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81.
P. Pütz A. Hedden P. Gensheimer D. Golish C. E. Groppi C. Kulesa G. Narayanan A. Lichtenberger J. W. Kooi N. Wadefalk S. Weinreb C. K. Walker 《International Journal of Infrared and Millimeter Waves》2006,27(10):1365-1379
We report on heterodyne measurements at submillimeter wavelengths using a receiver with a Superconductor-Insulator-Superconductor
(SIS) mixer device and a Microwave Monolithic Integrated Circuit (MMIC) cryogenic low noise amplifier (LNA) module integrated
into the same block. The mixer characterization presented in this work demonstrates the feasibility of operating a MMIC LNA
in close proximity to the SIS device without penalty in mixer performance due to heating effects. Verification of this functionality
is crucial for the ongoing development of SuperCam, a 64-pixel focal plane array receiver consisting of eight, 1 × 8 integrated
mixer/LNA modules. The test setup included a mixer block modified to accept a MMIC amplifier. Our tests show that the LNA
can be operated over a broad range of Vdrain voltages from 0.40–1.40 V, corresponding to dissipative powers of 2.6–29 mW. We observe no significant effect on the measured
uncorrected receiver noise temperatures in the 345 GHz band. 相似文献
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Dielectric observations on lithium hydrazinium sulphate have shown earlier that it is ferroelectric over a range of temperatures from below ?15° C. to above 80° C. and a new type of hydrogen bond rearrangement which would allow the protons to migrate along the chain has also been suggested by others. The infrared spectrum of LiH z S in the form of mull and as single crystal sections parallel and perpendicular to the ‘C’ axis exhibit about 21 well-defined absorption maxima. The position and the width of the maxima agree with the known structure of the crystal according to which the hydrazine group exists in the form of the hydrazinium ion, NH2·NH 3 + and the observed N+-H frequencies agree better with the new correlation curve given by R. S. Krishnan and K. Krishnan (1964). However it has been pointed out that from a comparative study of the new infrared spectra of hydrazonium sulphate and lithium ammonium sulphate that the absorption band at 969 cm.?1 is due to N-N stretching vibration and that the fairly intense band between 2050–2170 cm.?1 is due to the bending vibrations of the NH 3 + group. 相似文献
86.
Cheng W Kuthirummal N Gosselin JL Sølling TI Weinkauf R Weber PM 《The journal of physical chemistry. A》2005,109(9):1920-1925
Local photoionization pathways and charge-transfer dynamics of 2-phenylethyl-N,N-dimethylamine (PENNA) are explored using the recently developed Rydberg fingerprint spectroscopy. PENNA, a molecule that derives its biological significance from its relation to neurotransmitters, has two ionization centers that are separated by an ethyl group. We ionize the molecule in various multiphoton ionization processes using different laser wavelengths. The Rydberg fingerprint spectrum reveals the local nature of the ionization process and identifies the center of charge. We discovered that the laser wavelength provides substantial control over the activation of the individual ionization centers. The resonant (2+1) ionization with 400-nm radiation is dominated by the ejection of an electron from the amine moiety. In contrast, the resonant (1+1) ionization with 266-nm radiation leads predominantly to an ion with the charge in the phenyl group. The clean separation of the two ionization processes allows the exploration of ultrafast charge-transfer dynamics ensuing from a specific starting state characterized by a charged phenyl moiety. The width of the corresponding spectral features suggests that the charge transfer proceeds on a femtosecond time scale, suggesting a strong coupling between the two lowest-energy electronic surfaces of the PENNA cation. 相似文献
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The infrared absorption spectra of glycine silver nitrate (GAgNO3) and glycine nitrate (GHNO3) show that the glycine group exists completely in the zwitter ion form in the former and in both forms in the latter. The spectrum of GAgNO3 at liquid air temperature did not reveal any striking change which can be attributed to a freezing of the rapid reorientation of the NH 3 + group taking place at higher temperatures. The position of the COO? stretching frequencies indicate that this group is co-ordinated only weakly to the Ag+ ion. The summation frequencies reported by Schroeder, Wier and Lippincott (1962) for AgNO3 were not observed in the present study on GAgNO3. It shows however that ferroelectricity in GAgNO3 is in all probability due to the motion of the Ag+ ion in the oxygen co-ordination polyhedron and is not directly connected with the ordering of the hydrogen bonds below Curie point. 相似文献
90.
T. M. Preethi M. Manukumara A. Narayanan 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2010,60(2):389-395
A three photon resonance arising due to
coherent population trapped (CPT) states in multi-level systems,
is experimentally shown to be a powerful spectral marker to detect interacting CPT states.
In systems showing N type or double Λ type level configurations, these absorption resonances
can be used to identify spectral positions of maximal interactions between competing CPT ground states.
The contrast
of the absorption resonance serves to identify even partially destructive interactions between the CPT states, eliminating
the need for strong resonant changes of ground state coherence for identification. We demonstrate this effect in a room
temperature, gaseous collection of 87Rb. atoms. Three laser fields interact with a
double Λ configuration in the Zeeman degenerate levels of the ground state 5S1/2S_{1/2}, F = 1
and those of the excited states 5P3/2P_{3/2}, F = 0,1, around the D2 line.
The three-photon resonance is studied in the
counter-propagating third field when the other two co-propagating fields
satisfy the two-photon resonance condition necessary for creation of CPT
states. We envisage that this absorption feature in the third field, can become a veritable tool to quantify degradation of
CPT induced effects in engineered quantum states using multi-level systems. 相似文献