全文获取类型
收费全文 | 4408篇 |
免费 | 256篇 |
国内免费 | 106篇 |
专业分类
化学 | 3299篇 |
晶体学 | 20篇 |
力学 | 236篇 |
综合类 | 2篇 |
数学 | 525篇 |
物理学 | 688篇 |
出版年
2024年 | 4篇 |
2023年 | 24篇 |
2022年 | 73篇 |
2021年 | 128篇 |
2020年 | 157篇 |
2019年 | 207篇 |
2018年 | 252篇 |
2017年 | 203篇 |
2016年 | 356篇 |
2015年 | 229篇 |
2014年 | 300篇 |
2013年 | 559篇 |
2012年 | 378篇 |
2011年 | 345篇 |
2010年 | 273篇 |
2009年 | 217篇 |
2008年 | 248篇 |
2007年 | 174篇 |
2006年 | 123篇 |
2005年 | 94篇 |
2004年 | 106篇 |
2003年 | 65篇 |
2002年 | 55篇 |
2001年 | 21篇 |
2000年 | 23篇 |
1999年 | 20篇 |
1998年 | 13篇 |
1997年 | 3篇 |
1996年 | 11篇 |
1995年 | 12篇 |
1994年 | 7篇 |
1993年 | 7篇 |
1992年 | 9篇 |
1991年 | 4篇 |
1990年 | 5篇 |
1989年 | 7篇 |
1988年 | 5篇 |
1987年 | 2篇 |
1986年 | 3篇 |
1985年 | 7篇 |
1984年 | 6篇 |
1983年 | 6篇 |
1982年 | 3篇 |
1981年 | 3篇 |
1980年 | 4篇 |
1979年 | 2篇 |
1977年 | 4篇 |
1975年 | 3篇 |
1937年 | 2篇 |
1927年 | 3篇 |
排序方式: 共有4770条查询结果,搜索用时 78 毫秒
151.
In this study, a novel Cu-immobilized ionic liquid (IL)was designed, characterized, and employed as both promoter and solvent in the synthesis of some dihydropyrano[2,3-c]pyrazoles. The synthesized ionic liquid was characterized by 1H NMR, 13C NMR, FTIR, ICP and EDX analysis and showed high catalytic activity to proceed the synthesis of bioactive dihydropyrano[2,3-c]pyrazole derivatives. This method has the advantage of using the IL as a green medium for the synthesize of the products in high to excellent yields within short reaction times. 相似文献
152.
153.
Synthesis,characterization and application of 3‐methyl‐1‐sulfonic acid imidazolium tetrachloroferrate as nanostructured catalyst for the tandem reaction of β‐naphthol with aromatic aldehydes and amide derivatives
下载免费PDF全文
![点击此处可从《应用有机金属化学》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Ardeshir Khazaei Ahmad Reza Moosavi‐Zare Saeed Firoozmand Mohammad Reza Khodadadian 《应用有机金属化学》2018,32(2)
3‐methyl‐1‐sulfonic acid imidazolium tetrachloroferrate {[Msim]FeCl4} was prepared and fully characterized by fourier transform infrared spectroscopy (FT‐IR), X‐ray diffraction (XRD), thermal gravimetric analysis (TGA), differential thermal gravimetric (DTG), field emission scanning electron microscopy (FESEM), energy dispersive X‐ray analysis (EDX) and vibrating sample magnetometer (VSM) and used, as an efficient catalyst, for the tandem reaction of β‐naphthol with aromatic aldehydes and benzamide at 110 °C under solvent‐free conditions to give 1‐amidoalkyl‐2‐naphthols in high yields and very short reaction times. 相似文献
154.
155.
156.
157.
Patrick Homenya Markus Messerschmidt Muhammad Nawaz Tahir Victor Martinez Yajun Cheng Jochen S. Gutmann Michael Klein Stefan Jung Morris Wolff Reza Saadat Driss Nariaki Roman Bo?a G?star Klingelh?fer Wolfgang Tremel Franz Renz 《Hyperfine Interactions》2012,205(1-3):63-67
The nonanuclear coordination compound [MoIV{(CN)FeIII(3-methyl-saldptn)}8]Cl4 exhibits multiple spin transitions (3-methyl-saldptn = N,N′-bis(3′′-methyl-2′′-hydroxy-benzyliden)-1,7-diamino-4-azaheptane). This spin crossover cluster is bound via a self-assembled monolayer onto a two dimensional array gold surface. M?ssbauer spectroscopy indicates that the thermally and optically induced spin crossover of the compound is maintained. Thereby, the foundation for its potential practical application (e.g. in the field of information storage) was laid. 相似文献
158.
The aim of this study is to investigate the performance of nanoclay reinforced unsaturated polyester (UP) resin under impact loads. Nanocomposite specimens containing nanoclay in 0, 1.5, and 3 (wt%) were prepared by melt mixing method. X‐ray diffraction, transmission electron microscopy analysis, scanning electron microscope photographs, and viscosity changes in liquid state resin confirmed exfoliation and intercalation of the nanoclay in the UP resin system used. Tensile modulus showed an increase with increase in nanoclay content. However, the tensile strength and elongation at break exhibited reducing performance with increase in nanoclay content. Izod impact test results indicated better performance for the specimens containing nanoclay reinforcements, with 1.5 (wt%) of nanoclay specimens showing the highest value. High velocity impact tests were carried out using gas gun in velocity range of 20–100 m/sec and harden steel hemispherical tip projectile with diameter of 8.7 mm and weight of 11.54 g. Results for high velocity impact test indicated better performance by the specimens containing nanoclay, with 1.5 (wt%) nanoclay showing the highest attained value. Damage assessments of impact area for all specimens showed spalling type brittle failure with punch out and sever fragmentation pattern. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
159.
160.