Polarimetric-Spectral-Sensitive Compressed Ultrafast Photography Enables Real-Time Intensity Visualization of Time-Varying Polarized Ultrafast Laser Pulses

Ultrafast laser pulses with complex spatiotemporal and polarization couplings have shown great application prospects in coherent control, particle acceleration, molecular dynamics excitation, and chiral or anisotropic detection. It is very important to observe the polarization-coupled ultrafast laser pulses for characterizing the performance of laser source and understanding the laser-matter interaction, but there is currently no detection technique that can completely characterize them, including the spatio-, spectral-, and polarimetric-temporal information. In this work, a polarimetric-spectral-sensitive has been compressed ultrafast photography (PS-CUP) to realize the real-time intensity visualization of time-varying polarized (TP) ultrafast laser pulses. PS-CUP can not only distinguish the polarization state of a TP pulse, but also realize the spatio-, spectral- and polarimetric-temporal measurement. To demonstrate the ability of polarization resolving detection, PS-CUP is used to successfully distinguish between the sinistral and dextral TP pulses and measure the angle and degree of linear polarization of a dextral TP pulse, respectively, and the experimental results are highly consistent with theoretical simulations. Owing to the unprecedented multidimensional detection ability, PS-CUP is prospected to provide a powerful tool for the diagnosis of various complex ultrafast laser pulses and the detection of ultrafast chiral optics.     

柔性悬臂梁与钢球碰撞机制模拟与响应分析

采用线性-弹簧阻尼模型模拟钢球与梁之间的碰撞机制,研究了钢球碰撞下柔性悬臂欧拉梁的衰减振动问题;通过分析推导并建立了整个系统的分段非线性动力学方程。数值结果表明:碰撞是一个瞬时的能量传递过程,碰撞前后梁与钢球的速度均会发生突变;柔性梁从碰撞中获得初始能量,在自身阻尼的作用下作衰减振动;改变系统的参数如钢球质量与速度、碰撞位置等均会对梁的衰减振动产生显著的影响。     

离子液体-水混合溶剂中制备纳米晶TiO2的结构特性及其光催化活性

以钛酸四丁酯为原料, 离子液体1-乙基-3-甲基咪唑醋酸盐([EMIM]+AcO-)-水为混合溶剂, 通过低温水热法制备了锐钛矿相TiO2纳米晶. 用XRD、N2吸附-脱附、XPS及UV-Vis漫反射等技术对产物的晶相、比表面积、表面性质及光吸收性进行表征, 并以甲基橙水溶液为研究对象, 考察了产物的光催化活性及催化剂用量、溶液酸碱度对其的影响. 结果表明, 离子液体鄄水混合溶剂中反应24 h 所得到的TiO2具有较高光催化活性, 并明显优于Degussa P25, 这一结果可归因于其具有较高的锐钛矿含量和较大的比表面积.     

硝酸铀酰与缩二脲的固体配合物的合成及性质

在无水乙醇溶剂中合成出硝酸铀酰与缩二脲的固体配合物UO₂(BuH₂)₄(NO₃)₂,并对其红外光谱、热谱、x-射线粉末衍射及电导等性质进行了研究。     

一种无机阻燃剂的成分剖析研究

介绍了一种无机阻燃剂的成分分析过程,通过化学定性分析判断其成分组成;通过容量分析和重量分析确定成分含量,并辅以原子吸收光谱法加以佐证。     

Decreased Electron Transfer Rates of Manganese Porphyrins with Conformational Distortion of the Macrocycle

Slow electron transfer to manganese(iii) porphyrins results when the macrocycle deviates from planarity. This was demonstrated by measuring the kinetics of homogeneous electron transfer from a series of semiquinone radical anions to synthetic manganese porphyrins (shown schematically; R¹=H, Cl, F; R²=H, F). Three of the four porphyrins studied have nonplanar macrocycles. These results could have implications for the role of manganese in biological electron transfer processes.