全文获取类型
收费全文 | 720篇 |
免费 | 22篇 |
专业分类
化学 | 434篇 |
晶体学 | 6篇 |
力学 | 9篇 |
数学 | 68篇 |
物理学 | 225篇 |
出版年
2024年 | 3篇 |
2023年 | 5篇 |
2022年 | 18篇 |
2021年 | 13篇 |
2020年 | 12篇 |
2019年 | 24篇 |
2018年 | 26篇 |
2017年 | 18篇 |
2016年 | 27篇 |
2015年 | 24篇 |
2014年 | 22篇 |
2013年 | 63篇 |
2012年 | 54篇 |
2011年 | 54篇 |
2010年 | 29篇 |
2009年 | 33篇 |
2008年 | 42篇 |
2007年 | 39篇 |
2006年 | 29篇 |
2005年 | 19篇 |
2004年 | 19篇 |
2003年 | 16篇 |
2002年 | 16篇 |
2001年 | 6篇 |
2000年 | 5篇 |
1999年 | 7篇 |
1998年 | 3篇 |
1997年 | 4篇 |
1996年 | 3篇 |
1995年 | 5篇 |
1993年 | 5篇 |
1992年 | 4篇 |
1991年 | 2篇 |
1990年 | 5篇 |
1989年 | 6篇 |
1988年 | 7篇 |
1986年 | 8篇 |
1985年 | 3篇 |
1984年 | 4篇 |
1983年 | 2篇 |
1982年 | 5篇 |
1981年 | 7篇 |
1980年 | 10篇 |
1979年 | 5篇 |
1977年 | 8篇 |
1976年 | 3篇 |
1975年 | 9篇 |
1974年 | 2篇 |
1971年 | 2篇 |
1970年 | 2篇 |
排序方式: 共有742条查询结果,搜索用时 0 毫秒
101.
102.
103.
Patil Priyanka T. Warekar Poojali P. Patil Kirti T. Jamale Dattatraya K. Kolekar Govind B. Anbhule Prashant V. 《Research on Chemical Intermediates》2017,43(7):4103-4114
Research on Chemical Intermediates - A convenient and new method has been developed for the synthesis of highly substituted dihydro-2H-dipyrimido[1,2-a,4,5-d]pyrimidine-2,4(3H)-dione derivatives by... 相似文献
104.
Nucleophilic C-S bond formation using easily available β-hydroxysulfonate derivatives allowed direct access to new mono- and disubstituted divinyl sulfones. Our strategy uses thioethanol (HSCH(2)CH(2)OH) and its analogues such as HSCH(2)CH(Y)OH generated in situ. The strategy also allows the synthesis of modified divinyl sulfones attached to chiral appendages like carbohydrates. Bis-heteronucleophilic Michael addition reactions with 1 equiv of a primary amine afforded new generations of S,S-dioxothiomorpholine derivatives known for their therapeutic applications. Further synthetic manipulations of some of these cyclic compounds led to the synthesis of novel bicyclic derivatives. 相似文献
105.
This is the first report on the diastereoselective addition of carbon nucleophiles to vinyl sulfone-modified hex-5-enofuranosides. The stereoelectronic properties of the substituents at the C-3 position and their interactions with the incoming carbon nucleophiles control the diastereoselectivity of addition at the C-5 position, favoring the formation of l-ido derivatives as major products in most of the cases studied. This new concept of stereocontrolled carbon-carbon bond formation in vinyl sulfone-modified carbohydrates is general in nature. The novel chirons generated by this diversity-oriented synthetic method have been implemented in the preparation of a wide range of hexofuranosyl C-5 branched-chain sugars, bicyclic derivatives, chirally pure enals, and densely functionalized carbocycles. 相似文献
106.
Govind P. Agrawal 《Optics Communications》1982,42(5):366-370
Phase conjugation through four-wave mixing is considered in a two-photon resonant medium pumped by two distinct-frequency counter-propagating beams. This configuration eliminates the formation of stationary spatial holes. The relative magnitude of the pump intensities plays an important role and the phase-conjugation efficiency is found to be maximum for unequal values of the pump intensities. 相似文献
107.
This paper presents the influence of magnetic field on heat due to viscous and electrical dissipations for an incompressible, viscous, electrically conducting fluid through a circular pipe in the presence of an applied (transverse) uniform magnetic field. The walls of the pipe are assumed to be non-conducting and kept at uniform temperature gradient in one case and at a constant temperature gradient in another case. The heat equation governing the present problem is solved exactly in hypergeometric series. The temperature at the centre of the pipe Te, unweighted mean temperature Tm and weight mean temperature TM are calculated. The temperature profiles are shown graphically for different values of Hartmann number M, Brinkman number Br and a non-dimensional number S. Numerical calculations are made for the Nusselt number and are entered in the table. 相似文献
108.
Non-isothermal studies of the dehydration of double salt hydrates of the type K2AB4·M(II)SO4·6H2O where AB4BeF2?4 or SeO2?4 and M(II)Mg(II), Co(II), Ni(II), Cu(II) or Zn(II) and their D2O analogues were carried out. Thermal parameters like activation energy, order of reaction, enthalpy change, etc., for each step of dehydration were evaluated from the analysis of TG, DTA and DTG curves. These parameters were compared with the corresponding double sulphate, i.e., K2SO4·M(II)SO4·6H2O and their D2O analogues. The role of divalent cation on the thermal properties of dehydration of the salt hydrates and also the effect on the thermal properties due to deuteration were discussed. The order of reaction was always found unity. The values of ΔH were within ~11-~19 kcal mol?1 相似文献
109.
110.
Radio pulses from extensive air showers (EAS) at 30, 44, and 60 MHz frequencies have been studied, using wide band broad-side
arrays of half-wave dipole antenna systems. The experimental results support the theoretical prediction that the field strength
of radio emission depends on the shower size. An asymmetry has been noticed in the pulse height distributions of radio pulses
detected by North-South and East-West directed arrays. These observations are in agreement with the theory that the charge
separation mechanism is predominant in generating radio pulses from EAS and radio emission is polarised in the East-West direction.
Experimental data are compared with those of earlier workers. 相似文献