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51.
On the basis of the realistic argon atom model consisting of 65 discrete effective levels numerical results for the collisional-radiative volume recombination, ionization and decay coefficients are obtained. The computations are carried out without any approximations of integral functions. The presented comparison of theoretical and experimental results for the decay coefficient shows that the values calculated by us are in much better agreement with experimental values than those obtained by Desai and Corcoran on the assumption that the argon atom is hydrogen-like. 相似文献
52.
Helmut Schwarz Claus Koppel Ferdinand Bohlmann 《Journal of mass spectrometry : JMS》1973,7(10):1211-1213
By the investigation of 13C-labelled dimethylbenzylbromide, it has been shown that the [M – Br]+ ion isomerises to a dimethyltrophylium cation. 相似文献
53.
Ferdinand Nf Ren Decorzant Walter Thommen Bruno Willhalm Günther Ohloff 《Helvetica chimica acta》1975,58(4):1016-1037
The four geometrical isomers of 1,3,5-undecatriene, 1a–d have been prepared (stereospecifically and non-stereospecifically), using either (1) the Wittig reaction, (2) thermal sigmatropic hydrogen shifts, (3) partial reduction of triple bonds by zinc, or (4) organocopper reagents. The thermal behaviour of the four 1,3,5-undecatrienes has been investigated and the products formed have been characterized. The spectra of 1a–d, and of related compounds, have been discussed in order to corroborate their configurational assignment. 相似文献
54.
Zusammenfassung Eine Methode wurde entwickelt, um Calcium und Magnesium in natürlichen Wässern bei pH 10 an einer Tl2O3-Anode unter Verwendung von ÄDTA und ÄGTA als Titrationsmittel zu bestimmen. Die dabei verwendete Apparatur eignet sich gut für Serienbestimmungen, da die Zugabe des Titrationsmittels und die Aufzeichnung des Kurvenverlaufs automatisch erfolgen. Die Auswertung wird graphisch durchgeführt.
Automatic amperometer determination of calcium and magnesium through complexometric titration
Summary A method has been developed for the determination of calcium and magnesium in natural waters at pH 10 on a Tl2O3-anode with employment of EDTA and EGTA as titration agents. The apparatus used is well suited to series determinations, because the addition of the titration agent and the recording of the course of the curve are done automatically. The evaluation is conducted graphically.相似文献
55.
Ferdinand Hucho 《Angewandte Chemie (International ed. in English)》1975,14(9):591-601
The three enzymes pyruvate dehydrogenase, dihydrolipoamide transacetylase, and dihydrolipoamide dehydrogenase constitute the pyruvate dehydrogenase multienzyme complex of E. coli; in mammals the complex also contains a kinase and a phosphatase. Multienzyme complexes are structural, functional, and regulatory units enabling the organism to operate more economically than with single enzymes. The pyruvate dehydrogenase multienzyme complex may stand at the switch-point between energy metabolism and gluconeogenesis. 相似文献
56.
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58.
In the present paper the construction of the distribution functions for OH radicals in the H2-O2 flame is dealt with. The construction is based on the fact stated in [1] that there are two groups of OH radicals in the flame. It is shown here that the method for temperature determination used in [1] can be considered as the first approximation only. According to this fact the method of determining the parameters of the flame (temperature etc.) solving system of equations for line intensities is presented here. In practice it is possible under certain conditions, discussed here, to use an improved method in order to determine the flame parameters and distribution functions of OH radicals. Also the reduction of the temperatures of the cold group of OH radicals based on above mentioned improved method is discussed here. The values of the temperature of the cold group of OH radicals to be reduced are taken from [1]. 相似文献
59.
60.
The structure of stable [C9H11]+ ions from different model compounds with the molecular formula C9H11Cl has been estimated by energy measurements. It has further been shown that acetylenic compounds cyclise to form aromatic ions in the range of the appearance potentials. 相似文献