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81.
82.
83.
Jaemin Lee Byung‐Jun Jung Sang Kyu Lee Jeong‐Ik Lee Hoon‐Je Cho Hong‐Ku Shim 《Journal of polymer science. Part A, Polymer chemistry》2005,43(9):1845-1857
We report here the synthesis via Suzuki polymerization of two novel alternating polymers containing 9,9‐dioctylfluorene and electron‐withdrawing 4,4′‐dihexyl‐2,2′‐bithiazole moieties, poly[(4,4′‐dihexyl‐2,2′‐bithiazole‐5,5′‐diyl)‐alt‐(9,9‐dioctylfluorene‐2,7‐diyl)] (PHBTzF) and poly[(5,5′‐bis(2″‐thienyl)‐4,4′‐dihexyl‐2,2′‐bithiazole‐5″,5″‐diyl)‐alt‐(9,9‐dioctylfluorene‐2,7‐diyl)] (PTHBTzTF), and their application to electronic devices. The ultraviolet–visible absorption maxima of films of PHBTzF and PTHBTzTF were 413 and 471 nm, respectively, and the photoluminescence maxima were 513 and 590 nm, respectively. Cyclic voltammetry experiment showed an improvement in the n‐doping stability of the polymers and a reduction of their lowest unoccupied molecular orbital energy levels as a result of bithiazole in the polymers' main chain. The highest occupied molecular orbital energy levels of the polymers were ?5.85 eV for PHBTzF and ?5.53 eV for PTHBTzTF. Conventional polymeric light‐emitting‐diode devices were fabricated in the ITO/PEDOT:PSS/polymer/Ca/Al configuration [where ITO is indium tin oxide and PEDOT:PSS is poly(3,4‐ethylenedioxythiophene) doped with poly(styrenesulfonic acid)] with the two polymers as emitting layers. The PHBTzF device exhibited a maximum luminance of 210 cd/m2 and a turn‐on voltage of 9.4 V, whereas the PTHBTzTF device exhibited a maximum luminance of 1840 cd/m2 and a turn‐on voltage of 5.4 V. In addition, a preliminary organic solar‐cell device with the ITO/PEDOT:PSS/(PTHBTzTF + C60)/Ca/Al configuration (where C60 is fullerene) was also fabricated. Under 100 mW/cm2 of air mass 1.5 white‐light illumination, the device produced an open‐circuit voltage of 0.76 V and a short‐circuit current of 1.70 mA/cm2. The fill factor of the device was 0.40, and the power conversion efficiency was 0.52%. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 1845–1857, 2005 相似文献
84.
Sang Eun Shim Sunhye Yang Hyang Hee Choi Soonja Choe 《Journal of polymer science. Part A, Polymer chemistry》2004,42(4):835-845
Fully crosslinked, stable poly(styrene‐co‐divinylbenzene) microspheres, which are composed of various concentrations of divilylbenzene from 5 to 75 mol % based on styrene monomer, were prepared without a significant particle coagulation by the precipitation polymerization. The number‐average particle diameter ranged from 3.5 to 2.8 μm and decreased with an increasing concentration of divinylbenzene in monomer. In addition, the coefficient of variation of the microspheres was slightly reduced with the increasing concentration of divinylbenzene. The circularity and the measured specific surface area indicated that lesser particles are coagulated because of the improved stability of individual particles at a high divinylbenzene concentration and that the resulting particles have a smooth surface without micropores. The glass‐transition temperature was not observed for all microspheres formed from the range of divinylbenzene concentrations. In addition, the onset of the thermal‐degradation temperature was increased from 339.8 to 376.9 °C upon higher contents of divinylbenzene. On the basis of the DSC and thermogravimetric data, the polymer microspheres prepared by the precipitation polymerization possessed a fully crosslinked structure and highly enhanced thermal stability. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 835–845, 2004 相似文献
85.
Evolution of G-band modes of single metallic carbon nanotubes with the Fermi level shift is examined by simultaneous Raman and electron transport studies. Narrow Lorentzian line shape and upshifted frequencies are observed near the van Hove singularities. However, all G modes soften and broaden at the band crossing point. The concurrent appearance of an asymmetric Fano line shape at this point indicates that phonon-continuum coupling is intrinsic to single metallic tubes. The apparent Lorentzian line shapes of as-synthesized metallic tubes are induced by O2 adsorption causing the Fermi level shift. 相似文献
86.
Formation of a Syndiotactic Organic Polymer Inside a MOF by a [2+2] Photo‐Polymerization Reaction 下载免费PDF全文
Dr. In‐Hyeok Park Dr. Raghavender Medishetty Hyeong‐Hwan Lee Caroline Evania Mulijanto Hong Sheng Quah Prof. Shim Sung Lee Prof. Jagadese J. Vittal 《Angewandte Chemie (International ed. in English)》2015,54(25):7313-7317
Getting suitable crystals for single‐crystal X‐ray crystallographic analysis still remains an art. Obtaining single crystals of metal–organic frameworks (MOFs) containing organic polymers poses even greater challenges. Here we demonstrate the formation of a syndiotactic organic polymer ligand inside a MOF by quantitative [2+2] photopolymerization reaction in a single‐crystal‐to‐single‐crystal manner. The spacer ligands with trans,trans,trans‐conformation in the pillared‐layer MOF with guest water molecules in the channels, undergo pedal motion to trans,cis,trans‐conformation prior to [2+2] photo‐cycloaddition reaction and yield single crystals of MOF containing two‐dimensional coordination polymers fused with the organic polymer ligands. We also show that the organic polymer in the single crystals can be depolymerized reversibly by cleaving the cyclobutane rings upon heating. These MOFs also show interesting photoluminescent properties and sensing of small organic molecules. 相似文献
87.
Won Sohn Jonghwa Kim So Hee Kang Se Ra Yang Ju-Yeon Cho Hyun Chin Cho Sang Goon Shim Yong-Han Paik 《Experimental & molecular medicine》2015,47(9):e184
Recent studies have shown that circulating microRNAs are a potential biomarker in various types of malignancies. The aim of this study was to investigate the feasibility of using serum exosomal microRNAs as novel serological biomarkers for hepatocellular carcinoma (HCC) in patients with chronic hepatitis B (CHB). We measured the serum exosomal microRNAs and serum circulating microRNAs in patients with CHB (n=20), liver cirrhosis (LC) (n=20) and HCC (n=20). Serum exosomal microRNA was extracted from 500 μl of serum using an Exosome RNA Isolation kit. The expression levels of microRNAs were quantified by real-time PCR. The expression levels of selected microRNAs were normalized to Caenorhabditis elegans microRNA (Cel-miR-39). The serum levels of exosomal miR-18a, miR-221, miR-222 and miR-224 were significantly higher in patients with HCC than those with CHB or LC (P<0.05). Further, the serum levels of exosomal miR-101, miR-106b, miR-122 and miR-195 were lower in patients with HCC than in patients with CHB (P=0.014, P<0.001, P<0.001 and P<0.001, respectively). There was no significant difference in the levels of miR-21 and miR-93 among the three groups. Additionally, the serum levels of circulating microRNAs showed a smaller difference between HCC and either CHB or LC. This study suggests that serum exosomal microRNAs may be used as novel serological biomarkers for HCC. 相似文献
88.
Gold Nanorod–Photosensitizer Complex Obtained by Layer‐by‐Layer Method for Photodynamic/Photothermal Therapy In Vitro 下载免费PDF全文
Seung Beom Kim Tae Heon Lee Prof. Il Yoon Prof. Young Key Shim Prof. Woo Kyoung Lee 《化学:亚洲杂志》2015,10(3):563-567
Gold nanorod (GNR)–photosensitizer (PS) complex was prepared using anionic PS (sodium salt of purpurin‐18) and cationic poly(allylamine hydrochloride) by layer‐by‐layer method, and was characterized by transmission electron microscopy, UV‐vis spectroscopy, and zeta potential. The GNR–PS complex is a promising agent for synergistic (photothermal and photodynamic) therapy (PTT/PDT), in which PTT generates heat as well as operates the PS release which maximize the following PDT activity. The combined dual therapy, PTT followed by PDT, exhibits a significantly higher photocytotoxicity result based on synergistic effect of hyperthermia from PTT as well as singlet oxygen photogeneration from PDT. 相似文献
89.
To date, there is no method to measure non-destructively the modulus of trabeculae within cancellous bone, whilst retaining
its structural integrity. In this study ultrasonic scanning, coupled with microCT imaging, is employed to determine trabeculae
modulus along the three major anatomical axes non-destructively. The proposed method allows cancellous bone specimens to remain
intact, for possible use in subsequent studies. Volume rendering of the microCT images allows three-dimensional visualization
of cancellous bone specimens to be tested. This facilitates trabeculae selection and accurate measurement of distance traveled
by the ultrasonic wave, thus yielding a good degree of confidence in the acoustic velocity measured. For all the three principal
anatomical directions, the measured acoustic speeds ranged from 2,115 to 3,077 m/s, giving an average of 2,505 m/s. Average
wave velocities in the superior–inferior, medial–lateral and anterior–posterior anatomical directions were found to be 2,295,
2,469 and 2,754 m/s, respectively; the differences corresponding to the three directions do not appear to be significant.
Subsequently, the modulus was then determined using elastic wave propagation theory. 相似文献
90.
An experimental study is undertaken to examine the dynamic stress–strain characteristics of ligaments from the human cervical
spine (neck). Tests were conducted using a tensile split Hopkinson bar device and the engineering strain rates imposed were
of the order of 102∼103/s. As ligaments are extremely soft and pliable, specialized test protocols applicable to Hopkinson bar testing were developed
to facilitate acquisition of reliable and accurate data. Seven primary ligaments types from the cervical spines of three male
cadavers were subjected to mechanical tests. These yielded dynamic stress–strain curves which could be approximated by empirical
equations. The dynamic failure stress/load, failure stain/deformation, modulus/stiffness, as well as energy absorption capacity,
were obtained for the various ligaments and classified according to their location, the strain rate imposed and the cadaveric
source. Compared with static responses, the overall average dynamic stress–strain behavior foreach type of ligament exhibited
an elevation in strength but reduced elongation. 相似文献