km[P]/1 + K[P], where [PS] was the concentration of adsorbed protein, [P] was the concentration of freeprotein at equilibrium state, and Km and K was constant. According to the interactions of protein and ligands, there were three patterns in the interactions of protein and ligands. On the similar assumption that the interaction of protein and microspheres were three styles, and based on the definition of the holding degree of surface active sites (Y), three adsorption behaviors could be described as Y K[ P ]φ/ K[P]φ+1 or ln K + φ ln[P] =ln(Y/1-Y) in which [P] was the concentration of free protein at equilibrium state, and φ and K was constant. Different scale of φ presented different adsorption behaviors, especially when φ was 1, the adsorption behavior was Langmuir adsorbing model. Figure I indicated the different adsorbing results in different adsorption behaviors (φ>1, φ<1,and φ=1). 相似文献
79.
JianXinCAO YiFengWANG GuoFangLAI ShiDeLUO 《中国化学快报》2004,15(7):797-800
From the dried aerial part ofParepigynumfuningesis Tsiang et P. T. Li (Apocynaceae),a new cardiac glucoside, named parefuningoside (1) had been isolated. Its structure was determined by means of hydrolysis and spectral analysis. 相似文献
80.
WeiMinSHI JianWU YiFengWU KaiXianQIAN 《中国化学快报》2004,15(12):1427-1429
A mono-funtionalised tetraphenylporphyrin (TPP) bearing valine moiety at the phenyl ring was synthesized for photocytotoxicity examination in four steps, starting from regiospecific mono-nitration of TPP at the phenyl ring. The in vitro photocytotoxicitic effect against SPC-Al adenocarcinona cell line was tested. 相似文献