全文获取类型
收费全文 | 1149篇 |
免费 | 60篇 |
国内免费 | 4篇 |
专业分类
化学 | 974篇 |
晶体学 | 10篇 |
力学 | 10篇 |
数学 | 58篇 |
物理学 | 161篇 |
出版年
2023年 | 8篇 |
2022年 | 6篇 |
2021年 | 16篇 |
2020年 | 22篇 |
2019年 | 29篇 |
2018年 | 21篇 |
2017年 | 14篇 |
2016年 | 32篇 |
2015年 | 33篇 |
2014年 | 37篇 |
2013年 | 44篇 |
2012年 | 88篇 |
2011年 | 100篇 |
2010年 | 59篇 |
2009年 | 47篇 |
2008年 | 53篇 |
2007年 | 82篇 |
2006年 | 80篇 |
2005年 | 69篇 |
2004年 | 49篇 |
2003年 | 65篇 |
2002年 | 59篇 |
2001年 | 17篇 |
2000年 | 13篇 |
1999年 | 18篇 |
1998年 | 7篇 |
1997年 | 12篇 |
1996年 | 10篇 |
1995年 | 13篇 |
1994年 | 13篇 |
1993年 | 7篇 |
1992年 | 10篇 |
1991年 | 5篇 |
1990年 | 3篇 |
1989年 | 2篇 |
1988年 | 4篇 |
1987年 | 3篇 |
1986年 | 5篇 |
1985年 | 8篇 |
1984年 | 13篇 |
1983年 | 4篇 |
1982年 | 8篇 |
1981年 | 6篇 |
1980年 | 5篇 |
1978年 | 4篇 |
1977年 | 2篇 |
1973年 | 1篇 |
1971年 | 1篇 |
1968年 | 2篇 |
1963年 | 1篇 |
排序方式: 共有1213条查询结果,搜索用时 31 毫秒
151.
152.
Akihiro Uchiyama 《Nuclear Physics B》1984,244(1):57-76
We show that the Bogomolny bound is saturated by supersymmetric solitons in 1 + 1 dimensions to all orders of the expansion. 相似文献
153.
Akihiro Tsutsumi Kunio Hikichi Motozo Kaneko Jiro Furuichi 《Journal of Polymer Science.Polymer Physics》1968,6(3):493-498
Nuclear magnetic resonance of poly-β-alanine samples differing in solubility in water was studied over a wide temperature range as part of an investigation of their physical properties. Water-soluble poly-β-alanine has more branches and a lower degree of crystallinity than water-insoluble poly-β-alanine. NMR spectra of poly-β-alanine show one component at 77°K. which splits into two components, broad and narrow, at room temperature. Two transition regions were observed in curves for line width and second moment versus temperature. The higher transition temperature, corresponding to the glass transition of the polymer, appears to decrease with increasing water content. The second moment for the water-soluble polymer differs from that of the water-insoluble polymer at 77°K. This is interpreted in terms of the difference in the degree of crystallinity of the polymers. 相似文献
154.
Akihiro Fukabori Takayuki Yanagida Federico Moretti Yuui Yokota Rayko Shimura Shuji Maeo Jan Pejchal Kei Kamada Akira Yoshikawa 《Radiation measurements》2010,45(3-6):453-456
Micro-pulling down (μ-PD) method allows to prepare single crystals quickly and relatively inexpensively. Since it is a melt growth and taking into account segregation phenomena, the μ-PD method allows also to obtain single crystals characterized by dopant concentration gradients. Especially, taking the advantage of the grown crystal high aspect ratio, it allows to prepare crystalline samples with variable and wide range concentrations of dopants. These samples can help in understanding the correlation between dopant concentration and luminescence properties. 相似文献
155.
Nakayama T Kurosawa Y Furui S Kerman K Kobayashi M Rao SR Yonezawa Y Nakano K Hino A Yamamura S Takamura Y Tamiya E 《Analytical and bioanalytical chemistry》2006,386(5):1327-1333
Polymerase chain reaction (PCR) is an essential part of research based on genomics or cell analysis. The development of a
microfluidic device that would be suitable for high-temperature-based reactions therefore becomes an important contribution
towards the integration of micro-total analysis systems (μTAS). However, problems associated with the generation of air bubbles
in the microchannels before the introduction of the assay liquid, which we call the “initial start-up” in this study, made
the flow irregular and unstable. In this report, we have tried to address these problems by adapting a novel liquid-flow method
for high-temperature-based reactions. A PDMS-based microfluidic device was fabricated by soft-lithography techniques and placed
on a cartridge heater. The generation of the air bubbles was prevented by introducing the fluorinated oil, an inert and highly
viscous liquid, as the cap just before the introduction of the sample solutions into the microchannels. The technique was
applied for continuous-flow PCR, which could perform PCR on-chip in a microfluidic system. For the evaluation of practical
accuracy, plasmid DNA that serves as a reference molecule for the quantification of genetically modified (GM) maize was used
as the template DNA for continuous-flow PCR. After PCR, the products were collected in a vial and analyzed by gel electrophoresis
to confirm the accuracy of the results. Additionally, quantitative continuous-flow PCR was performed using TaqMan technology
on our PCR device. A laser detection system was also used for the quantitative PCR method. We observed a linear relationship
between the threshold cycle (Ct) and the initial DNA concentration. These results showed that it would be possible to quantify
the initial copies of the template DNA on our microfluidic device. Accurate quantitative DNA analysis in microfluidic systems
is required for the integration of PCR with μTAS, thus we anticipate that our device would have promising potential for applications
in a wide range of research. 相似文献
156.
A new dendritic oligoarylamine, N,N,N',N',N",N"-hexakis[4-(di-4-anisylamino)phenyl]- 1,3,5-benzenetriamine (BTA) 2, which contains a 1,3,5-benzenetriamine molecular unit as an potential precursor of a high-spin molecule and three oligoarylamine moieties as spin-carrying units surrounding the core BTA, has been prepared by the sequential palladium-catalyzed amination reactions. The redox property has been investigated by cyclic voltammetry, and the highly charged states up to the hexacation are accessible to 2. The polycationic high-spin species have been generated by stepwise chemical oxidation, and the electronic structures have been examined in detail by the continuous wave (CW) and pulsed ESR spectroscopy in comparison with the previously studied 1. The pulsed ESR technique enabled us to determine the definite spin multiplicity of the generated polycationic species of 2. It was confirmed that the dominant oxidized species observed by the two- and three-electron oxidations were assigned to the spin triplet 2(2+) and the spin quartet 2(3+), respectively. Moreover, these high-spin polycationic species turned out to be far more stable as compared to 1, and the isolation of 2(3+) as the SbCl(6)(-) salt has been accomplished. The temperature dependence of the magnetic susceptibility for the 2(3+)(SbCl(6)(-))(3) salt revealed that the intramolecular ferromagnetic interaction exists in 2(3+), and moreover, the trication 2(3+) was found to be deformed in the solid state. 相似文献
157.
In this Letter, we consider lattice versions of the decomposition of the Yang–Mills field a la Cho–Faddeev–Niemi, which was extended by Kondo, Shinohara and Murakami in the continuum formulation. For the SU(N) gauge group, we propose a set of defining equations for specifying the decomposition of the gauge link variable and solve them exactly without using the ansatz adopted in the previous studies for SU(2) and SU(3). As a result, we obtain the general form of the decomposition for SU(N) gauge link variables and confirm the previous results obtained for SU(2) and SU(3). 相似文献
158.
Akihiro Takezawa Shinji Nishiwaki Mitsuru Kitamura 《Journal of computational physics》2010,229(7):2697-2718
This paper discusses a structural optimization method that optimizes shape and topology based on the phase field method. The proposed method has the same functional capabilities as a structural optimization method based on the level set method incorporating perimeter control functions. The advantage of the method is the simplicity of computation, since extra operations such as re-initialization of functions are not required. Structural shapes are represented by the phase field function defined in the design domain, and optimization of this function is performed by solving a time-dependent reaction diffusion equation. The artificial double well potential function used in the equation is derived from sensitivity analysis. The proposed method is applied to two-dimensional linear elastic and vibration optimization problems such as the minimum compliance problem, a compliant mechanism design problem and the eigenfrequency maximization problem. The numerical examples provided illustrate the convergence of the various objective functions and the effect that perimeter control has on the optimal configurations. 相似文献
159.
We theoretically investigate the phase noise in quasi-linear optical transmission systems and study the mitigation of phase noise by properly choosing periodic dispersion compensation and amplification. Variational method is used to deduce the analytical formula for calculating the phase fluctuations of a Gaussian pulse. The analytical predictions are then checked against direct simulations by numerically solving the nonlinear Schrödinger equation. We find that stronger dispersion compensation maps can be used to reduce phase noise and it can be further mitigated by modifying the dispersion map appropriately. It is also found that shorter amplifier spacing yields lower phase noise. We also explore the effect of pre-, post- and bi-end dispersion compensation configurations on phase noise with full compensation and check the reduction of phase noise along the fiber link. 相似文献
160.
The basic mechanism of cross-phase modulation induced phase fluctuations in optical RZ pulse propagating in a periodically dispersion compensated transmission line has been investigated. Ordinary differential equations have been derived using variational analysis to estimate the phase fluctuation and the analytical result is verified by numerical simulations based on split-step Fourier method. We therefore explore the impact of different dispersion compensation maps on phase fluctuation for 10 Gb/s and 40 Gb/s WDM transmission systems. The effects of initial pulse spacing between channels, channel spacing and residual dispersion on phase shift have been studied. We find that cross-phase modulation induced phase fluctuation can be mitigated by proper adjustment of channel spacing and/or residual dispersion. 相似文献