Effects of A1 site occupation on dielectric and ferroelectric properties of Sr4CaRTi3Nb7O30（R=Ce,Eu） tungsten bronze ceramics

Sr4Ca RTi3Nb7O30（R = Ce, Eu） tungsten bronze ceramics are prepared by a standard solid state reaction method. The effects of A1 site occupation on the dielectric and ferroelectric properties of Sr4 Ca RTi3Nb7O30（R = Ce, Eu） tetragonal tungsten bronzes are investigated. The Sr4 Ca Ce Ti3Nb7O30 shows a normal transition behavior due to the closer size ion occupation in A1 sites, which could suppress the distortion of B2 octahedra effectively. Sr4 Ca Eu Ti3Nb7O30 ceramic exhibits two dielectric anomalies, which might be related to the fact that the large radius difference between Ca^2＋ and Eu^3＋ could lead to the uneven distribution of Ca^2＋ and Eu^3＋ in A1 sites and form two slightly different kinds of compositions with different transition temperatures in the structure. Our results indicate that the ionic radius difference in A1 sites plays an important role in determining the dielectric and ferroelectric natures of the filled tungsten bronze ceramics. Polarization–electric field（P–E） curves are evaluated at room temperature and both of them show hysteresis loops. Sr4 Ca Ce Ti3Nb7O30 shows a fat hysteresis loop, indicating the long-range ferroelectric order in the ceramic. The current density–electric field（J–E） curves are measured at room temperature with a largest leakage current density of ～ 10^-6A/cm^2, indicating that their leakage currents are rather low.     

基于垂直距离的直线拟合

在分析传统的直线拟合基础上,提出基于垂直距离的直线拟合问题.针对3种准则,给出了3个模型.对于使残差的平方和为最小准则,经过推导得到一个精确结果.     

Application of longitudinal generalized magneto-optical ellipsometry in magnetic ultrathin films

The longitudinal generalized magneto-optical ellipsometry(GME) method is extended to the measurement of threelayer ultrathin magnetic films. In this work, the theory of the reflection matrix is introduced into the GME measurement to obtain the reflective matrix parameters of ultrathin multilayer magnetic films with different thicknesses. After that, a spectroscopic ellipsometry is used to determine the optical parameter and the thickness of every layer of these samples, then the magneto-optical coupling constant of the multilayer magnetic ultrathin film can be obtained. After measurements of a series of ultrathin Fe films, the results show that the magneto-optical coupling constant Q is independent of the thickness of the magnetic film. The magneto-optical Kerr rotations and ellipticity are measured to confirm the validity of this experiment. Combined with the optical constants and the Q constant, the Kerr rotations and ellipticity are calculated in theory. The results show that the theoretical curve fits very well with the experimental data.     

解微分方程组的改进尤拉方法的改进

对改进尤拉方法解微分方程组的方法作了改进,改进的算法与原来算法的计算量一样,但精度比较高.     

偏光干涉法测量波片相位延迟量和厚度

基于偏光干涉理论,提出一种宽光谱范围内测量波片相位延迟量和厚度的方法。利用矩阵光学方法分析了光谱透射率曲线与中值透射率直线交点波长之间的关系,给出待测波片的相位延迟量、波片厚度等多个物理量的计算公式并进行了误差分析。误差分析表明本方法相位延迟量测量最大误差为3.38°,厚度测量最大误差为0.66μm。实验上利用分光光度计验证了本方法的有效性。本方法能够实现波片多物理量的同时测量,且调节过程对于起偏器、检偏器透光轴方向及待测波片快轴方向无严苛要求,测量过程对波片也无损伤和污染,在波片加工、使用前质量评估等方面都具有一定的应用价值。     

基于超平表面的原子力显微镜探针磨损研究

探针磨损是影响原子力显微镜图像质量的关键因素之一。为了研究原子力显微镜(AFM)探针针尖磨损问题,选取超平表面(R_q0.5 nm)作为测试样品,采用材料表面的粗糙度(R_q)评估探针针尖磨损效率。在较低的探针悬臂目标振幅比例(10%),较低反馈回路设定值比例(10%),较低扫描速度(1.0 Hz)以及适中I-gain(1.7)的测试条件下,探针的磨损最小,可以有效地延长探针的使用寿命。最后利用扫描电镜对比了不同测试条件下探针针尖的形貌,推测了探针针尖在连续测试中磨损与断裂的机理。     

rK1∪Im的匹配等价图类

计算了rK₁∪I_m的匹配等价图的个数,并且刻画了rK₁∪I_m以及它的补图的匹配等价图类.     

Structure and electronic structure of S-doped graphitic C₃N₄ investigated by density functional theory

The structures of the heptazine-based graphitic C3N4 and the S-doped graphitic C3N4 are investigated by using the density functional theory with a semi-empirical dispersion correction for the weak long-range interaction between layers.The corrugated structure is found to be energetically favorable for both the pure and the S-doped graphitic C3N4.The S doptant is prone to substitute the N atom bonded with only two nearest C atoms.The band structure calculation reveals that this kind of S doping causes a favorable red shift of the light absorption threshold and can improve the electroconductibility and the photocatalytic activity of the graphitic C3N4.     

基于支持向量机的武器系统参数费用模型

在武器系统分析中,建立武器参数费用模型时,首先要挑选特征参数,这里采用R ough理论中的知识约简方法选择武器的特征参数;利用支持向量机建立了参数费用模型;给出了实例和解决此问题的支持向量机源程序.通过实例与线性回归法和神经网络法的结果进行了比较,结果表明支持向量机比较精确和简单.     

套汇问题研究

把套汇问题转化为网络规划中找负回路问题,用F loyd算法解决了套汇问题.讨论了避免套汇兑换率矩阵必须是正互反矩阵的结论,以及给出了兑换率矩阵调整为正互反矩阵的方法.