全文获取类型
收费全文 | 1299篇 |
免费 | 51篇 |
国内免费 | 2篇 |
专业分类
化学 | 925篇 |
晶体学 | 16篇 |
力学 | 38篇 |
数学 | 91篇 |
物理学 | 282篇 |
出版年
2023年 | 8篇 |
2022年 | 29篇 |
2021年 | 25篇 |
2020年 | 32篇 |
2019年 | 28篇 |
2018年 | 33篇 |
2017年 | 34篇 |
2016年 | 57篇 |
2015年 | 47篇 |
2014年 | 59篇 |
2013年 | 95篇 |
2012年 | 117篇 |
2011年 | 84篇 |
2010年 | 47篇 |
2009年 | 47篇 |
2008年 | 96篇 |
2007年 | 58篇 |
2006年 | 51篇 |
2005年 | 44篇 |
2004年 | 43篇 |
2003年 | 28篇 |
2002年 | 33篇 |
2001年 | 8篇 |
2000年 | 6篇 |
1998年 | 7篇 |
1997年 | 8篇 |
1996年 | 13篇 |
1994年 | 4篇 |
1991年 | 7篇 |
1990年 | 5篇 |
1986年 | 10篇 |
1985年 | 11篇 |
1984年 | 10篇 |
1983年 | 6篇 |
1982年 | 6篇 |
1981年 | 11篇 |
1980年 | 6篇 |
1979年 | 9篇 |
1978年 | 16篇 |
1977年 | 5篇 |
1975年 | 4篇 |
1974年 | 4篇 |
1969年 | 6篇 |
1968年 | 9篇 |
1964年 | 4篇 |
1963年 | 7篇 |
1962年 | 7篇 |
1961年 | 12篇 |
1958年 | 8篇 |
1955年 | 5篇 |
排序方式: 共有1352条查询结果,搜索用时 8 毫秒
61.
Short and convenient synthesis of bicyclic lactones (1) and (2), important intermediates in trichothecene synthesis is described. 相似文献
62.
A recent report by El Feraly et. al 3 describing the direct conversion of 5, 7-dimethoxy - 2, 3 - dihydro - 1H-benzcyclopenten- 1 -one(1) to the homologated aldehyde (3) by dimethyl sulfonium 4 methylide4 (2), prompted us to present results obtained from our investigation of the reaction of various aromatic aldehydes and ketones, possessing electron releasing p-substituent, with (2). Our interest in examining this particular reaction arose from a need to prepare the oxirane (5) and the aldehyde (6), required in connection with the synthesis and biological evaluation of semi-rigid analogues of catecholamines as probes for the study 5 of adrenergic and dopaminergic receptors.5 相似文献
63.
Atul C. Chaskar Arun A. Yadav Bhushan P. Langi Anita Murugappan Chetan Shah 《合成通讯》2013,43(19):2850-2856
Simple, efficient, and mild method for α-thiocyanation of ketones in presence of heteropolyacid has been developed. This methodology offered α-oxothiocyanates in good to excellent yields at room temperature in a highly selective manner. The catalyst could be efficiently recovered from the reaction and reused. 相似文献
64.
A mild, efficient, and highly regio- and stereoselective method for the methoxy and ethoxy bromination of olefins has been developed using NH4Br as a bromine source and Oxone as an oxidant. Various kinds of olefins (aromatic, linear, and cyclic olefins) afforded the corresponding alkoxy brominated products in moderate to excellent yields. [Supplementary materials are available for this article. Go to the publisher's online edition of Synthetic Communications® for the following free supplemental resources: Full experimental and spectral details.] 相似文献
65.
Aetheramides A and B are very potent anti-HIV agents. An enantioselective synthesis of a MEM-protected aetheramide A derivative is described. The synthesis was accomplished in a convergent and stereoselective manner. The key reactions involved asymmetric dihydroxylation, asymmetric allylation, asymmetric syn-aldol reactions, and asymmetric hydrogenation. 相似文献
66.
Can quantum-information theory shed light on black-hole evaporation? By entangling the in-fallen matter with an external system we show that the black-hole information paradox becomes more severe, even for cosmologically sized black holes. We rule out the possibility that the information about the in-fallen matter might hide in correlations between the Hawking radiation and the internal states of the black hole. As a consequence, either unitarity or Hawking's semiclassical predictions must break down. Any resolution of the black-hole information crisis must elucidate one of these possibilities. 相似文献
67.
M. S. Gaur Pramod Kumar Singh Asif Ali Rekha Singh 《Journal of Thermal Analysis and Calorimetry》2014,117(3):1407-1417
β-phase polyvinylidene fluoride (PVDF)–BaTiO3 nanocomposite samples have been prepared by solution mixing method. XRD data represent that the crystallinity of PVDF decreases with increase in loading level of BaTiO3 nanoparticles. DSC curve represents that the melting point of PVDF is lightly affected by loading concentration of BaTiO3. The morphology and microstructure of PVDF and PVDF embedded by BaTiO3 nanofillers were investigated by using inverted contrast microscopy (ICM) and scanning electron microscopy (SEM). FTIR interferrometry is proven that PVDF and BaTiO3 are not chemically interacting; therefore, interaction of BaTiO3 is van der Waals type of interaction. The thermally stimulated discharge current (TSDC) of PVDF and PVDF–BaTiO3 nanocomposites sample was characterized by single peak. The observed TSDC peak is discussed on the basis of dipolar and interfacial polarization. 相似文献
68.
Modification of Extended Open Frameworks with Fluorescent Tags for Sensing Explosives: Competition between Size Selectivity and Electron Deficiency 下载免费PDF全文
Bappaditya Gole Dr. Arun Kumar Bar Prof. Partha Sarathi Mukherjee 《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(8):2276-2291
Three new electron‐rich metal–organic frameworks ( MOF‐1 – MOF‐3 ) have been synthesized by employing ligands bearing aromatic tags. The key role of the chosen aromatic tags is to enhance the π‐electron density of the luminescent MOFs. Single‐crystal X‐ray structures have revealed that these MOFs form three‐dimensional porous networks with the aromatic tags projecting inwardly into the pores. These highly luminescent electron‐rich MOFs have been successfully utilized for the detection of explosive nitroaromatic compounds (NACs) on the basis of fluorescence quenching. Although all of the prepared MOFs can serve as sensors for NACs, MOF‐1 and MOF‐2 exhibit superior sensitivity towards 4‐nitrotoluene (4‐NT) and 2,4‐dinitrotoluene (DNT) compared to 2,4,6‐trinitrotoluene (TNT) and 1,3,5‐trinitrobenzene (TNB). MOF‐3 , on the other hand, shows an order of sensitivity in accordance with the electron deficiencies of the substrates. To understand such anomalous behavior, we have thoroughly analyzed both the steady‐state and time‐resolved fluorescence quenching associated with these interactions. Determination of static Stern–Volmer constants (KS) as well as collisional constants (KC) has revealed that MOF‐1 and MOF‐2 have higher KS values with 4‐NT than with TNT, whereas for MOF‐3 the reverse order is observed. This apparently anomalous phenomenon was well corroborated by theoretical calculations. Moreover, recyclability and sensitivity studies have revealed that these MOFs can be reused several times and that their sensitivities towards TNT solution are at the parts per billion (ppb) level. 相似文献
69.
70.
Thimmaiah Srivatsa Wahidi Tabish Yadav Ajay Kumar Mahalingam Arun 《Journal of Thermal Analysis and Calorimetry》2020,141(6):2219-2229
Journal of Thermal Analysis and Calorimetry - Natural circulation loop (NCL) is a geometrically simple heat transfer device in which fluid flow occurs due to density gradient of loop fluid, induced... 相似文献