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41.
This paper presents the investigation results of the polarized IR spectra of 3-hydroxybenzaldehyde and 4-hydroxybenzaldehyde crystals measured at 293 and 77 K. Analysis of the results concerned the linear dichroic, H/D isotopic and temperature effects observed in the spectra of the hydrogen and deuterium bond at the frequency ranges of the νO–H and the νO–D bands, respectively. The main spectral properties of the crystals were interpreted in terms of the “strong-coupling” theory on the basis of the hydrogen bond dimer model. The spectra revealed that the strongest vibrational exciton coupling involved the closely-spaced hydrogen bonds, each belonging to a different chain of associated molecules. The reason for two different crystalline systems, are characterized by almost identical νO–H and νO–D band shapes, is explained. It was proved that a random distribution of the protons and deuterons took place in the lattices of the isotopically diluted crystals. 相似文献
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The interaction of atomic antihydrogen with helium has been studied within the Born-Oppenheimer approximation. The linear combination of explicitly correlated Gaussian functions was used as the ansatz for the wave function of light particles. The potential energy curve with the minimum at 3.63 bohr and the barrier at 2.42 bohr has been obtained. 相似文献
44.
Jan Halkiewicz Henryk Lamparczyk Aleksander Radecki 《Fresenius' Journal of Analytical Chemistry》1985,320(6):577-580
Summary Fifteen Dialkyldithiocarbamate complexes each of copper(II) and Ni(II) have been prepared and the retention times of these complexes have been measured on the non-polar OV-101 phase and the polar NGA and OV-225 phases. The relationship has been studied between the retention characteristics of the complexes and their structure. The lenght of the alkyl substituent, regarded as a steric hindrance, turned out to affect the retention of the complexes on the non-polar phases.
Verhalten von Kupfer(II)- und Nickel(II)-dialkyldithiocarbamaten auf polaren und unpolaren stationären Phasen
Zusammenfassung Je 15 Dialkyldithiocarbamatkomplexe von Kupfer(II) und Nickel(II) wurden dargestellt und ihre Retentionszeiten auf der unpolaren Phase OV-101 sowie den polaren Phasen NGA und OV-225 gemessen. Die Beziehung zwischen der Retentionscharakteristik der Komplexe und ihrer Struktur wurde untersucht. Es zeigte sich, daß die Länge des Alkylsubstituenten (als sterische Hinderung) die Retention auf der unpolaren Phase beeinträchtigt.相似文献
45.
The perturbation energies for model ammonia and imidazole systems have been calculated using all valence molecular orbitais in a LCMO formulation. With semi-empirical parametrization the method was extended to the adenine-thymine and guanine-cytosine base pairs. The results indicate that the σ-σ interactions are dominant, whereas the π-π component confers only a negligible contribution to the stabilization energy. 相似文献
46.
We have explored the opportunities for enhanced ratiometric pH sensing using the well-known carboxy seminaphthofluorescein (SNAFL-2) and silver island films (SiFs). Our results show that the metallic surfaces can provide up to a 40-fold increase in probe fluorescence intensity as compared to nonmetallic surfaces with the same probe coverage. However, while the S/N is significantly better for pH sensing, the emission wavelength ratiometric values are similar to that obtained in solution, due to the fact that the emission of both the acidic and basic forms of the probe are enhanced to similar extents. To the best of our knowledge this is the first report of enhanced ratiometric fluorescence sensing on metallic surfaces. 相似文献
47.
Shutao Chen Yunan Cui Henryk Hudzik 《Proceedings of the American Mathematical Society》2004,132(2):473-480
Criteria in order that an Orlicz space equipped with the Orlicz norm contains a linearly isometric copy (or an order linearly isometric copy) of (or ) are given.
48.
Henryk Michalewski 《Proceedings of the American Mathematical Society》2003,131(11):3601-3606
For a coanalytic-complete or -complete subspace of a Polish space we prove that there exists a continuous bijection of onto the Hilbert cube . This extends results of Pytkeev. As an application of our main theorem we give an answer to some questions of Arkhangelskii and Christensen.
Under the assumption of Projective Determinacy we also give some generalizations of these results to higher projective classes.
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