全文获取类型
收费全文 | 14597篇 |
免费 | 2884篇 |
国内免费 | 2576篇 |
专业分类
化学 | 11130篇 |
晶体学 | 341篇 |
力学 | 777篇 |
综合类 | 172篇 |
数学 | 1358篇 |
物理学 | 6279篇 |
出版年
2024年 | 59篇 |
2023年 | 314篇 |
2022年 | 621篇 |
2021年 | 723篇 |
2020年 | 755篇 |
2019年 | 745篇 |
2018年 | 633篇 |
2017年 | 642篇 |
2016年 | 812篇 |
2015年 | 886篇 |
2014年 | 1067篇 |
2013年 | 1347篇 |
2012年 | 1510篇 |
2011年 | 1508篇 |
2010年 | 1116篇 |
2009年 | 1034篇 |
2008年 | 1153篇 |
2007年 | 923篇 |
2006年 | 823篇 |
2005年 | 625篇 |
2004年 | 507篇 |
2003年 | 362篇 |
2002年 | 294篇 |
2001年 | 248篇 |
2000年 | 234篇 |
1999年 | 200篇 |
1998年 | 138篇 |
1997年 | 97篇 |
1996年 | 114篇 |
1995年 | 77篇 |
1994年 | 79篇 |
1993年 | 72篇 |
1992年 | 69篇 |
1991年 | 58篇 |
1990年 | 33篇 |
1989年 | 39篇 |
1988年 | 25篇 |
1987年 | 17篇 |
1986年 | 34篇 |
1985年 | 20篇 |
1984年 | 5篇 |
1983年 | 5篇 |
1982年 | 4篇 |
1981年 | 6篇 |
1980年 | 2篇 |
1978年 | 2篇 |
1976年 | 3篇 |
1975年 | 4篇 |
1957年 | 5篇 |
1936年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
71.
72.
Bitao Su Ke Wang Jie Bai Hongmei Mu Yongchun Tong Shixiong Min Shixiong She Ziqiang Lei 《Frontiers of Chemistry in China》2007,2(4):364-368
Fe3+-doped TiO2 composite nanoparticles with different doping amounts were successfully synthesized using sol-gel method and characterized
by X-ray diffraction (XRD), transmission electron microscopy (TEM) and ultravioletvisible spectroscopy (UV-Vis) diffuse reflectance
spectra (DRS). The photocatalytic degradation of methylene blue was used as a model reaction to evaluate the photocatalytic
activity of Fe3+/TiO2 nanoparticles under visible light irradiation. The influence of doping amount of Fe3+ (ω: 0.00%–3.00%) on photocatalytic activities of TiO2 was investigated. Results show that the size of Fe3+/TiO2 particles decreases with the increase of the amount of Fe3+ and their absorption spectra are broaden and absorption intensities are also increased. Doping Fe3+ can control the conversion of TiO2 from anatase to rutile. The doping amount of Fe3+ remarkably affects the activity of the catalyst, and the optimum efficiency occurs at about the doping amount of 0.3%. The
appropriate doping of Fe3+ can markedly increase the catalytic activity of TiO2 under visible light irradiation.
__________
Translated from Journal of Northwest Normal University (Natural Science), 2006, 42(6): 55–56 [译自: 西北师范大学学报(自然科学版)] 相似文献
73.
反向流动注射化学发光法测定痕量铁 总被引:10,自引:1,他引:10
基于邻菲别名林对高碘酸钾-碱性鲁米诺-铁体系发光强度的增敏作用建立了水体中总铁的反向流动性化学发光检测方法。该法线性范围在1×10^-4-10mg/L,检测限为3×10^-6mg/L,对于5×10^-3mg/L Fe测定9次的相对标准偏差为0.9%。此方法已用在水处理中总铁的监测。 相似文献
74.
75.
A series of 2-benzyl-1,3-dicabonyl derivatives was synthesized.Their insulin-sensitizing activity was evaluated in 3T3-L1 preadipocyte cells.Compounds3,26 and 27 were found to possess strong insulin-sensitizing activity in vitro and were selected for further hypoglycemic evaluation in vivo. 相似文献
76.
A novel mode of affinity chromatography (AC) based on an open tubular capillary column (OTAC) is demonstrated. The OTAC column is prepared by immobilizing Cibacron blue F3GA onto the inner surface of a 50-microm-i.d. capillary column. The AC experiment is performed on a capillary electrophoresis instrument by using its pressure system as the driving force. Bovine serum albumin and lysozyme (Lys) are successfully separated with stepwise gradient elution. The relative standard deviation (RSD) for the elution time of the retained Lys is 0.08%, and good repeatability of its peak area and peak height with an RSD value lower than 2.12% for 10 consecutive runs is observed. The loading capacity and detection limit for the retained Lys are approximately 36 ng and 8.6 ng, respectively. It is also found that the amount of protein adsorbed is unaffected by the flow rate of the loading buffer, and OTAC can be used for the fast determination of biopolymers. Some of the advantages of OTAC over conventional modes of open tubular capillary liquid chromatography are that the detection sensitivity and loading capacity of a sample can be greatly improved, because the relatively large inner diameter of the capillary can be adopted and the whole capillary column can be used to adsorb the solute in OTAC. 相似文献
77.
78.
Ju-Chun Huang Chien Hong Cheng Shyang Roeng Sheen Zhi Ling Lee Chien Ming Lei Maw Kuen Wu 《中国化学会会志》1996,43(2):139-143
The synthesis of bulk Y2Ba4Cu7O15-δ superconductor at atmospheric oxygen pressure via solid state sintering is reported. Temperature ranging from 860 to 890 °C as well as time interval over 2 to 15 days were used to investigate the formation of the Y2Ba4Cu7O15-δ phase. A time-temperature profile characterizing the conditions for the preparation of Y2Ba4Cu7O15-δ phase suggests the optimal condition to be sintering at 890 °C for over 10 days. Detailed results of X-ray diffraction, electrical resistivity, iodometric titration and magnetization measurements are described. 相似文献
79.
Yoshimitsu H Nishida M Qian ZZ Lei ZH Nohara T 《Chemical & pharmaceutical bulletin》2000,48(6):828-831
Four new triterpene glycosides were isolated from the dried aerial parts of Thalictrum squarrosum (Ranunculaceae). They were designated as squarroside I, being a cycloartane-type glycoside, and squarrosides II, III and IV, being oleanene-type glycosides. Their structures were established by using two dimensional (2D) NMR techniques. 相似文献
80.