Synthesis and characterization of epoxy-modified cement slurries--kinetic data at hardened slurries/HCl interfaces

In this study, two new epoxy-modified oilwell cement slurries were synthesized. All characterization measurements were performed and compared in relation to a standard cement slurry, which was synthesized using only cement and water. The XRD patterns, as well as TG/DTG and DSC analyses have suggested that portlandite (Ca(OH)2) and carbonate phases were not present in detectable amounts in the new cement slurries. The isothermal kinetic data of the interaction of HCl with the epoxy-modified cement were obtained using the batch mode from 25 to 55 degrees C. The kinetic data were best fitted to the second-order and the Avrami kinetic models, since differences between experimental and calculated values were lower for these models. The intraparticle diffusion model has pointed out that the new slurries present positive values for the parameter "C," which is related to higher boundary layer resistance to HCl diffusion into the internal parts of the slurries, in relation to the standard slurry. The characterization and the HCl interaction kinetic studies have suggested that the new cement slurries present good potential, from the chemical viewpoint, to be used in oilwell operations.     

Electrokinetics in nanochannels: part II. Mobility dependence on ion density and ionic current measurements

In the first of this two-paper series, a new model was developed for calculating the electric potential field in a long, thin nanochannel with overlapped electric double layers. The model takes into account the dependence of ion mobility on local ion densities and pH. This model is used here to study and demonstrate the effect of ion density and pH on ionic current measurements. A comparison is shown of predictions based on each of three boundary conditions, as studied in Part I. The model developed in Part I is validated by comparing simulations with measurements of ionic current as a function of sodium borate concentration. Results show that predictions based on extended Debye-Hückel theory for ion mobility significantly improve the accuracy of simulations, but that these do not predict exact scaling behavior. A simple bulk conductivity measurement used as input parameter for the simulations, in place of the predicted bulk conductivity (K(0)), guarantees agreement with data in the thin EDL region. Results also indicate that the charge regulation boundary condition, complemented with an adequate bulk electrolyte model, provides better agreement with experimental trends than the specified zeta potential or specified surface net charge boundary conditions. Further, it is shown that currents due to advection (by electroosmotic flow) are in all cases studied less than 25% of the total current in the system.     

Direct palladium-catalyzed C-3 arylation of free (NH)-indoles with aryl bromides under ligandless conditions

A new method for the efficient, practical, and highly regioselective direct palladium-catalyzed C-3 arylation of free (NH)-indole and its electron-rich 1-unsubstituted derivatives under ligandless conditions is described. The reactions, which are run outside a glovebox without purification of solvent and reagents, involve treatment of free (NH)-indoles with activated, unactivated, and deactivated aryl bromides in refluxing toluene in the presence of K2CO3 as the base and a catalyst system consisting of a combination of Pd(OAc)2 and benzyl(tributyl)ammonium chloride. The experimental results are consistent with a catalytic cycle based on an electrophilic palladation pathway at the 3-position of 1-indolyl potassium salts.     

Leveraging circuit theory and nonlinear dynamics for the efficiency improvement of energy harvesting

Nonlinear Dynamics - The Hopf–Hopf bifurcations of an aircraft nose landing gear model are investigated in this paper based on two pairs of continuation parameters. It is shown that due to...     

Stochastic Precedence and Minima Among Dependent Variables

Methodology and Computing in Applied Probability - The notion of stochastic precedence between two random variables emerges as a relevant concept in several fields of applied probability. When one...     

Random Linkage: a family of acceptance/rejection algorithms for global optimisation

Received July 24, 1997 / Revised version received August 9, 1998 Published online January 20, 1999     

Kernel Theorems for Modulation Spaces

Journal of Fourier Analysis and Applications - We deal with kernel theorems for modulation spaces. We completely characterize the continuity of a linear operator on the modulation spaces $$M^p$$...     

A finiteness result for groups which quasi-act on hyperbolic spaces

Let (X, d) be a Gromov-hyperbolic metric space endowed with a measure having finite entropy H and such that the measure of every ball of radius R > 0 is finite and bounded from below by a positive function of R. In this paper we look at the set Q(X; L, C, D) of the isomorphism classes of torsion-free groups Γ which admit a discrete, D-co-bounded (L, C)-quasi-action on X (D > 0, L ≥ 1, C ≥ 0) and we describe some algebraic conditions which, imposed on the groups Γ, define finite subsets of Q(X; L, C, D), provided C < ε for some ε > 0. As an example, these conditions are satisfied when Γ is assumed to admit a faithful, discrete, m-dimensional representation over some local field (in this case ε = ε(m, H, L)). In particular (set C = 0, L = 1), our results apply when the groups are assumed to act by isometries.