Pyrroles from ketoximes and acetylene. 43. 1,2-Dihaloalkanes and vinyl chloride in the synthesis of 2-(4-alkylthiophenyl)pyrroles

2-(4-Alkylthiophenyl)-3- and 2-(4-alkylthiophenyl)-5-methylpyrroles and their 1-vinyl derivatives were synthesized by the reaction of alkyl(4-alkylthiophenyl)ketoximes with dihaloalkanes or vinyl chloride in the KOH-DMSO system at 120–140C and atmospheric pressure.See [1] for Communication 42.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1, 1337–1340, October, 1990.     

Simulation of the Electronic Structure of Graphene–Polyvinylidene Fluoride Composite Material

Physics of the Solid State - Theoretical models of shockproof composite materials based on two-layer graphenes and multilayer polyvinylidene fluoride C124H40 + n(H–(C2H2F2)5–H) (n =...     

Rare-earth-cation-induced change in the cholesteric twisting of neighboring nucleic acid molecules

Certain physicochemical characteristics of particles of the cholesteric liquid-crystal dispersions of complexes of double-stranded nucleic acids with rare earth elements have been determined. It is shown for the first time that the binding of the rare earth cations to linear nucleic acid molecules ordered in the structure of particles of the cholesteric liquid crystal dispersions is accompanied not only by amplification of the abnormal band in the circular dichroism spectrum, but also by the disappearance of the characteristic maximum on the X-ray scattering curves for small angles. The (cholesteric 1-cholesteric 2) transition induced by rare earth cations is an example of the operation of a microscopic machine consisting of spatially ordered nucleic acid molecules. Particles of the cholesteric liquid crystal dispersions of nucleic acid complexes with rare earth elements hold the abnormal optical properties for a long time.