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31.
32.
Ligia Bicudo de Almeida Marilene De Vuono Camargo Penteado George Britton Peter Uebelhart Murat Acemoglu Conrad Hans Eugster 《Helvetica chimica acta》1988,71(1):31-32
The 5,6:5′,6′-diepoxy-5,6:5′,6;-tetrahydro-β,β-carotene, isolated from tubers of a white-fleshed variety of sweet potato (Ipomoea batatas LAM .) has been assigned the (5R,6S,5′R,6′S)-chirality on the basis of its HPLC, UV/VIS, and CD data. 相似文献
33.
Eric Johnsen Johan Larsson Ankit V. Bhagatwala William H. Cabot Parviz Moin Britton J. Olson Pradeep S. Rawat Santhosh K. Shankar Bj?rn Sj?green H.C. Yee Xiaolin Zhong Sanjiva K. Lele 《Journal of computational physics》2010,229(4):1213-1237
Flows in which shock waves and turbulence are present and interact dynamically occur in a wide range of applications, including inertial confinement fusion, supernovae explosion, and scramjet propulsion. Accurate simulations of such problems are challenging because of the contradictory requirements of numerical methods used to simulate turbulence, which must minimize any numerical dissipation that would otherwise overwhelm the small scales, and shock-capturing schemes, which introduce numerical dissipation to stabilize the solution. The objective of the present work is to evaluate the performance of several numerical methods capable of simultaneously handling turbulence and shock waves. A comprehensive range of high-resolution methods (WENO, hybrid WENO/central difference, artificial diffusivity, adaptive characteristic-based filter, and shock fitting) and suite of test cases (Taylor–Green vortex, Shu–Osher problem, shock-vorticity/entropy wave interaction, Noh problem, compressible isotropic turbulence) relevant to problems with shocks and turbulence are considered. The results indicate that the WENO methods provide sharp shock profiles, but overwhelm the physical dissipation. The hybrid method is minimally dissipative and leads to sharp shocks and well-resolved broadband turbulence, but relies on an appropriate shock sensor. Artificial diffusivity methods in which the artificial bulk viscosity is based on the magnitude of the strain-rate tensor resolve vortical structures well but damp dilatational modes in compressible turbulence; dilatation-based artificial bulk viscosity methods significantly improve this behavior. For well-defined shocks, the shock fitting approach yields good results. 相似文献
34.
R. Britton J. L. Burnett A. V. Davies P. H. Regan 《Journal of Radioanalytical and Nuclear Chemistry》2014,300(3):1253-1259
GEANT4 Monte Carlo simulations have been successfully utilised to characterise a Compton suppressed broad-energy HPGe detector. The detector setup has been fully recreated in the simulation, which has been optimised to consistently reproduce the detector response. The peak efficiencies for both the primary BEGe detector and NaI(Tl) guard detectors agree with the simulated values for multiple test sources within 3 %. Compton suppression has also been simulated, with good agreement seen between the simulated and actual CSF values (<10 %) for multiple radionuclides. A secondary reference source was also simulated, which contained up to 30 radionuclides in a different geometry to that of the previous source. This showed excellent agreement with experimental data in both unsuppressed and suppressed modes of operation. 相似文献
35.
Shira D. Halperin Hope Fan Stanley Chang Dr. Rainer E. Martin Prof. Robert Britton 《Angewandte Chemie (International ed. in English)》2014,53(18):4690-4693
Fluorination reactions are essential to modern medicinal chemistry, thus providing a means to block site‐selective metabolic degradation of drugs and access radiotracers for positron emission tomography imaging. Despite current sophistication in fluorination reagents and processes, the fluorination of unactivated C? H bonds remains a significant challenge. Reported herein is a convenient and economic process for direct fluorination of unactivated C? H bonds that exploits the hydrogen abstracting ability of a decatungstate photocatalyst in combination with the mild fluorine atom transfer reagent N‐fluorobenzenesulfonimide. This operationally straightforward reaction provides direct access to a wide range of fluorinated organic molecules, including structurally complex natural products, acyl fluorides, and fluorinated amino acid derivatives. 相似文献
36.
37.
Peter G. Doyle Colin Mallows Alon Orlitsky Larry Shepp 《Israel Journal of Mathematics》1989,67(1):34-42
Letn cells be arranged in a ring, or alternatively, in a row. Initially, all cells are unmarked. Sequentially, one of the unmarked
cells is chosen at random and marked until, aftern steps, each cell is marked. After thekth cell has been marked the configuration of marked cells defines some number of islands: maximal sets of adjacent marked
cells. Let ξ
k
denote the random number of islands afterk cells have been marked.
We give explicit expressions for moments of products of ξ
k
’s and for moments of products of 1/ξ
k
’s.
These are used in a companion paper to prove that if a random graph on the natural number is made by drawing an edge betweeni≧1 andj>i with probabilityλ/j, then the graph is almost surely connected ifλ>1/4 and almost surely disconnected ifλ≦1/4. 相似文献
38.
Highly optimized tolerance (HOT) is a mechanism that relates evolving structure to power laws in interconnected systems. HOT systems arise where design and evolution create complex systems sharing common features, including (1) high efficiency, performance, and robustness to designed-for uncertainties, (2) hypersensitivity to design flaws and unanticipated perturbations, (3) nongeneric, specialized, structured configurations, and (4) power laws. We study the impact of incorporating increasing levels of design and find that even small amounts of design lead to HOT states in percolation. 相似文献
39.
High brightness amine‐terminated silicon nanocrystals (Si NCs) have been utilized in a simple and rapid assay for the highly selective and sensitive detection of Fe3+ via quenching of their strong blue luminescence, without the need for analyte‐specific labeling groups. Sensitive detection of Fe3+ is successfully demonstrated, with a linear relationship observed between luminescence quenching and Fe3+ concentration from 5 × 10?6 to 900 × 10?6m and a limit of detection of 1.3 × 10?6m . The Si NCs show excellent selectivity toward Fe3+ ions, with no quenching of the luminescence signal induced by the presence of Fe2+ ions, allowing for solution phase discrimination between the ionic species in different charge states. 相似文献
40.
Optical parametric oscillation in periodically poled lithium niobate driven by a diode-pumped Q-switched erbium fiber laser 总被引:2,自引:0,他引:2
Britton PE Taverner D Puech K Richardson DJ Smith PG Ross GW Hanna DC 《Optics letters》1998,23(8):582-584
We describe what is to our knowledge the first nanosecond periodically poled lithium niobate (PPLN) optical parametric oscillator (OPO) driven by a fiber laser. The source was frequency doubled by a PPLN sample before pumping a second, 20-mm-long, PPLN crystal. The OPO threshold was <10muJ, with pump depletions of as much as 45% and a tunable signal range of 945-1450 nm (1690-4450-nm idler range). We demonstrated 130-nm signal tuning by varying the pump wavelength and doubling crystal's temperature. Also, we achieved 15-nm tuning with all crystals at a constant temperature. The results demonstrate the potential of the fiber laser:PPLN combination for practical, versatile, and tunable sources. 相似文献