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491.
492.
A. V. Aksenov I. V. Aksenova I. V. Borovlev A. A. Zamorkin 《Russian Chemical Bulletin》2008,57(1):215-216
Heating of 2-ethoxynaphthalene with 1,3,5-triazine or 2,4,6-trimethyl-1,3,5-triazine in polyphosphoric acid leads to the corresponding
products of mono- or diacylation: 2-ethoxy-naphthalene-1-carbaldehyde, 1-acetyl-2-ethoxynaphthalene, 2-ethoxynaphthalene-1,8-dicarb-aldehyde,
and 1,8-diacetyl-2-ethoxynaphthalene in ∼60–80% yield.
Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 207–208, January, 2008. 相似文献
493.
T. N. Sidorenko G. A. Terent'eva V. S. Raida O. S. Andrienko Yu. V. Savinykh V. S. Aksenov 《Chemistry of Heterocyclic Compounds》1982,18(12):1246-1250
A number of 3-chloro-2-chlorocarbonylbenzo [b] thiophenes with alkyl substituants in various positions of the benzene ring were synthesized by arylation of acrylic acid with the corresponding alkyl-substituted iodobenzenes under the influence of catalytic amounts of palladium acetate and subsequent oxidation of the resulting arylacrylic acids with thionyl chloride. Replacement of the pyridine added in the oxidation reaction by triethylbenzylammonium chloride led to substantial increases in the yields of the desired products. The possibility of conversion of the resulting benzo [b] thiophene derivatives to thiophene ring-unsubstituted benzo[b] thiophenes was shown in the case of 3-chloro-2-chlorocarbonylbenzo [b] thiophene as a result of successive saponification of the 2-chlorocarbonyl group, decarboxylation, and dechlorination.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 12, pp. 1618–1622, December, 1982. 相似文献
494.
Nikita V. Chukanov Ramiza K. Rastsvetaeva Natalia V. Zubkova Marina F. Vigasina Igor V. Pekov Andrey A. Zolotarev Julia A. Mikhailova Sergey M. Aksenov 《Journal of Raman spectroscopy : JRS》2024,55(5):581-597
Microporous materials containing hydrated silanol groups Si–OH as well as hydrated proton complexes, H2n+1On+, including hydronium (n = 1), Zundel (n = 2), and Eigen (n = 4) cations, are of practical importance as potential ion exchangers and ion conductors. In this paper, we provide data on crystal-chemical features, hydrogen bonding and Raman spectra of alkaline microporous titano-, niobo-, zircono-, and aluminosilicate minerals belonging to the labuntsovite, lovozerite, eudialyte, and sodalite groups in which a part of sodium was substituted by hydrated proton complexes under low-temperature hydrothermal or supergene conditions. Most minerals studied in this work do not have synthetic analogues and are considered as possible natural prototypes of microporous materials with technologically important properties. The obtained experimental data and their comparison with the results of ab initio theoretical calculations published elsewhere show that Raman spectroscopy is an effective tool for the precise identification of hydrated proton complexes with extremely strong hydrogen bonds and estimation of corresponding O···O distances in the range of 2.37–2.68 Å. The presence of hydrated proton complexes in microporous silicates is a clear and sensitive geological indicator showing that a rock underwent the low-temperature alteration. 相似文献