Homolytic ethoxycarbonylation of aminopyridines

Pyridinecarboxylic acid ethyl esters are formed in the reaction of ethoxycarbonyl radicals with aminopyridines.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1075–1077, August, 1988.     

Synthesis of condensed pregnano[17,16-<Emphasis Type="Italic">d</Emphasis>]triazolines under high pressure

Condensed pregnano[17,16-d]triazolines were produced in 1,3-dipolar cycloaddition of 16-dehydropregnenolone acetate with organic azides at 10 kbar. The structure of the synthesized compounds was determined by using two-dimensional NMR spectroscopy (¹H—¹H COSY, NOESY, HSQC, and HMBC).     

Neutralizing a high-aperture metal-ion beam

It is found that secondary electrons ejected by the ions from the collector are responsible for neutralizing 300 sec pulses of wide-aperture ion beams (about 100–300 cm²) formed by various metals and having current densities ji of about 10^–2 A/cm² and energy _i 100 keV. A negative potential _ee=–500 V applied to the extracting electrode relative to the grounded collector improves substantially not only the beam neutralization in the transport section but also the ion generation efficiency in the accelerating gap.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 4, pp. 53–56, April, 1990.     

Investigations of 2,3′-biquinolyl. 8. Reduction of 1-alkyl-3-(2-quinolyl)-quinolinium halides with sodium borohydride

Reduction of 1-alkyl-3-(2-quinolyl)quinolinium halides with sodium borohydride leads to 1-alkyl-1,2-dihydro-2,3-biquinolyls which, except for the ethoxycarbonyl derivative, undergo rearrangement to 1-alkyl-1,4-dihydro-2,3-biquinolyls. The last can be synthesized by the alkylation of the corresponding 1,4-dihydro-2,3-biquinolyls under conditions of interphase catalysis and in the system KOH-DMSO.For Communication 7, see [1].Stavropol' State University, Stavropol' 355009, Russia; nauka@stavsu.ru. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1084–1087, August, 2000.     

On Mutual Generation of Magnetic Fields in Tokamaks and Methods of Its Suppression

Russian Physics Journal -