宽调谐范围垂直腔面发射激光器特性分析及设计

运用光学传输矩阵和有限元方法对波长可调谐垂直腔面发射激光器(VCSELs)的波长调谐范围进行了研究.对中心波长为980nm的可调谐VCSELs的波长调谐特性和微电子机械系统(MEMS)悬臂梁结构进行了设计，并进行了实验研究.结果表明，MEMS可调谐VCSELs调谐特性同时受到光波谐振腔结构和悬臂梁最大位移的共同影响.在悬臂梁几何尺寸和激光器有源区结构一定的条件下，通过优化可调谐VCSELs的牺牲层厚度可实现大范围波长调谐.同时，对可调谐VCSELs整体结构进行了设计，计算结果显示波长调谐范围达到30nm以 关键词： 悬臂梁 可调谐垂直腔面发射激光器     

关于对称性曲线运动的处理技巧

由于宏观的对称性,导致了某些量间的等值关系,从而可将实际问题简单化.本文利用这种特性,把它应用到具有对称性的曲线运动上,取得复杂问题简单处理的效果.     

炸药爆轰制备纳米石墨粉储放氢性能实验研究

介绍了一种新的制备纳米石墨粉的方法——炸药爆轰法.通过对爆轰合成的黑色粉末进行x射线衍射分析，确认其为六方结构的纳米石墨，平均晶粒度为1.86—2.61nm.用BET气体吸附仪测试纳米石墨粉的比表面积约为500—650m2/g，由比表面积计算得到的纳米石墨粒度为4.41—6.85nm.在室温（≈290K）和12MPa压力条件下对纳米石墨粉进行储放氢气性能测试，结果表明纳米石墨粉样品的储放氢量为0.33wt%—0.37wt％.在相同实验条件下，纳米石墨粉原始样品的储放氢能力较原始纳米炭纤维（0.15wt%—0.35wt％）和多壁碳纳米管（0.15wt%—0.20wt％）的储放氢能力略强,但低于超级活性炭（0.92wt%—0.98wt％）.纳米碳材料的比表面积在其储放氢实验中起关键作用. 关键词： 爆轰 纳米石墨粉 比表面积 储放氢量     

A mild CuI-catalyzed Glaser-type homo-coupling reaction using α,α-dibromo-β-dicarbonyl compounds as oxidants

Exploration of α,α-dibromo-β-dicarbonyl compounds as novel organic oxidants for the mild Cu(I)-catalyzed Glaser-type homo-coupling reaction has been achieved, which provides an alternatively efficient pathway for the construction of 1,3-conjugated structures. In addition, the mechanism of this reaction was investigated.     

Dioxomolybdenum(VI) complex covalently attached to amino‐modified graphene oxide: heterogeneous catalyst for the epoxidation of alkenes

Transition metal salen complex MoO₂–salen was successfully tethered onto amino‐functionalized graphene oxide (designated as MoO₂–salen–GO), which was tested in the epoxidation of various alkenes using tert‐butylhydroperoxide or H₂O₂ as oxidant. Characterization results showed that dioxomolybdenum(VI) complex was successfully grafted onto the amino‐functionalized graphene oxide and the structure of the graphene oxide was well preserved after several stepwise synthesis procedures. Catalytic tests showed that heterogeneous catalyst MoO₂–salen–GO was more active than its homogeneous analogue MoO₂–salen in the epoxidation of cyclooctene due to site isolation. In addition, the MoO₂–salen–GO catalyst could be reused three times without significant loss of activity. Copyright © 2014 John Wiley & Sons, Ltd.     

Enhanced electrochemical properties of a novel polyvinyl formal membrane supporting gel polymer electrolyte by Al2O3 modification

Polyvinyl formal (PVFM)‐based dense polymer membranes with nano‐Al₂O₃ doping are prepared via phase inversion method. The membranes and also their performances as gel polymer electrolytes (GPEs) for lithium ion battery are studied by field emission scanning electron microscope, X‐ray diffraction, differential scanning calorimetry, mechanical strength test, electrolyte uptake test, electrochemical impedance spectroscopy, cyclic voltammetry, and charge–discharge test. The polymer membrane with 3 wt % nano‐Al₂O₃ doping shows the improved mechanical strength of 12.16 MPa and electrolyte uptake of 431.25% compared with 10.47 MPa and 310.59% of the undoped sample, respectively. The membrane absorbs and swells liquid electrolyte to form stable GPE with ionic conductivity of 4.92 × 10^?4 S cm^?1 at room temperature, which is higher than 1.77 × 10^?4 S cm^?1 of GPE from the undoped membrane. Moreover, the Al₂O₃‐modified membrane supporting GPE exhibits wide electrochemical stability window of 1.2–4.8 V (vs. Li/Li⁺) and good compatibility with LiFePO₄ electrode, which implies Al₂O₃‐modified PVFM‐based GPE to be a promising candidate for lithium ion batteries. © 2014 Wiley Periodicals, Inc. J. Polym. Sci. Part B: Polym. Phys. 2014 , 52, 572–577     

Synthesis and properties of cross‐linkable high molecular weight fluorinated copolyimides

A series of novel high molecular weight fluorinated co‐polyimides (Co‐PIs) containing styryl side chain based on 1,3‐bis(2‐trifluoromethyl‐4‐aminophenoxy)‐5‐(2,3,4,5‐tetrafluorophenoxy)benzene (6FTFPB) were successfully synthesized. The weight‐average molecular weights (M_ws) and polydispersities of the co‐polyimides were in the range 8.93–10.81 × 10⁴ and 1.33–1.82, respectively. The co‐polyimide film showed excellent solubility in organic solvents, high tensile properties (tensile strength exceeded 91 MPa), excellent optical transparency (cutoff wavelength at 332–339 nm and light transparencies above 89% at a wavelength of 550 nm), and high thermal stability (5% thermal weight‐loss temperature up to 510 °C). The casting and spinning films could be cross‐linked by thermal curing. The cured films show better combination property (including excellent resistance to solvents) than that of co‐polyimides. For instance, the glass transition temperature of Co‐PI‐1 (the molar weight ratio of 6FTFPB was 30%) increased from 217 to 271 °C, the tensile strength enhanced from 94 to 96 MPa, the 5% thermal weight‐loss temperature improved from 514 to 525 °C. Moreover, after cured, Co‐PI‐1 film also has a coefficient of thermal expansion (CTE) value of 60.3 ppm °C^?1, low root mean square surface roughness (R_q) at 4.130 nm and low dielectric constant of 2.60. © 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 349–359