全文获取类型
收费全文 | 543篇 |
免费 | 10篇 |
国内免费 | 6篇 |
专业分类
化学 | 407篇 |
晶体学 | 3篇 |
力学 | 1篇 |
数学 | 75篇 |
物理学 | 73篇 |
出版年
2020年 | 5篇 |
2019年 | 6篇 |
2018年 | 3篇 |
2017年 | 5篇 |
2016年 | 7篇 |
2015年 | 4篇 |
2014年 | 6篇 |
2013年 | 10篇 |
2012年 | 23篇 |
2011年 | 33篇 |
2010年 | 14篇 |
2009年 | 10篇 |
2008年 | 30篇 |
2007年 | 32篇 |
2006年 | 29篇 |
2005年 | 34篇 |
2004年 | 27篇 |
2003年 | 25篇 |
2002年 | 23篇 |
2001年 | 3篇 |
2000年 | 15篇 |
1998年 | 8篇 |
1997年 | 8篇 |
1996年 | 8篇 |
1995年 | 5篇 |
1994年 | 12篇 |
1993年 | 9篇 |
1992年 | 11篇 |
1991年 | 5篇 |
1990年 | 4篇 |
1989年 | 12篇 |
1988年 | 7篇 |
1987年 | 7篇 |
1985年 | 11篇 |
1984年 | 11篇 |
1982年 | 10篇 |
1981年 | 7篇 |
1980年 | 3篇 |
1979年 | 13篇 |
1978年 | 10篇 |
1977年 | 4篇 |
1976年 | 4篇 |
1975年 | 4篇 |
1974年 | 5篇 |
1973年 | 6篇 |
1971年 | 4篇 |
1969年 | 3篇 |
1968年 | 3篇 |
1967年 | 3篇 |
1966年 | 3篇 |
排序方式: 共有559条查询结果,搜索用时 62 毫秒
91.
Koizumi H Kimata Y Shiraishi Y Hirai T 《Chemical communications (Cambridge, England)》2007,(18):1846-1848
A polymeric photosensitizer, poly(NIPAM-co-RB), consisting of N-isopropylacrylamide and rose bengal units, demonstrates a temperature-controlled changeable oxygenation selectivity by singlet oxygen in water. 相似文献
92.
Hidenori Hanaoka Masaaki Nabika Kazunori Yanagi Akio Imai 《Journal of organometallic chemistry》2007,692(21):4717-4724
A series of titanium complexes bearing a SiMe2-bridged phenoxy-cyclopentadienyl ligand were synthesized and characterized, and their catalytic behavior for copolymerization of ethylene and 1-hexene was investigated. Treatment of dimethylsilyl(2,3,4,5-tetramethylcyclopentadienyl)(3-tert-butyl-5-methyl-2-phenoxy)-titanium dichloride (1) with appropriate nucleophiles afforded dimethoxy complex 2, dimethyl complex 3, and dibenzyl complex 4. Standing a toluene solution of 2 in air afforded a dinuclear μ-oxo complex 5 as a single isomer. 1,3-Diene complexes 6-8 were prepared by reaction of 1 with the corresponding 1,3-dienes in the presence of 2 equiv. of n-BuLi. X-ray analysis of 1,4-diphenyl-1,3-butadiene complex 6 revealed that the diene ligand coordinates to titanium in s-cis fashion with a prone orientation. The newly prepared titanium complexes were applied to copolymerization of ethylene and 1-hexene upon activation with AliBu3 and [C6H5NMe2H][B(C6F5)4]. It was found that the alkyl complexes 3-4 and the diene complexes 6-8 showed higher activities than 1 at elevated temperature. 相似文献
93.
Shimizu H Fujimoto K Furusyo M Maeda H Nanai Y Mizuno K Inouye M 《The Journal of organic chemistry》2007,72(4):1530-1533
We newly prepared para- and meta-linked alkynylpyrene oligomers and examined their photophysical properties. Oligomerization of monomeric building blocks was performed by CuI-promoted oxidative coupling reaction. The resulting oligomers mainly consist of 2-mer to 6-mer that were assigned on the basis of MALDI-TOF mass spectra, and the 2-mer, 3-mer, and 4-mer were isolated and fully characterized. From their absorption and fluorescence spectra, the para-linked oligomers were found to be somewhat pi-conjugated compared with meta-linked ones, and the fluorescence quantum yields decreased with increasing oligomer length (Phif = 0.79-0.55). 相似文献
94.
Serizawa T Sawada T Matsuno H 《Langmuir : the ACS journal of surfaces and colloids》2007,23(22):11127-11133
We investigated polymer-binding 7-mer peptides that recognize differences in the polymer stereoregularity of all-purpose poly(methyl methacrylate)s (PMMAs) with simple chemical structures. Quantitative surface plasmon resonance measurements detected association/dissociation processes of the peptides against PMMA film surfaces, followed by an estimation of kinetic parameters such as association/dissociation rate constants and affinity constants. Greater association and smaller dissociation constants of the peptides were observed against a target isotactic PMMA than the structurally similar reference syndiotactic PMMA, followed by greater affinity constants against the target. A c02 peptide composed of the Glu-Leu-Trp-Arg-Pro-Thr-Arg sequence showed the greatest affinity constant (2.8x10(5) M(-1)) for the target, which was 41-fold greater than that for the reference, thus demonstrating extremely high peptide specificities. The substitution of each amino acid of the c02 peptide to Ala (Ala scanning) clearly revealed the essential amino acids for the affinity constants; the essential order was Pro5>Thr6>Arg7>Glu1>Arg4. In fact, the shorter 4-mer peptide composed of the C-terminal Arg-Pro-Thr-Arg sequence of the c02 peptide still demonstrated strong target specificity, although the N-terminal 4-mer peptide Glu-Leu-Trp-Arg completely lost its specificity. The possible conformations modeled with Molecular Mechanics supported the significance of the Arg-Pro-Thr-Arg sequence. The thermodynamic parameters of the c02 peptide suggested an induced fit mechanism for the specific affinity. The present affinity analyses of polymer-recognizing peptides revealed significant and general information that was essential for potential applications in peptidyl nanomaterials. 相似文献
95.
96.
A compact permanent‐magnet system for measuring magnetic circular dichroism in resonant inelastic soft X‐ray scattering
下载免费PDF全文
![点击此处可从《Journal of synchrotron radiation》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Jun Miyawaki Shigemasa Suga Hidenori Fujiwara Hideharu Niwa Hisao Kiuchi Yoshihisa Harada 《Journal of synchrotron radiation》2017,24(2):449-455
A compact and portable magnet system for measuring magnetic dichroism in resonant inelastic soft X‐ray scattering (SX‐RIXS) has been developed at the beamline BL07LSU in SPring‐8. A magnetic circuit composed of Nd–Fe–B permanent magnets, which realised ~0.25 T at the center of an 11 mm gap, was rotatable around the axis perpendicular to the X‐ray scattering plane. Using the system, a SX‐RIXS spectrum was obtained under the application of the magnetic field at an angle parallel, nearly 45° or perpendicular to the incident X‐rays. A dedicated sample stage was also designed to be as compact as possible, making it possible to perform SX‐RIXS measurements at arbitrary incident angles by rotating the sample stage in the gap between the magnetic poles. This system enables facile studies of magnetic dichroism in SX‐RIXS for various experimental geometries of the sample and the magnetic field. A brief demonstration of the application is presented. 相似文献
97.
Ryuta Nishida Katsuyoshi Kakinuma Hanako Nishino Takeo Kamino Hisao Yamashita Masahiro Watanabe Hiroyuki Uchida 《Solid State Ionics》2009,180(14-16):968-972
Aiming at SOFC anode applications, we have synthesized nanometer-sized nickel catalysts supported on hollow spherical particles of samaria-doped ceria (Ni/SDC) by spraying a mixed solution of nickel, samarium, and cerium nitrates into an atmospheric pressure plasma. The as-prepared particles consisted of SDC (average diameter dSDC = ca. 0.8 µm) and uniformly dispersed nanometer-sized NiO particles. When reduced in H2 at 800 °C or 1000 °C, Ni nanoparticles (average diameter dNi = 34 nm) were found to be embedded uniformly into the SDC surface. 相似文献
98.
S. Furuichi K. Yanagi K. Kuriyama 《Journal of Mathematical Analysis and Applications》2009,356(1):179-1156
We introduce a generalized Wigner-Yanase skew information and then derive the trace inequality related to the uncertainty relation. This inequality is a non-trivial generalization of the uncertainty relation derived by S. Luo for the quantum uncertainty quantity excluding the classical mixture. In addition, several trace inequalities on our generalized Wigner-Yanase skew information are argued. 相似文献
99.
To model electron transport through a molecular junction, we propose an efficient method using an ab initio self-consistent nonequilibrium Green's function theory combined with density functional theory. We have adopted a model close to the extended molecule approach, due to its flexibility, but have improved on the problems relating to molecule-surface couplings and the long-range potential via a systematic procedure for the same ab initio level as that of Green's function. The resulting algorithm involves three main steps: (i) construction of the embedding potential; (ii) perturbation expansion of Green's function in the molecular orbital basis; and (iii) truncation of the molecular orbital space by separating it into inactive, active, and virtual spaces. The above procedures directly reduce the matrix size of Green's function for the self-consistent calculation step, and thus, the algorithm is suitable for application to large molecular systems. 相似文献
100.
Ito Y Goto T Yamada S Matsumoto H Oka H Takahashi N Nakazawa H Nagase H Ito Y 《Journal of chromatography. A》2006,1108(1):20-25
Dual counter-current chromatography (dual CCC) has been successfully applied to rapid sample preparation for the simultaneous determination of residual carbaryl, fenobucarb and methomyl in vegetable oil and citrus fruit. The citrus fruit samples were extracted with n-hexane solution containing stable isotopically labeled internal standards (methomyl-d3, fenobucarb-d3 and carbaryl-d9), and applied to dual CCC using a two-phase solvent system of n-hexane-acetonitrile to purify the carbamate pesticides from aliphatic sample matrix. The coiled column was rotated at 420 rpm, the lower mobile phase was introduced through the head toward the tail, and the upper mobile phase in the opposite direction. Due to the high partition efficiency of dual CCC, the lower phase fraction collected from 2 to 5 min after injection could be subjected to flow-injection tandem mass spectrometry directly after concentration. Repetitive sample injection can be performed at high reproducibility without a risk of contamination from the compounds retained in the column. 相似文献