排序方式: 共有77条查询结果,搜索用时 15 毫秒
61.
Murphy JM Lawrence JD Kawamura K Incarvito C Hartwig JF 《Journal of the American Chemical Society》2006,128(42):13684-13685
We report the regiospecific, ruthenium-catalyzed borylation of saturated terminal C-H bonds. Alkylboronates were obtained in 78-98% yields. The borylations of alkanes, trialkylamines, protected alcohols, and fluoroalkanes occurred regiospecifically at the methyl group that is least sterically hindered. In contrast to most organometallic C-H activation, the reactions of alkanes occurred in higher yields than the reactions of arenes. Reactions were conducted that probed steric and electronic effects on the alkyl borylation. These reactions showed that the borylation occurred preferentially at the methyl group that is least sterically hindered and most electron-deficient. Ruthenium compounds containing boryl ligands were synthesized, and one was characterized by X-ray crystallography. One of these compounds contained a rare bridging boryl ligand and served as a catalyst precursor for the borylation of octane. 相似文献
62.
Zhong Z Highfield J Lin M Teo J Han YF 《Langmuir : the ACS journal of surfaces and colloids》2008,24(16):8576-8582
CO oxidation and decomposition behaviors over nanosized 3% Au/alpha-Fe2O3 catalyst and over the alpha-Fe2O3 support were studied in situ via thermogravimetry coupled to on-line FTIR spectroscopy (TG-FTIR), which was used to obtain temperature-programmed reduction (TPR) curves and evolved gas analysis. The catalyst was prepared by a sonication-assisted Au colloid based method and had a Au particle size in the range of 2-5 nm. Carburization studies of H 2-prereduced samples were also made in CO gas. According to gravimetry, for the 3% Au/alpha-Fe2O3 catalyst, there were three distinct stages of CO interaction with the Au catalyst but only two stages for the catalyst support. At low temperatures (相似文献
63.
Perkas N Teo J Shen S Wang Z Highfield J Zhong Z Gedanken A 《Physical chemistry chemical physics : PCCP》2011,13(34):15690-15698
The preferential oxidation (PROX) of CO in the presence of H(2) is an important step in the production of pure H(2) for industrial applications. In this report, two sonochemical methods (S1 and S2) were used to prepare highly dispersed Ru catalysts supported on mesoporous TiO(2) (TiO(2)(MSP)) for the PROX reaction, in which a reaction gas mixture containing 1% CO + 1% O(2) + 18% CO(2) + 78% H(2) was used. The supported Ru catalysts performed better than the supported Au and Pt catalysts, and the S1 and S2 methods are superior to the impregnation method. The Ru/TiO(2)(MSP) catalysts were active for the PROX reaction below 200 °C and good for the methanation reactions of CO and CO(2) above 200 °C. The presence of residual chlorine in the catalysts severely suppressed their PROX reaction activity, and a higher dispersion of Ru particles led to better catalytic performances. The addition of Au in the Ru/TiO(2)(MSP) catalyst also caused a poorer catalytic activity for both the PROX and the methanation reactions. TPR results showed that in the active catalysts prepared by the S1 and S2 methods, the well dispersed Ru particles, after calcination in air, had a stronger interaction with the support than those in the catalyst prepared by the impregnation method and in the Au-Ru/TiO(2)(MSP) catalyst. In situ CO absorption experiments performed with the diffusion reflectance Fourier transform infra red (DRIFT) method showed that the bridged adsorbed CO species on isolated Ru(0) sites correlated with the catalytic performances, indicating that these isolated Ru(0) sites are the most active sites of the Ru/TiO(2)(MSP) catalysts in the PROX reaction. 相似文献
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65.
Microwire electrodes are presented as an alternative to screen-printed electrodes for detection in electrochemical paper-based analytical devices (ePADs). Compared to carbon ink electrodes, microwire electrodes offer lower resistance and a significant increase in current density relative to carbon ink electrodes. Various microwire compositions and diameters, including 30 μm Pt, 25 μm Au, 18 μm Pt with 8% W, and 15 μm Pt with 20% Ir, were tested and compared to theoretically predicted behavior. The measured current in static solution was below predicted levels for cylindrical microelectrodes but greater than levels predicted for hemi-cylindrical electrodes most likely as a result of the proximity of the electrode to the paper surface. Furthermore, the current response was indicative of semi-thin layer behavior, likely due to the confined solution volume in the paper. After electrode characterization, a device was developed for the non-enzymatic detection of glucose, fructose, and sucrose using a Cu electrode in alkaline solution. The limits of detection for glucose, fructose, and sucrose were 270 nM, 340 nM, and 430 nM, respectively, which are significantly below sugar concentrations found in sweetened beverages or glucose levels in serum. 相似文献
66.
Beer L Brusso JL Haddon RC Itkis ME Kleinke H Leitch AA Oakley RT Reed RW Richardson JF Secco RA Yu X 《Journal of the American Chemical Society》2005,127(51):18159-18170
A synthetic sequence to salts of N-alkylated pyridine-bridged 1,2,3-thiaselenazolo-1,2,3-thiaselenazolylium cations [2]+ (R1 = Me, Et; R2 = H) is described. The corresponding radicals 2 (R1 = Me, Et; R2 = H) can be generated from the cations by chemical or electrochemical reduction. Crystals of the two radicals are isostructural and consist of interpenetrating pi-stacked arrays of closed-shell Se-Se sigma-bonded dimers [2]2 laced together with numerous short intermolecular Se- - -Se, Se- - -S, and Se- - -N contacts. Variable-temperature magnetic, conductivity, and near-infrared optical measurements indicate that the bulk materials behave as small band gap semiconductors with room-temperature conductivities sigma(RT) near 10(-6) S cm(-1) and thermal activation energies Ea of 0.32 eV (R1 = Me) and 0.36 eV (R1 = Et). LMTO band structure calculations on both compounds are consistent with this interpretation. The application of external pressure leads to dramatic increases in conductivity; at 4 GPa sigma(RT) reaches a value near 10(-1) S cm(-1) for R1 = Me and 10(-2) S/cm for R1 = Et. The conductivity remains activated for both compounds, but for R1 = Me the activation energy Ea is reduced to near 0.03 eV at 5 GPa, suggestive of a weakly metallic state. 相似文献
67.
Beer L Brusso JL Haddon RC Itkis ME Leitch AA Oakley RT Reed RW Richardson JF 《Chemical communications (Cambridge, England)》2005,(12):1543-1545
Resonance stabilized bis-1,2,3-thiaselenazolyl radicals associate in the solid state to afford Se-Se sigma-bonded dimers. 相似文献
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69.
Jaclyn Anderson 《Journal of Number Theory》2008,128(9):2591-2615
For a positive integer t, a partition is said to be a t-core if each of the hook numbers from its Ferrers-Young diagram is not a multiple of t. In 1996, Granville and Ono proved the t-core partition conjecture, that at(n), the number of t-core partitions of n, is positive for every nonnegative integer n as long as t?4. As part of their proof, they showed that if p?5 is prime, the generating function for ap(n) is essentially a multiple of an explicit Eisenstein Series together with a cusp form. This representation of the generating function leads to an asymptotic formula for ap(n) involving L-functions and divisor functions. In 1999, Stanton conjectured that for t?4 and n?t+1, at(n)?at+1(n). Here we prove a weaker form of this conjecture, that for t?4 and n sufficiently large, at(n)?at+1(n). Along the way, we obtain an asymptotic formula for at(n) which, in the cases where t is coprime to 6, is a generalization of the formula which follows from the work of Granville and Ono when t=p?5 is prime. 相似文献
70.
The effect of selenium incorporation on the bandwidth and conductivity of neutral radical conductors
Beer L Brusso JL Haddon RC Itkis ME Oakley RT Reed RW Richardson JF Secco RA Yu X 《Chemical communications (Cambridge, England)》2005,(46):5745-5747
The first example of an undimerized pi-stacked bis-1,2,3-thiaselenazolyl radical displays improved bandwidth and conductivity relative to an isostructural bis-1,2,3-dithiazolyl. 相似文献