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151.
Dr. Hui Ming Ge Han Sun Dr. Nan Jiang Yan Hua Qin Huan Dou Tong Yan Prof. Ya Yi Hou Prof. Christian Griesinger Prof. Ren Xiang Tan 《Chemistry (Weinheim an der Bergstrasse, Germany)》2012,18(17):5213-5221
Bioactive natural products offer multiple opportunities for the discovery of novel chemical entities with potential pharmaceutical, nutraceutical and agrochemical applications. Many new organic compounds with novel scaffolds are isolated in small quantities and established methods often fail to determine the structure and bioactivity of such novel natural products. To meet this challenge, we present here a new methodology combining RDC (residual dipolar coupling)‐based NMR spectroscopy in microtubes, with a motif‐inspired biological assessment strategy. Using only one milligram (ca. 1.5 μmol) of sample, the new protocol established the bioactivity as well as the relative and absolute configuration of vatiparol obtained from Vatica parvifolia. Vatiparol is unique in its unprecedented carbon skeleton and selective inhibitory effect on the expression of monocyte chemo‐attractant protein‐1 (MCP‐1, also known as CCL2). The plausible biosynthetic pathway of vatiparol is briefly discussed. The approach introduced here promises to be widely applicable to the determination of the structure and bioactivity of structurally unknown organic samples available in very limited amounts. 相似文献
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本文提出了一类求解大型稀疏鞍点问题的新的广义不精确Uzawa算法.该方法不仅可以包含 前人的方法, 而且可以拓展出很多新方法. 理论分析给出该方法收敛的条件, 并详细的分析了其收敛性质和参数矩阵的选取方法. 通过对有限元离散的Stokes问题的数值实验表明, 新方法是行之有效的, 其收敛速度明显优于原来的算法. 相似文献
154.
Nonlinear Dynamics - This paper proposes the consensus tracking control problem for a class of uncertain nonlinear multi-agent systems. By using a group of nonnegative functions, an adaptive neural... 相似文献
155.
G. H. Wang X. Y. Li Y. Y. Lu Y. Z. Zhu H. W. Wang L. Dou R. X. Yu 《Zeitschrift für Physik B Condensed Matter》1987,65(3):347-351
12 MeV electron beams with different doses of 4, 8, 16 and 32 Mrad from LINAC designed by Nanjing University have been used to irradiate polypropylene films and their structures studied by X-ray diffraction afterwards. We have found that the electron irradiation does not change the total crystallinity of polypropylene but greatly inflences its crystal structure with increase of phase and decrease of phase as irradiation dose increases (within 16 Mrad). However, it is unexpected that the structure of irradiated sample with 32 Mrad are similar to that of the control sample. This behavior has also been observed in positron annihilation lifetime measurements. 相似文献
156.
X.Y. Dou Z.P. Zhou P.H. Tan L. Song L.F. Liu X.W. Zhao S.D. Luo X.Q. Yan D.F. Liu J.X. Wang Y. Gao Z.X. Zhang H.J. Yuan W.Y. Zhou S.S. Xie 《Physica E: Low-dimensional Systems and Nanostructures》2005,27(4):469-473
In this paper, we developed a new kind of substrate, the silver-coated anodic aluminum oxide (AAO), to investigate the characters of surface-enhanced resonant Raman scattering (SERRS) of the dilute single-walled carbon nanotubes. Homogeneous Ag-coated AAO substrate was obtained by decomposing the AgNO3 on the surface of AAO. single-walled carbon nanotubes (SWNTs) were directly grown onto this substrate through floating catalyst chemical vapor deposition method (CVD). SERRS of SWNTs was carried out using several different wavelength lasers. The bands coming from metallic SWNTs were significantly enhanced. The two SERRS mechanisms, the “electromagnetic” and “chemical” mechanism, were mainly responsible for the experiment results. 相似文献
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This paper is concerned with the asymptotic stability of travelling wave solution to the two-dimensional steady isentropic irrotational flow with artificial viscosity. We prove that there exists a unique travelling wave solution up to a shift to the system if the end states satisfy both the Rankine–Hugoniot condition and Lax's shock condition, and that the travelling wave solution is stable if the initial disturbance is small. 相似文献