新型氟代三苯胺衍生物的合成和光谱特性研究

设计和合成了一种新型氟代三苯胺衍生物——N,N,N′,N′-四苯基-[2′,2″,3′,3″,5′,5″,6′,6″-八氟对四联苯]-4,4″′-二胺(OFTPA)。通过元素分析、熔点测定、红外光谱和1 H NMR谱等手段对OFTPA的分子结构进行了表征,并对其主要的红外光谱吸收峰和1 H NMR谱带进行了归属分析。利用紫外-可见吸收光谱、荧光光谱和循环伏安法(CV)对OFTPA的电子能级结构和发光性能进行了研究。紫外-可见吸收光谱测定结果表明,OFTPA薄膜的最大吸收峰波长为355nm,光学带隙(Eg)为3.09eV。荧光光谱测定结果表明,OFTPA薄膜在365nm紫外光的激发下,产生发光峰波长在448nm附近、半峰宽(FWHM)为68nm的蓝光发射,色纯度高,有望成为优良的蓝光发射材料。循环伏安法测定结果表明,OFTPA的最高占有轨道(HOMO)能级为-5.41eV,最低空轨道(LUMO)能级为-2.32eV,具有良好的空穴传输性能。研究结果为进一步研究其在有机光电器件中的应用提供了参考。     

Existence and uniqueness of solutions of reaction–convection equations with non-Lipschitz nonlinearity

In this work we study single balance law _ut+∇⋅Φ(u)=f(u)$u_t+\mathrm{\nabla }\cdot \Phi (u)=f(u)$ with bounded initial value, and find that there may exist maximal and minimal solutions, if f(u)$f(u)$ is not Lipschitz continuous at u=0$u=0$. We also show that comparison principle is valid for such solutions, and the solutions may blow up or not under certain conditions. It is determined by the strength of source supply, as well as the competition between the source and flux.     

Complemented subgroups and the structure of finite groups

Let $p$ be the smallest prime divisor of the order of a finite group $G$ . We examine the structure of $G$ under the hypothesis that $p$ -subgroups of $G$ of certain orders are complemented in $G$ . In particular, we extend some recent results.     

求解PageRank问题的多步幂法修正的内外迭代法

引用两种加速计算PageRank的算法,分别为内外迭代法和两步分裂迭代算法.从这两种方法中,得到多步幂法修正的内外迭代方法.首先,详细介绍了算法实施过程.然后,对此算法的收敛性进行证明,并且将此算法的谱半径与两步分裂迭代算法的谱半径进行比较.最后,数值试验说明该算法的计算速度比两步分裂迭代法要快.     

猪瘟病毒HCLV株E_2核苷酸序列与结构分析

用 Ｒ Ｔ Ｐ Ｃ Ｒ技术从 Ｃ Ｓ Ｆ Ｖ Ｈ Ｃ Ｌ Ｖ 株 Ｆ４８２ 代感染兔脾的细胞总 Ｒ Ｎ Ａ 中分段扩增出了 Ｃ Ｓ Ｆ Ｖ Ｅ２ 基因特异的３ 个部分重叠的 Ｄ Ｎ Ａ 片段（大小分别为 ４９９ ｂｐ、５７２ ｂｐ 和 ２４５ ｂｐ）,并将之分别克隆到ｐ Ｇ Ｅ Ｍ Ｔ 载体上 经核苷酸序列测定和片段重叠完成了包含 Ｅ２ 全长基因的 １ １４４ ｂｐ 序列的测定,其 Ｇ Ｃ含量为４９．０％ ：核苷酸序列与国外报道的各株病毒的 Ｅ２ 基因同源性分别为８３．５％ ～９７．５％ ;其推导的氨基酸序列的同源性也分别为８９．３％～９６．２％ ,变异主要分布在 Ｅ２ 蛋白的 Ｎ 半部分     

一类线性差分方程的亚纯解与一个亚纯函数分担3个值的唯一性

主要研究差分方程a_1(z)f(x+1)+a_0(z)f(z)=F(z)的一个有穷级超越亚纯解f(z)与亚纯函数g(z)分担0,1,∞CM时的唯一性问题(其中a_(z),a0(z),F(z)为非零多项式,且满足a_1(z)+a_0(z)■0),得到f(x)≡g(z),或f(z)+g(z)≡f(z)g(z),或存在一个多项式β(z)=az+b_0和一个常数a_0满足e~(a_0)≠e~(b_0),使得f(z)=(1-e~(β(x)))/(e~(β(x))(e~(a_o-b_0)-1))与g(z)=(1-e~(β(x)))/(1-e~(b_o-a_0)),其中a(≠0),b_0为常数.     

几种广义非线性发展方程的新解

本文研究了构造了广义Kd V方程和广义KP-Burgers方程等几种广义非线性发展方程的新解的问题.利用三种辅助方程及其新解,获得了广义Kd V方程和广义KP-Burgers方程等几种广义非线性发展方程的新解.这些解由双曲余割函数、双曲正切函数、双曲正割函数、双曲余切函数和余割函数组成.     

New Di-(p-hydroxybenzyl) A Hydroxylamine from Gastrodia eleta Bl

Gush.()(/i'leleluBI.isapronlinenttraditionalchineseherbmedicinei.Studiesonthecllenlicalcollstituentsofthisplantwerestartedtwentyyearsago=1andsincethenman}'papershavebeenpublished=-'.However.previouswork1hostlyreportedtheisolationsofphenolcompoundsincludingtheirglycosides=-'.Duringourreinvestigatingonthisplant,di-(p-hydroxybenzyl)hydroxylamineI(Figurel)wasisolatedanditsstructurewaselucidatedonthebasisofHRFABMS(highresolutiontestatombombardmentmassspectroscopy),and1DandZDNMRexperiments.Po…     

Tensor force effect on proton shell structure in neutron-rich Ca isotopes

In the framework of the Skyrme-Hartree-Fock approach with 36 sets of the TI J parameterizations,the tensor force effect on the evolution of the single-proton states in the calcium isotopes is systematically investigated.It is shown that the single-proton states with higher angular momenta are influenced significantly by the tensor force and the trend in the evolution of somesingle-particle energy differences with the mass number of the isotopes depends sensitively on a parameter βT associated with the intensity of the tensor force.To understand this phenomenon,we analyze the spin-orbit potentials and the radial wave functions of relevant single-proton orbits in detail.In addition,it is found that some TI J interactions could cause the 2s1/21d3/2 energy level inversion in 48Ca.