掺杂8-羟基喹啉铝薄膜的电致发光特性研究

在具有电致发光(EL)的有机整合染料8-羟基喹啉铝(Alq3)中接以染料罗丹明6G(R6G),用真空热蒸发的方法制备器件,获得了峰值波长575nm的黄色直流薄膜电致发光,从而通过掺杂改变了发光颜色.并在Alq3发光层不同区域插入一掺杂薄层(Alq3:R6G),利用其发光波长与未掺杂部分(Alq3)的不同,以此作为“探测层”,通过对器件光谱及电学特性的测量与分析,探讨了有关发光区域,发光机理,界面对发光影响等基本问题.     

Intersections of random walks and Wiener sausages in four dimensions

Let {S ₁ (n)} _n0and {S ₂ (n)} _n0be independent simple random walks in Z ⁴ starting at the origin, and let % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiGc9yrFr0xXdbba91rFfpec8Eeeu0x% Xdbba9frFj0-OqFfea0dXdd9vqaq-JfrVkFHe9pgea0dXdar-Jb9hs% 0dXdbPYxe9vr0-vr0-vqpWqaaeaabiGaciaacaqabeaadaqaaqGaaO% qaaiabfc6aqnaaBaaaleaacaqGPbaabeaatCvAUfKttLearyqr1ngB% Prgaiuaakiab-HcaOiaadggacaGGSaGaamOyaiab-LcaPiabg2da9i% ab-Tha7Hqbciab+Hha4jabgIGiolab+PfaAnaaCaaaleqabaGaaGin% aaaakiaacQdaieGacaqFtbWaaSbaaSqaaiaabMgaaeqaaOGae8hkaG% Iaa0xBaiab-LcaPiabg2da9iab+Hha4baa!5761!\[\Pi _{\rm{i}} (a,b) = \{ x \in Z^4 :S_{\rm{i}} (m) = x\]for the some % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiGc9yrFr0xXdbba91rFfpec8Eeeu0x% Xdbba9frFj0-OqFfea0dXdd9vqaq-JfrVkFHe9pgea0dXdar-Jb9hs% 0dXdbPYxe9vr0-vr0-vqpWqaaeaabiGaciaacaqabeaadaqaaqGaaO% qaaGqaciaa-1gacqGHiiIZtCvAUfKttLearyqr1ngBPrgaiuaacqGF% OaakcaWGHbGaaiilaiaadkgacqGFPaqkcqGF9bqFaaa!4936!\[m \in (a,b)\} \]. Let two integervalued sequences {a _n}_n0and {b _n}_n0be given, such that the limit lim_n a _nexists and lim _n b _n=+. In this paper, it is shown that the probability of % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiGc9yrFr0xXdbba91rFfpec8Eeeu0x% Xdbba9frFj0-OqFfea0dXdd9vqaq-JfrVkFHe9pgea0dXdar-Jb9hs% 0dXdbPYxe9vr0-vr0-vqpWqaaeaabiGaciaacaqabeaadaqaaqGaaO% qaaiabfc6aqnaaBaaaleaacaaIXaaabeaatCvAUfKttLearyqr1ngB% Prgaiuaakiab-HcaOiab-bdaWiab-XcaSiabg6HiLkab-LcaPiabgM% Iihlabfc6aqnaaBaaaleaacaaIYaaabeaakiab-HcaOiaadggadaWg% aaWcbaGaamOBaiaacYcaaeqaaOGaamyyamaaBaaaleaacaWGUbaabe% aakiabgUcaRiaadkgadaWgaaWcbaGaamOBaaqabaGccqWFPaqkcqGH% GjsUieaacaGFydaaaa!5904!\[\Pi _1 (0,\infty ) \cap \Pi _2 (a_{n,} a_n + b_n ) \ne \O \] is asymptotic to % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiGc9yrFr0xXdbba91rFfpec8Eeeu0x% Xdbba9frFj0-OqFfea0dXdd9vqaq-JfrVkFHe9pgea0dXdar-Jb9hs% 0dXdbPYxe9vr0-vr0-vqpWqaaeaabiGaciaacaqabeaadaqaaqGaaO% qaamaalaaabaGaaGymaaqaaiaaikdaaaGaciiBaiaac+gacaGGNbWe% xLMBb50ujbqeguuDJXwAKbacfaGae8hkaGIae8xmaeJae83kaSIaam% OyamaaBaaaleaacaWGUbaabeaakiaac+cacaWGHbWaaSbaaSqaaiaa% d6gaaeqaaOGae8xkaKIae83la8IaciiBaiaac+gacaGGNbGaamOyam% aaBaaaleaacaWGUbaabeaaaaa!5364!\[\frac{1}{2}\log (1 + b_n /a_n )/\log b_n \] if it tends to zero as n, and the probability of % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiGc9yrFr0xXdbba91rFfpec8Eeeu0x% Xdbba9frFj0-OqFfea0dXdd9vqaq-JfrVkFHe9pgea0dXdar-Jb9hs% 0dXdbPYxe9vr0-vr0-vqpWqaaeaabiGaciaacaqabeaadaqaaqGaaO% qaaiabfc6aqnaaBaaaleaacaaIXaaabeaatCvAUfKttLearyqr1ngB% Prgaiuaakiab-HcaOiab-bdaWiab-XcaSiabg6HiLkab-LcaPiabgM% Iihlabfc6aqnaaBaaaleaacaaIYaaabeaakiab-HcaOiaadggadaWg% aaWcbaGaamOBaaqabaGccaGGSaGaamyyamaaBaaaleaacaWGUbaabe% aakiabgUcaRiaadkgadaWgaaWcbaGaamOBaaqabaGccqWFPaqkcqWF% 9aqpieaacaGFydaaaa!583C!\[\Pi _1 (0,\infty ) \cap \Pi _2 (a_n ,a_n + b_n ) = \O \]is asymptotic to % MathType!MTEF!2!1!+-% feaafeart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqefm0B1jxALjhiov2D% aebbfv3ySLgzGueE0jxyaibaiGc9yrFr0xXdbba91rFfpec8Eeeu0x% Xdbba9frFj0-OqFfea0dXdd9vqaq-JfrVkFHe9pgea0dXdar-Jb9hs% 0dXdbPYxe9vr0-vr0-vqpWqaaeaabiGaciaacaqabeaadaqaaqGaaO% abaeqabaaabaGaam4yaiaacUfaciGGSbGaai4BaiaacEgatCvAUfKt% tLearyqr1ngBPrgaiuaacqWFOaakcaWGHbWaaSbaaSqaaiaad6gaae% qaaOGaey4kaSIaamOyamaaBaaaleaacaWGUbaabeaakiab-LcaPiab% -9caViab-XgaSjab-9gaVjab-DgaNjab-HcaOiaadggadaWgaaWcba% GaamOBaaqabaGccqGHRaWkcaaIYaGae8xkaKIae8xxa01aaWbaaSqa% beaacqWFTaqlcqWFXaqmcqWFVaWlcqWFYaGmaaaaaaa!5BAC!\[\begin{array}{l} \Pi _1 (0,\infty ) \cap \Pi _2 (a_n ,a_n + b_n ) = \O \\ c[\log (a_n + b_n )/log(a_n + 2)]^{ - 1/2} \\ \end{array}\], for some constant c, if it tends to a finite constant (1) as n. These results extend some results obtained by G. F. Lawler about the intersection properties of simple random walks in Z ⁴. By using similar arguments, we also get corresponding results for the intersections of Wiener sausages in four dimensions. In particular, a conjecture suggested by M. Aizenman, which describes nonintersection of independent Wiener sausages in R ⁴, is proven.Partly supported by AvH Foundation.     

Almost linearity of -bi-Lipschitz maps between real Banach spaces

Let and be real Banach spaces. A map between and is called an -bi-Lipschitz map if for all . In this note we show that if is an -bi-Lipschitz map with from onto , then is almost linear. We also show that if is a surjective -bi-Lipschitz map with , then there exists a linear isomorphism such that

where as and .

     

Orthogonal array design (OAD) for the optimization of mercury extraction from soils by dilute acid with microwave heating

The use of dilute acid for mercury extraction from geological samples with microwave assisted heating was investigated. An orthogonal array design OA(16)(4(1)x2(12)) was applied to select the optimum conditions. The effects of the concentration of HNO(3), the additions of HCl and H(2)S0(4), the extraction time and their interactions were evaluated by the mixed-level orthogonal array design (OAD). The results indicated that the addition of small amount of HCl would improve significantly the extraction of mercury from soil matrices. From the study, it is seen that the mercury in the soil matrices could be extracted completely by 14% (v/v) HNO(3) with small quantity of HCl. The effects of the pressure within the digestion vessel and the sample mass were studied under the optimum conditions derived from the OAD. The extraction methods with optimum conditions were evaluated by determining mercury in NIST SRM 1645 River Sediment, NIES CRM No. 2 Pond Sediment and NRCC BCSS-1 Marine Sediment. Recoveries of 78-109% were achieved. Good mean recoveries of 95-98% were also obtained from real soil samples spiked with different species of mercury.