排序方式: 共有114条查询结果,搜索用时 375 毫秒
31.
Janin T. Offenloch Marvin Gernhardt Dr. James P. Blinco Dr. Hendrik Frisch Dr. Hatice Mutlu Prof. Dr. Christopher Barner-Kowollik 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(15):3700-3709
Catalyst-free and bond-forming light-induced reactions have seen an unprecedented renaissance in the realm of soft matter materials science due to their efficiency, spatio-temporal controllability and, sometimes, photoreversible nature. However, many of these reactions rely on the application of high energy UV light that can cause photo-degradation and is inapplicable in biological environments. If up-conversion systems or two-photon processes are to be avoided, strategies for red-shifting catalyst-free ligation technology are critically required. This Concept article introduces the reader to recent methods that lead to efficient, catalyst-free visible-light-induced ligation chemistry based on polyaromatic substituted photoreactive compounds—pyrene and anthracene—and, furthermore, emphasizes the broad and facile applicability of these molecules in polymeric material design. Concomitantly, we highlight that a careful action plot analysis of photochemical reactivity can provide deep insights into reactivity patterns, far beyond those suggested by the absorption spectrum. Indeed, we suggest that an action plot analysis is necessary for the evaluation of any photochemical system and its response to structural chemical changes. 相似文献
32.
Hatice Boylan Nils-Peter Skoruppa 《Abhandlungen aus dem Mathematischen Seminar der Universit?t Hamburg》2010,80(2):213-226
We derive an explicit formula for Hecke Gauss sums of quadratic number fields. As an immediate consequence we obtain a quadratic
reciprocity law in quadratic number fields which generalizes the classical one given by Hecke. The proofs use, apart from
the well-known formulas for ordinary Gauss sums, only elementary algebraic manipulations. 相似文献
33.
Geometry is one of the disciplines children involve within early years of their lives. However, there is not much information about geometry education in Turkish kindergarten classes. The current study aims to examine teachers’ perspectives on teaching geometry in kindergarten classes. The researchers inquired about teachers’ in-class experiences in geometry and asked a series of questions such as “what are the benchmarks in your kindergarten class?”; “what kind of tools and materials you use to teach geometry in your class?”; “what shape do you teach first in your kindergarten class?”; “what do you expect to hear when you asked your students ‘what is square’?”; “how do you teach rectangular?”. The study utilized one of the qualitative research methods, namely phenomenography, to collect the data and analyze the data. The study involved with eight kindergarten teachers who work in different schools in central Kutahya, Turkey. The researchers collected data by conducting face-to-face half-structured interviews. The findings of this phenomenographic research showed that kindergarten teachers have some difficulties in teaching geometry and have lack of knowledge and skills in teaching geometry in kindergarten classes. 相似文献
34.
Use of surfactants to remove water-based inks from plastic film: effect of calcium ion concentration and length of surfactant hydrophobe 总被引:1,自引:0,他引:1
Hatice?GecolEmail author John?F.?Scamehorn Sherril?D.?Christian Brian?P.?Grady Fred?E.?Riddell 《Colloid and polymer science》2004,283(2):154-163
Effective plastic film deinking could permit the reuse of recycled polymer to produce clear film, reduce solid waste for landfills, reduce raw material demand for polymer production, and aid process economics. In this study, the deinking of a commercial polyethylene film printed with water-based ink was studied using surfactants in the presence of hardness ions (calcium ions) at various pH levels. The electrostatic properties of ink particles in a washing bath were also investigated. Synthetic anionic surfactant or fatty acid soap in the presence of calcium ions at alkaline pH levels was found to be nearly as effective at deinking as cationic, nonionic, or amphoteric surfactants alone. However, adding calcium ions decreases the deinking effectiveness of cationic, nonionic, and amphoteric surfactants. Increasing the length of the ionic surfactant hydrophobe enhances deinking. Zeta potential measurements showed that water-based ink particles in water reach the point of zero charge (PZC) at a pH of about 3.6, above which ink particles are negatively charged, so cationic surfactant tends to adsorb better on the ink than anionic surfactant above the PZC in the absence of calcium. As the cationic surfactant concentration is varied between 0.005 and 25 mM, the zeta potential of the ink particles reverses from negative to positive owing to adsorption of cationic surfactant. For anionic surfactants, added calcium probably forms a bridge between the negatively charged ink and the negatively charged surfactant head groups, which synergizes adsorption of the surfactant and aids deinking. In contrast, calcium competes for adsorption sites with cationic and nonionic surfactants, which inhibits deinking. All the surfactants studied here disperse ink particles effectively in the washing bath above pH 3 except for the ethoxylated amine surfactant. 相似文献
35.
Hatice Yildirim 《Phosphorus, sulfur, and silicon and the related elements》2020,195(6):516-522
AbstractA set of bis(arylthio) substituted 5,8-quinolinedione derivatives were synthesized and investigated for their in vitro antimicrobial effect. The antibacterial and antifungal activities of 6,7-bis(arylthio)-5,8-quinolinedione (4a–f) and 6,7-bis(arylthio)-2-methyl-5,8-quinolinedione (5a–f) were evaluated against four gram-negative bacteria, three gram-positive bacteria, and three fungi strains. The bis(methoxyarylthio) 5,8-quinolinedione analogs presented better activity against especially gram-positive bacteria compared to bis(halogenarylthio) 5,8-quinolinedione analogs. Bis(3-methoxyarylthio) 5,8-quinolinedione (4e) had the same activity of the reference drug against Staphylococcus aureus. Bis(2-methoxyarylthio) 5,8-quinolinedione (4f) showed two-and-a half-fold better activity with 89.69?μM against Enterococcus faecalis, and two-fold better activity with 11.20?μM against Staphylococcus epidermidis. Bis(2-methoxyarylthio)-2-methyl-5,8-quinolinedione 5f exhibited five-fold higher antibacterial activity with 43.44?μM against E. faecalis and also eight-fold activity of the reference drug with 2.71?μM against S. epidermidis. 相似文献
36.
The behavior of proteins is closely related to the protonation states of the residues. Therefore, prediction and measurement of pKa are essential to understand the basic functions of proteins. In this work, we develop a new empirical scheme for protein pKa prediction that is based on deep representation learning. It combines machine learning with atomic environment vector (AEV) and learned quantum mechanical representation from ANI-2x neural network potential (J. Chem. Theory Comput. 2020, 16, 4192). The scheme requires only the coordinate information of a protein as the input and separately estimates the pKa for all five titratable amino acid types. The accuracy of the approach was analyzed with both cross-validation and an external test set of proteins. Obtained results were compared with the widely used empirical approach PROPKA. The new empirical model provides accuracy with MAEs below 0.5 for all amino acid types. It surpasses the accuracy of PROPKA and performs significantly better than the null model. Our model is also sensitive to the local conformational changes and molecular interactions.We developed new empirical ML model for protein pKa prediction with MAEs below 0.5 for all amino acid types. 相似文献
37.
We have experimentally studied polarization properties of the two-dimensional coupled photonic crystal microcavity arrays and observed a strong polarization dependence of the transmission and reflection of light from the structures-effects that can be employed in building miniaturized polarizing optical components. Moreover, by combining these properties with a strong sensitivity of the coupled bands on the surrounding refractive index, we have demonstrated a detection of small refractive-index changes in the environment, which is useful for construction of biochemical sensors. 相似文献
38.
Recep Özen Kutalmis Guven Hatice Can Metin Balci 《Journal of chemical crystallography》2004,34(7):477-481
The title compound 6-phenyl-4,6,8-triazatetracyclo[9.2.1.02,10.04,8]tetradec-2(10)-ene-5,7-dione (6) has been synthesized by the addition of 4-phenyl-1,2,4-triazole-3,5-dione (PTAD) to 2,3-dimethylenebicyclo[2.2.1]heptane. The cell parameters are a = 9.991(5), b = 11.754(9), c = 6.549(5) Å, = 101.08(7)°, = 103.31(5)°, = 98.24(5)°. The crystal structure of 6 was determined. The obtained geometrical parameters were highly correlated with the DFT calculations. The experimentally determined folding angle of the double bond was found to be 8.44°. The effect of the electron-withdrawing ability of nitrogen atom on the degree of pyramidalization is discussed. 相似文献
39.
40.
Beyler Çiğil Aslı Aydın Urucu Oya Birtane Hatice Kahraman Memet Vezir 《Cellulose (London, England)》2021,28(10):6439-6448
Cellulose - In the present study, a novel, eco-friendly, and simple polymeric adsorbent was obtained from cellulose acetate butyrate (CAB) and cysteine (Cys) to remove silver (I) ions in the... 相似文献