首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   247026篇
  免费   1886篇
  国内免费   885篇
化学   111459篇
晶体学   3778篇
力学   13757篇
综合类   3篇
数学   50811篇
物理学   69989篇
  2020年   1403篇
  2019年   1571篇
  2018年   12185篇
  2017年   12080篇
  2016年   9092篇
  2015年   2717篇
  2014年   3383篇
  2013年   7943篇
  2012年   9391篇
  2011年   17051篇
  2010年   10473篇
  2009年   10881篇
  2008年   12915篇
  2007年   14951篇
  2006年   6296篇
  2005年   6736篇
  2004年   6558篇
  2003年   6500篇
  2002年   5429篇
  2001年   5439篇
  2000年   4135篇
  1999年   3101篇
  1998年   2658篇
  1997年   2516篇
  1996年   2424篇
  1995年   2229篇
  1994年   2163篇
  1993年   2091篇
  1992年   2358篇
  1991年   2305篇
  1990年   2242篇
  1989年   2178篇
  1988年   2180篇
  1987年   2181篇
  1986年   2076篇
  1985年   2674篇
  1984年   2726篇
  1983年   2418篇
  1982年   2532篇
  1981年   2346篇
  1980年   2332篇
  1979年   2470篇
  1978年   2495篇
  1977年   2406篇
  1976年   2452篇
  1975年   2377篇
  1974年   2341篇
  1973年   2528篇
  1972年   1639篇
  1971年   1346篇
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
81.
CdSe和ZnO量子点的拉曼光谱研究   总被引:2,自引:0,他引:2  
本文介绍了用拉曼光谱研究CdSe和ZnO两种Ⅱ Ⅳ族量子点材料的结果,对拉曼峰进行了指认。观察到的光学声子峰位的移动被认为是由量子限制效应引起。  相似文献   
82.
We have analyzed the methyl fluoride RQ(J,0)Q branch lines located near 1475 cm−1 using a simultaneous multi-spectrum fitting technique. In this analysis we have used previously recorded diode-laser data in which we collected many data points covering only one or two Q branch lines in a particular run. The analysis consists of simultaneously fitting 57 spectra collected with numerous pressure and path length conditions for all absorption lines. The data are concatenated to create one continuous spectrum of the Q branch. We have determined the intensity and self-broadened widths at 296 K for 23 RQ(J,0) lines.  相似文献   
83.
We investigate the dynamics of the Λ system driven by two resonant laser fields in presence of dissipation for coupling strengths where the rotating‐wave approximation starts to break down. This regime is characterised by Rabi frequencies being approximately equal or smaller than the field frequencies. A systematic procedure to obtain an expansion for the solution of the Bloch evolution equations of the system is presented. The lowest contribution results to be the well‐known rotating‐wave approximation. The method is based on a semi‐classical treatment of the problem, and its predictions are interpreted fully quantum mechanically. The theory is illustrated by a detailed study of the disappearance of coherent population trapping as the intensities of the fields increase.  相似文献   
84.
85.
    
3-[4-(Azidocarbonyl)]phenylsydnone (2) obtained from 3-(4-hydrazinocarbonyl) phenylsydnone (1) on Curtius rearrangement with alcohols, water and amines afforded the corresponding carbamates (3a-h), 4,4′-(sydnone-3-yl) diphenyl urea (4) and 4-(heterocyclyl)phenyl ureas (5a-l). Compounds (5a-l) on one-pot ring conversion yielded the 1,3,4-oxadiazolin-2-one derivatives (6a-l), which on reaction with N2H4 gave the 4-amino-1,2,4-triazolin-3-ones (7a-l). All these compounds exhibited moderate antimicrobial activity against the few microbes tested. The carbamates have been found to be more toxic against fourth instar larvae ofAedes aegypti, in particular, then-butyl derivative (3e).  相似文献   
86.
Basic ideas and results which characterize quantum diffusion of defects in quantum crystals like solid helium as a new phenomenon are presented. Quantum effects in such media lead to a delocalization of point defects (vacancies, impurities etc.) and they turn into quasiparticles of a new type—defectons, which are characterized not by their position in the crystal lattice but by their quasimomentum and dispersion law. Defecton-defecton and defecton-phonon scattering are considered and an interpolation formula for the diffusion coefficient valid in all interesting temperature and concentration regions is presented. A comparison with the experimental data is made. Some alternative points of view are discussed in detail and the inconsistency of the Kisvarsanyi-Sullivan theory is shown.  相似文献   
87.
Sauer, Shelah, Vapnik and Chervonenkis proved that if a set system on n vertices contains many sets, then the set system has full trace on a large set. Although the restriction on the size of the groundset cannot be lifted, Frankl and Pach found a trace structure that is guaranteed to occur in uniform set systems even if we do not bound the size of the groundset. In this note we shall give three sequences of structures such that every set system consisting of sufficiently many sets contains at least one of these structures with many sets.  相似文献   
88.
89.
The smoothing spline function has been used for differentiation of photomechanical data in experimental stress analysis. However, since the available software packages use the algorithm with the so-called natural boundary conditions which are not necessarily suitable in many circumstances, errors tend to occur in both the first and second derivatives. In this paper we have modified the algorithm so that the user can have more freedom in selecting boundary conditions which suit the problem best and therefore, as a result, improve the accuracy of the analysis. Two examples are given to show the improvement achievable using the new scheme.  相似文献   
90.
We show that, in dimensions equal or greater than three, classical strings do not join or split. This is part of a no-interaction theorem that is also proved. The quantum theory is considered.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号