Adsorption of cyclic hydrocarbons on Pt and the interaction of the adsorbed species with hydrogen

The adsorption of six-membered hydrocarbon cycles and cyclopentane and the interaction of hydrogen with the adsorbed layer on polycrystalline Pt-foil have been studied. The work function change (Δφ) was followed by a Kelvin probe and the C/Pt peak ratio was determined by Auger electron spectroscopy. Combining these two techniques made it possible to distinguish between chemisorption via σ-bonds and π-complex formation. Benzene and toluene adsorbed first as π-complex while cyclohexane showed initially a partial aromatization and a π-complex-like bonding to the surface. Excess hydrocarbon or addition of hydrogen transformed the π-complex into σ-bonded species. Cyclopentane adsorbed via σ-bonds and showed no significant hydrogen effect.     

Determination of the rheological behavior of epoxy–amine thermosets by dynamic mechanical analysis: Isothermal methods versus nonisothermal methods

The reticulation process of an epoxy resin using an amine as a cure agent was studied at different temperatures and concentrations of the cure agent with dynamic mechanical thermal analysis. The study was performed under both isothermal and nonisothermal conditions, and a temperature–time–transformation diagram was obtained. The measurements from the two modes gave similar results, although the nonisothermal mode required fewer experiments. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 1965–1977, 2003     

DC corona discharge influence on chemical composition in mixtures of natural gas with air and its combustion exhaust with air

Experiments in dc supplied corona discharge in natural gas + air mixture and in combustion exhaust of natural gas + air mixture were realized. The influence of discharge on CO, CO₂, NO _x and other minority components was studied using IR absorption spectrometry. Production of NCO radicals in gas and consequent formation of NCO containing surface layers on a plate electrode was detected. In natural gas + air mixture after about 1 min oxygen poor combustion exhaust was produced due to slow combustion by corona discharge. Occurrence of various pulses in discharge current was typical.     

Smoothing minimally supported frequency wavelets: Part II

The main purpose of this paper is to give a procedure to “mollify” the low-pass filters of a large number ofMinimally Supported Frequency (MSF) wavelets so that the smoother functions obtained in this way are also low-pass filters for an MRA. Hence, we are able to approximate (in the L ² -norm) MSF wavelets by wavelets with any desired degree of smoothness on the Fourier transform side. Although the MSF wavelets we consider are bandlimited, this may not be true for their smooth approximations. This phenomena is related to the invariant cycles under the transformation x ↦2x (mod2π). We also give a characterization of all low-pass filters for MSF wavelets. Throughout the paper new and interesting examples of wavelets are described.     

Multicriteria Goal Games

In this paper, we deal with multicriteria matrix games. Different solution concepts have been proposed to cope with these games. Recently, the concept of Pareto-optimal security strategy which assures the property of security in the individual criteria against an opponent's deviation in strategy has been introduced. However, the idea of security behind this concept is based on expected values, so that this security might be violated by mixed strategies when replications are not allowed. To avoid this inconvenience, we propose in this paper a new concept of solution for these games: the G-goal security strategy, which includes as part of the solution the probability of obtaining prespecified values in the payoff functions. Thus, attitude toward risk together with payoff values are considered jointly in the solution analysis.